Visible light-induced direct α C–H functionalization of alcohols

Selective Hydrogen Atom Abstraction through Induced Bond Polarization: Direct α-Arylation of Alcohols through Photoredox, HAT, and Nickel Catalysis

(2018) Jack Twilton et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Tertiary-Alcohol-Directed Functionalization of Remote C(sp3 )−H Bonds by Sequential Hydrogen Atom and Heteroaryl Migrations

(2018) Xinxin Wu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Selectfluor-mediated regioselective nucleophilic functionalization of N-heterocycles under metal- and base-free conditions

(2018) Long-Yong Xie et al.   GREEN CHEMISTRY

δ-Selective Functionalization of Alkanols Enabled by Visible-Light-Induced Ligand-to-Metal Charge Transfer

(2018) Anhua Hu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Silver-catalyzed remote Csp3-H functionalization of aliphatic alcohols

(2018) Yuchao Zhu et al.   Nature Communications

Metal-free alcohol-directed regioselective heteroarylation of remote unactivated C(sp3)–H bonds

(2018) Xinxin Wu et al.   Nature Communications

Total Synthesis of Lycopodium Alkaloids Palhinine A and Palhinine D

(2017) Fang-Xin Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Electrocatalytic Radical Dichlorination of Alkenes with Nucleophilic Chlorine Sources

(2017) Niankai Fu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Exploring the Reducing Ability of Organic Dye (Acr+-Mes) for Fluorination and Oxidation of Benzylic C(sp3)–H Bonds under Visible Light Irradiation

(2017) Ming Xiang et al.   ORGANIC LETTERS

The photochemical alkylation and reduction of heteroarenes

(2017) T. McCallum et al.   Chemical Science

Ketones as directing groups in photocatalytic sp3 C–H fluorination

(2017) Desta Doro Bume et al.   Chemical Science

Simple and Clean Photo-induced Methylation of Heteroarenes with MeOH

(2017) Wenbo Liu et al.   Chem

Recent Advances of Oxidative Radical Cross-Coupling Reactions: Direct α-C(sp3)-H Bond Functionalization of Ethers and Alcohols

(2016) Sheng-rong Guo et al.   ADVANCED SYNTHESIS & CATALYSIS

Nickel-Catalyzed Esterification of Aliphatic Amides

(2016) Liana Hie et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Photocatalytic Dehydrogenative Cross-Coupling of Alkenes with Alcohols or Azoles without External Oxidant

(2016) Hong Yi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Carbon–Carbon Bond Forming Reactions via Photogenerated Intermediates

(2016) Davide Ravelli et al.   CHEMICAL REVIEWS

Organic Photoredox Catalysis

(2016) Nathan A. Romero et al.   CHEMICAL REVIEWS

Copper-Catalyzed Alkoxycarbonylation of Alkanes with Alcohols

(2016) Yahui Li et al.   ChemSusChem

Cu-Catalyzed Sequential Dehydrogenation–Conjugate Addition for β-Functionalization of Saturated Ketones: Scope and Mechanism

(2016) Xiaoming Jie et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Metal-Free, Visible Light-Photocatalyzed Synthesis of Benzo[b]phosphole Oxides: Synthetic and Mechanistic Investigations

(2016) Valentin Quint et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Free-Radical Triggered Ordered Domino Reaction: An Approach to C–C Bond Formation via Selective Functionalization of α-Hydroxyl-(sp3)C–H in Fluorinated Alcohols

(2016) Zhengbao Xu et al.   ORGANIC LETTERS

Persulfate-Enabled Direct C–H Alkylation of Heteroarenes with Unactivated Ethers

(2016) Louis Barriault et al.   SYNLETT

Copper-Catalyzed Hydroxyl-Directed Aminoarylation of Alkynes

(2016) Jiaqiong Sun et al.   ACS Catalysis

Development of a Rhodium(II)-Catalyzed Chemoselective C(sp3)H Oxygenation

(2015) Yun Lin et al.   CHEMISTRY-A EUROPEAN JOURNAL

Ni-Catalyzed Regioselective Hydrocarboxylation of Alkynes with CO2 by Using Simple Alcohols as Proton Sources

(2015) Xueqiang Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Stereoselective Synthesis of Chiral β-Fluoro α-Amino Acids via Pd(II)-Catalyzed Fluorination of Unactivated Methylene C(sp3)–H Bonds: Scope and Mechanistic Studies

(2015) Qi Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Alcohols as alkylating agents in heteroarene C–H functionalization

(2015) Jian Jin et al.   NATURE

Radical Mediated C–H Functionalization of 3,6-Dichloropyridazine: Efficient Access to Novel Tetrahydropyridopyridazines

(2015) Timothy D. Neubert et al.   ORGANIC LETTERS

Metal-Free Oxidative Functionalization of C(sp3)–H Bond Adjacent to Oxygen and Radical Addition to Olefins

(2015) Wei Zhou et al.   ORGANIC LETTERS

O-H hydrogen bonding promotes H-atom transfer from   C-H bonds for C-alkylation of alcohols

(2015) J. L. Jeffrey et al.   SCIENCE

Recent Advances of Transition-Metal Catalyzed Radical Oxidative Cross-Couplings

(2014) Chao Liu et al.   ACCOUNTS OF CHEMICAL RESEARCH

Direct α-Arylation of Ethers through the Combination of Photoredox-Mediated CH Functionalization and the Minisci Reaction

(2014) Jian Jin et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Direct, Catalytic Monofluorination of sp3 C–H Bonds: A Radical-Based Mechanism with Ionic Selectivity

(2014) Cody Ross Pitts et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper- and Cobalt-Catalyzed Direct Coupling of sp3 α-Carbon of Alcohols with Alkenes and Hydroperoxides

(2014) Jun-Kee Cheng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Alkylations and Hydroxymethylations of Pyrazines via Green Minisci-Type Reactions

(2014) Bjorn Bohman et al.   ORGANIC LETTERS

A Free Radical Cascade Cyclization of Isocyanides with Simple Alkanes and Alcohols

(2014) Zejiang Li et al.   ORGANIC LETTERS

The Photocatalyzed Meerwein Arylation: Classic Reaction of Aryl Diazonium Salts in a New Light

(2013) Durga Prasad Hari et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Metal-free oxidative hydroxyalkylarylation of activated alkenes by direct sp3 C–H functionalization of alcohols

(2013) Yuan Meng et al.   CHEMICAL COMMUNICATIONS

Visible Light Photoredox Catalysis with Transition Metal Complexes: Applications in Organic Synthesis

(2013) Christopher K. Prier et al.   CHEMICAL REVIEWS

Multifold Bond Cleavage and Formation between MeOH and Quinoxalines (or Benzothiazoles): Synthesis of Carbaldehyde Dimethyl Acetals

(2013) Yunkui Liu et al.   JOURNAL OF ORGANIC CHEMISTRY

Visible-Light-Induced Oxygenation of Benzene by the Triplet Excited State of 2,3-Dichloro-5,6-dicyano-p-benzoquinone

(2013) Kei Ohkubo et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Visible Light-Promoted Metal-Free C–H Activation: Diarylketone-Catalyzed Selective Benzylic Mono- and Difluorination

(2013) Ji-Bao Xia et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Selective Oxidation of Alcohols to Esters Using Heterogeneous Co3O4–N@C Catalysts under Mild Conditions

(2013) Rajenahally V. Jagadeesh et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Visible-Light Photoredox Catalysis

(2012) Jun Xuan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A General and Efficient Zinc-Catalyzed Oxidation of Benzyl Alcohols to Aldehydes and Esters

(2012) Xiao-Feng Wu   CHEMISTRY-A EUROPEAN JOURNAL

Fluorine Transfer to Alkyl Radicals

(2012) Montserrat Rueda-Becerril et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Silver-Catalyzed Decarboxylative Fluorination of Aliphatic Carboxylic Acids in Aqueous Solution

(2012) Feng Yin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-catalyzed decarboxylative alkenylation of sp3 C–H bonds with cinnamic acids via a radical process

(2012) Zili Cui et al.   Chemical Science

Palladium-Catalyzed Aerobic Oxidative Direct Esterification of Alcohols

(2011) Chao Liu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Direct Sp3α-C–H activation and functionalization of alcohol and ether

(2011) Shu-Yu Zhang et al.   CHEMICAL SOCIETY REVIEWS

Palladium-Catalyzed Minisci Reaction with Simple Alcohols

(2011) Camille A. Correia et al.   ORGANIC LETTERS

Direct C2-Alkylation of Azoles with Alcohols and Ethers through Dehydrogenative Cross-Coupling under Metal-Free Conditions

(2011) Tao He et al.   ORGANIC LETTERS

Minisci reactions: Versatile CH-functionalizations for medicinal chemists

(2011) Matthew A. J. Duncton   MedChemComm

Visible light photoredox catalysis: applications in organic synthesis

(2010) Jagan M. R. Narayanam et al.   CHEMICAL SOCIETY REVIEWS

Visible light photocatalysis as a greener approach to photochemical synthesis

(2010) Tehshik P. Yoon et al.   Nature Chemistry

Stereoselective VO(acac)2 catalyzed epoxidation of acyclic homoallylic diols. Complementary preparation of C2-syn-3,4-epoxy alcohols

(2010) Raúl R. Rodríguez-Berríos et al.   TETRAHEDRON

Iron-Catalyzed C(sp3)C(sp3) Bond Formation through C(sp3)H Functionalization: A Cross-Coupling Reaction of Alcohols with Alkenes

(2009) Shu-Yu Zhang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Chemoselective Chemical and Electrochemical Deprotections of Aromatic Esters

(2009) Kevin Lam et al.   ORGANIC LETTERS

Iridium-Catalyzed Coupling Reaction of Primary Alcohols with 1-Aryl-1-propynes Leading to Secondary Homoallylic Alcohols

(2009) Yasushi Obora et al.   ORGANIC LETTERS

Free-Radical-Initiated Coupling Reaction of Alcohols and Alkynes: Not C−O but C−C Bond Formation

(2009) Zhong-Quan Liu et al.   ORGANIC LETTERS