Asymmetric Allylic Alkylation with Deconjugated Carbonyl Compounds: Direct Vinylogous Umpolung Strategy

Asymmetric Allylic C–H Alkylation via Palladium(II)/cis-ArSOX Catalysis

(2018) Wei Liu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric Synthesis of α,β-Unsaturated δ-Lactones through Copper(I)-Catalyzed Direct Vinylogous Aldol Reaction

(2018) Hai-Jun Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective α-Allylation of Aryl Acetic Acid Esters via C1-Ammonium Enolate Nucleophiles: Identification of a Broadly Effective Palladium Catalyst for Electron-Deficient Electrophiles.

(2018) Luke Hutchings-Goetz et al.   ACS Catalysis

Direct Allylic C–H Bond Activation To Synthesize [Pd(η3-cin)(IPr)Cl] Complex: Application in the Allylation of Oxindoles

(2017) Rong-Bin Hu et al.   ACS Catalysis

Effective asymmetric vinylogous Mannich reaction of isatin imines with α,α-dicyanoolefins in the presence of a simple chiral amide phosphonium bifunctional phase transfer catalyst

(2017) Cang Cheng et al.   Organic Chemistry Frontiers

Enantioselective Allylic C−H Oxidation of Terminal Olefins to Isochromans by Palladium(II)/Chiral Sulfoxide Catalysis

(2016) Stephen E. Ammann et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Combinations of Aminocatalysts and Metal Catalysts: A Powerful Cooperative Approach in Selective Organic Synthesis

(2016) Samson Afewerki et al.   CHEMICAL REVIEWS

Amide-Phosphonium Salt as Bifunctional Phase Transfer Catalyst for Asymmetric 1,6-Addition of Malonate Esters to para-Quinone Methides

(2016) Luo Ge et al.   JOURNAL OF ORGANIC CHEMISTRY

Highly Enantioselective Allylic C–H Alkylation of Terminal Olefins with Pyrazol-5-ones Enabled by Cooperative Catalysis of Palladium Complex and Brønsted Acid

(2016) Hua-Chen Lin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Organocatalytic Enantioselective Vinylogous Aldol Reaction of Allyl Aryl Ketones to Activated Acyclic Ketones

(2016) Zhenzhong Jing et al.   ORGANIC LETTERS

Melohemsines A-I, melodinus-type alkaloids from Melodinus hemsleyanus

(2016) Jian Zhang et al.   RSC Advances

Asymmetric Organocatalysis Combined with Metal Catalysis: Concept, Proof of Concept, and Beyond

(2014) Dian-Feng Chen et al.   ACCOUNTS OF CHEMICAL RESEARCH

Chiral Counteranion Strategy for Asymmetric Oxidative C(sp3)H/C(sp3)H Coupling: Enantioselective α-Allylation of Aldehydes with Terminal Alkenes

(2014) Pu-Sheng Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Direct enantioselective vinylogous aldol–cyclization cascade reaction of allyl pyrazoleamides with isatins: asymmetric construction of spirocyclic oxindole–dihydropyranones

(2014) Tian-Ze Li et al.   CHEMICAL COMMUNICATIONS

General Allylic C–H Alkylation with Tertiary Nucleophiles

(2014) Jennifer M. Howell et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

The vinylogous Mukaiyama aldol reaction (VMAR) in natural product synthesis

(2014) Markus Kalesse et al.   NATURAL PRODUCT REPORTS

Asymmetric Direct Vinylogous Michael Additions of Allyl Alkyl Ketones to Maleimides through Dienamine Catalysis

(2014) Gu Zhan et al.   ORGANIC LETTERS

Trienamine catalysis with linear deconjugated 3,5-dienones

(2014) Peng-Qiao Chen et al.   Organic Chemistry Frontiers

Amino Acid-Derived Phosphonium Salts-Catalyzed Michael Addition of 3-Substituted Oxindoles

(2013) Xiaoyu Wu et al.   ADVANCED SYNTHESIS & CATALYSIS

Trienamines Derived from Interrupted Cyclic 2,5-Dienones: Remote δ,ε-CC Bond Activation for Asymmetric Inverse-Electron-Demand Aza-Diels-Alder Reaction

(2013) Xin Feng et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Direct Asymmetric Vinylogous Aldol Reaction of Allyl Ketones with Isatins: Divergent Synthesis of 3-Hydroxy-2-Oxindole Derivatives

(2013) Bo Zhu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Ligand-controlled E/Z selectivity and enantioselectivity in palladium-catalyzed allylation of benzofuranones with 1,2-disubstituted allylic carbonates

(2013) Kohsuke Ohmatsu et al.   CHEMICAL COMMUNICATIONS

Conformationally Constrained ortho-Anilino Diaryl Ureas: Discovery of 1-(2-(1′-Neopentylspiro[indoline-3,4′-piperidine]-1-yl)phenyl)-3-(4-(trifluoromethoxy)phenyl)urea, a Potent, Selective, and Bioavailable P2Y1 Antagonist

(2013) Jennifer X. Qiao et al.   JOURNAL OF MEDICINAL CHEMISTRY

Catalytic Direct β-Arylation of Simple Ketones with Aryl Iodides

(2013) Zhongxing Huang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iridium-catalyzed regiospecific and stereospecific allylic amination for the syntheses of α,β-unsaturated γ-amino esters and the bifurcation of the reaction pathway leading to the formation of oxazolidin-2-ones

(2013) Jun Hee Lee et al.   Chemical Science

Palladium-Catalyzed Enantioselective Allylic Alkylations through C-H Activation

(2012) Barry M. Trost et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Combining transition metal catalysis and organocatalysis – an update

(2012) Zhenting Du et al.   CHEMICAL SOCIETY REVIEWS

Palladium-Catalyzed Saegusa–Ito Oxidation: Synthesis of α,β-Unsaturated Carbonyl Compounds from Trimethylsilyl Enol Ethers

(2012) Yingdong Lu et al.   JOURNAL OF ORGANIC CHEMISTRY

Exploiting the Modularity of Ion-Paired Chiral Ligands for Palladium-Catalyzed Enantioselective Allylation of Benzofuran-2(3H)-ones

(2012) Kohsuke Ohmatsu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Organocatalytic Asymmetric Vinylogous Aldol Reactions

(2012) Vishnumaya Bisai   SYNTHESIS-STUTTGART

The Vinylogous Aldol and Related Addition Reactions: Ten Years of Progress†

(2011) Giovanni Casiraghi et al.   CHEMICAL REVIEWS

Synthesis of Cyclic Enones via Direct Palladium-Catalyzed Aerobic Dehydrogenation of Ketones

(2011) Tianning Diao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

General palladium-catalyzed aerobic dehydrogenation to generate double bonds

(2011) Weiming Gao et al.   Chemical Science

When Organocatalysis Meets Transition-Metal Catalysis

(2010) Cheng Zhong et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Pyrrolidinoindoline Alkaloids fromSelaginella moellendorfii

(2009) Yue-Hu Wang et al.   JOURNAL OF NATURAL PRODUCTS

Direct Catalytic Asymmetric Addition of Allyl Cyanide to Ketones

(2009) Ryo Yazaki et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY