Reactions of Fe 2 ( μ ‐odt)(CO) 6 (odt = 1, 3‐oxadithiolate) with small bite‐angle diphosphines to afford the monodentate, chelate, and bridge diiron complexes: Selective substitution, structures, protonation, and electrocatalytic proton reduction

Influence of Dithiolate Bridges on the Structures and Electrocatalytic Performance of Small Bite-Angle PNP-Chelated Diiron Complexes Fe2(μ-xdt)(CO)4{κ2-(Ph2P)2NR} Related to [FeFe]-Hydrogenases

(2019) Pei-Hua Zhao et al.   ORGANOMETALLICS

[Fe(C 5 Ar 5 )(CO) 2 Br] complexes as hydrogenase mimics for the catalytic hydrogen evolution reaction

(2018) E.B. Hemming et al.   APPLIED CATALYSIS B-ENVIRONMENTAL

Sterically Stabilized Terminal Hydride of a Diiron Dithiolate

(2018) Michaela R. Carlson et al.   INORGANIC CHEMISTRY

PNP-Chelated and -Bridged Diiron Dithiolate Complexes Fe2(μ-pdt)(CO)4{(Ph2P)2NR} Together with Related Monophosphine Complexes for the [2Fe]H Subsite of [FeFe]-Hydrogenases: Preparation, Structure, and Electrocatalysis

(2018) Pei-Hua Zhao et al.   ORGANOMETALLICS

Terminal Thiolate-Dominated H/D Exchanges and H2 Release: Diiron Thiol–Hydride

(2018) Xin Yu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Aminophosphine-substituted diiron dithiolate complexes: Synthesis, crystal structure, and electrocatalytic investigation

(2017) Yu-Long Li et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Direct Observation of an Iron-Bound Terminal Hydride in [FeFe]-Hydrogenase by Nuclear Resonance Vibrational Spectroscopy

(2017) Edward J. Reijerse et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Reaction Coordinate Leading to H2 Production in [FeFe]-Hydrogenase Identified by Nuclear Resonance Vibrational Spectroscopy and Density Functional Theory

(2017) Vladimir Pelmenschikov et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Interplay between Terminal and Bridging Diiron Hydrides in Neutral and Oxidized States

(2017) Xin Yu et al.   ORGANOMETALLICS

A New Route to the Synthesis of Phosphine-Substituted Diiron Aza- and Oxadithiolate Complexes

(2017) Jiao He et al.   ORGANOMETALLICS

Electrocatalytic Hydrogen Production by a Nickel(II) Complex with a Phosphinopyridyl Ligand

(2016) Ryo Tatematsu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Hydrogenase Enzymes and Their Synthetic Models: The Role of Metal Hydrides

(2016) David Schilter et al.   CHEMICAL REVIEWS

Synthesis of Diiron(I) Dithiolato Carbonyl Complexes

(2016) Yulong Li et al.   CHEMICAL REVIEWS

Hydrophilic Quaternary Ammonium-Group-Containing [FeFe]-Hydrogenase Models: Synthesis, Structures, and Electrocatalytic Hydrogen Production

(2016) Li-Cheng Song et al.   CHEMISTRY-A EUROPEAN JOURNAL

Biomimetics of the [FeFe]-hydrogenase enzyme: Identification of kinetically favoured apical-basal [Fe 2 (CO) 4 (μ-H){κ 2 -Ph 2 PC(Me 2 )PPh 2 }(μ-pdt)] + as a proton-reduction catalyst

(2016) Shishir Ghosh et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Hydrogenase biomimetics: structural and spectroscopic studies on diphosphine-substituted derivatives of Fe2(CO)6(µ-edt) (edt = ethanedithiolate) and Fe2(CO)6(µ-tdt) (tdt = 1,3-toluenedithiolate)

(2016) Shahed Rana et al.   TRANSITION METAL CHEMISTRY

Diiron Azadithiolates as Models for the [FeFe]-Hydrogenase Active Site and Paradigm for the Role of the Second Coordination Sphere

(2015) Thomas B. Rauchfuss   ACCOUNTS OF CHEMICAL RESEARCH

Diiron Complexes Bearing Bridging Hydrocarbyl Ligands as Electrocatalysts for Proton Reduction

(2015) Rita Mazzoni et al.   ORGANOMETALLICS

Hydrogenases

(2014) Wolfgang Lubitz et al.   CHEMICAL REVIEWS

Models of the iron-only hydrogenase: a comparison of chelate and bridge isomers of Fe2(CO)4{Ph2PN(R)PPh2}(μ-pdt) as proton-reduction catalysts

(2013) Shishir Ghosh et al.   DALTON TRANSACTIONS

Enzymes activated by synthetic components

(2013) Ryan D. Bethel et al.   NATURE

Biomimetic assembly and activation of [FeFe]-hydrogenases

(2013) G. Berggren et al.   NATURE

Synthetic Models for the Active Site of the [FeFe]-Hydrogenase: Catalytic Proton Reduction and the Structure of the Doubly Protonated Intermediate

(2012) Maria E. Carroll et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Sulfoxygenation of Active Site Models of [NiFe] and [FeFe] Hydrogenases - A Commentary on Possible Chemical Models of Hydrogenase Enzyme Oxygen Sensitivity

(2011) Marcetta Y. Darensbourg et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Diphosphine Mobility at a Binuclear Metal Center: A Concerted Double Trigonal-Twist in Bis(dithiolate) Complexes [M2(CO)4(μ-dppm){μ-S(CH2)nS}] (M = Fe, Ru;n= 2, 3)

(2010) Graeme Hogarth et al.   ORGANOMETALLICS

Structural and Functional Analogues of the Active Sites of the [Fe]-, [NiFe]-, and [FeFe]-Hydrogenases†

(2009) Cédric Tard et al.   CHEMICAL REVIEWS

Review of electrochemical studies of complexes containing the Fe2S2 core characteristic of [FeFe]-hydrogenases including catalysis by these complexes of the reduction of acids to form dihydrogen

(2009) Greg A.N. Felton et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

[Ni(PPh2NAr2)2(NCMe)][BF4]2 as an electrocatalyst for H2 production: PPh2NAr2=1,5-(di(4-(thiophene-3-yl)phenyl)-3,7-diphenyl-1,5-diaza-3,7-diphosphacyclooctane)

(2009) Douglas H. Pool et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Dithiomethylether as a Ligand in the Hydrogenase H-Cluster

(2008) Arti S. Pandey et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY