Article
Polymer Science
Behnam Eslami, Ismaeil Ghasemi, Masoud Esfandeh
Summary: Solid polymer electrolytes (SPEs) are a promising avenue for flexible lithium-ion batteries. However, the low ionic conductivity of polymers remains a challenge. In this study, SPE/FGO electrolytes were prepared using PEO, polyvinyl alcohol, LiClO4, and graphene functionalized with polyethylene glycol. The presence of functionalized graphene effectively reduced crystallinity, and the samples exhibited adequate ionic conductivity at room temperature.
Article
Chemistry, Physical
Elham Aram, Hanieh Shaki, Morteza Ehsani
Summary: High-performance gel polymer electrolytes based on PEO/PMMA incorporating different weight percentage of GO nanosheets were prepared, and the addition of GO increased the ionic conductivity and thermal properties of the electrolytes. The optimized polymer gel electrolyte, containing 1 wt% GO, showed a higher photon conversion efficiency of 6.98%, compared to the neat PEO/PMMA gel electrolyte (4.92%). The presence of GO also increased the charge recombination resistance and long-term stability of the gel electrolyte.
Article
Materials Science, Multidisciplinary
Recep Bakar, Saeid Darvishi, Tianyu Li, Mertcan Han, Umut Aydemir, Sedat Nizamoglu, Kunlun Hong, Erkan Senses
Summary: The use of nonlinear PEO in PEO/PMMA blends leads to a significant increase in their ionic conductivity by enhancing the decoupling of PMMA and PEO segmental dynamics, ultimately improving the performance of the electrolytes. Macromolecular architecture can serve as a tool to decouple segmental dynamics and ion mobility, allowing for the rational design of SPEs with improved performance.
ACS APPLIED POLYMER MATERIALS
(2022)
Article
Chemistry, Physical
Boyang Huang, Pengbin Lai, Haiming Hua, Ruiyang Li, Xiu Shen, Xueying Yang, Peng Zhang, Jinbao Zhao
Summary: In this paper, a low molecular weight polyether poly (EO-co-PCGE) (PECP) is synthesized and blended with PEO-based solid polymer electrolyte (SPE) to improve its ionic conductivity. The introduction of low molecular weight and cyclic carbonate pendant in the PEO matrix reduces crystallinity and affects the conduction mechanism, significantly increasing the lithium-ion transference number. The prepared PEO-based SPE exhibits excellent ionic conduction properties, especially at room temperature, and enables LiFePO4/Li batteries to have excellent cycling performance at 40 degrees C.
JOURNAL OF POWER SOURCES
(2023)
Article
Chemistry, Physical
S. Abdollahi, H. Sadadi, M. Ehsani, E. Aram
Summary: The study demonstrated that incorporating a small amount of graphene oxide into polymer electrolyte can effectively improve the electrical conductivity of the fibrous membrane, while reducing fiber diameter and crystallinity of polymer matrix. The resulting nanocomposite membrane showed high ionic conductivity and porosity, making it a promising candidate for dye-sensitized solar cells.
Article
Materials Science, Multidisciplinary
A. M. S. Nurhaziqah, M. K. Ahmad, A. B. Faridah, D. G. Saputri, S. A. Ramli, M. H. Mamat, M. Shimomura
Summary: This research aims to improve the conductivity of a polymer blend with quasi solid state electrolyte by selecting target polymers, PMMA and PVdF, and analyzing their ratio, electrical impedance spectroscopy (EIS) and thermogravimetric analysis (TGA). The optimum conductivity value was found to be 3.44 x 10-6 Scm-1 at ambient temperature with a PMMA:PVdF ratio of 70:30. The analysis also showed that conductivity increases with temperature and has low activation energy (Ea). Additionally, the TGA demonstrated the stability of PBE up to 651 degrees C. Different concentrations of PBE were investigated to assess its stability and conductivity performance.
Review
Chemistry, Multidisciplinary
Shuailei Liu, Wenyi Liu, Deliang Ba, Yongzhi Zhao, Yihua Ye, Yuanyuan Li, Jinping Liu
Summary: This review discusses the role of fillers in composite polymer electrolytes (CPEs) and their impact on the performance of solid-state lithium batteries. The article focuses on the crucial influence of filler size, concentration, and hybridization strategies on the filler-polymer interface, as well as the latest advances in filler-enabled in situ generation of a Li+-conductive layer. The review also provides insights into the future development and challenges of advanced CPEs for high-performing SSLBs.
ADVANCED MATERIALS
(2023)
Article
Polymer Science
P. Muthumari, S. Thangarasu, S. Asath Bahadur
Summary: Proton conducting polymer blend electrolytes were prepared using PVC, PMMA, NH4SCN salt, and THF as solvent, and their complexation, amorphousness, and ionic conductivity were studied through FTIR spectroscopy, XRD analysis, and AC impedance spectroscopy. The highest ionic conductivity was achieved in the PVC/PMMA/NH4SCN blend system, indicating ion conduction through relaxation dynamics.
JOURNAL OF POLYMER RESEARCH
(2021)
Article
Polymer Science
Venkata Ramana Jeedi, Kiran Kumar Ganta, Yalla Mallaiah, R. Swarnalatha, S. Narender Reddy, A. Sadananda Chary
Summary: The addition of succinonitrile to the blend polymer electrolyte membranes enhances the ionic conductivity, with the maximum ionic conductivity achieved at 12wt%. The temperature-dependent ionic conductivity follows Arrhenius relation, indicating increased ion dissociation and greater number of charge carriers for ion transport. Wagner's method is used to investigate the transference number.
JOURNAL OF POLYMER RESEARCH
(2022)
Article
Materials Science, Paper & Wood
Pradeep Nayak, Y. N. Sudhakar, Shounak De, Supriya K. Ismayil, Supriya Shetty, Vipin Cyriac
Summary: Different weight percentages of Mg(NO3)(2) were added to a polymer blend of chitosan (CS) and methylcellulose (MC) using the solution casting method. Interactions between the blend and Mg(NO3)(2) salt were observed through FTIR analysis. The polymer electrolyte films exhibited amorphous structure and their bulk resistance decreased with increasing salt content, resulting in improved electrical conductivity and stability. This eco-friendly and practical electrolyte shows great potential for electrochemical devices.
Article
Electrochemistry
Seyedeh Nooshin Banitaba, Dariush Semnani, Mohammad Karimi, Elahe Heydari-Soureshjani, Behzad Rezaei, Ali A. Ensafi
Summary: Solvent-free polymer electrolytes were prepared using electrospinning and solution casting techniques. Finer fibers were shown to enhance crystalline regions and free lithium ions. Nanofibrous mats had higher ionic conductivity, while solution-casted ones had higher resistance.
ELECTROCHIMICA ACTA
(2021)
Article
Chemistry, Physical
Dan-il Yoon, Nishad Mulay, Jericko Baltazar, Dang Khoa Cao, Valeria Perez, Johanna Nelson Weker, Min Hwan Lee, Robert D. Miller, Dahyun Oh, Sang-Joon John Lee
Summary: Repetitive mechanical stresses can significantly alter the performance of composite polymer electrolytes (CPEs), which may contribute to the degradation of all-solid-state batteries.
ACS APPLIED ENERGY MATERIALS
(2023)
Article
Nanoscience & Nanotechnology
Dheeraj Kumar Maurya, Ragupathy Dhanusuraman, John Zhanhu Guo, Subramania Angaiah
Summary: In this study, a nanofillers-reinforced 3D-electrospun nanofibrous hybrid polymer membrane (ESHPM) was prepared by electrospinning technique to overcome the challenges of poor thermal stability and low ionic conductivity in an electrolyte. The ESHPM exhibited excellent properties such as morphology, porosity, crystallinity, thermal stability, dimensional stability, operating potential window, and ionic conductivity. This research offers a potential solution for developing high-performing sodium-ion capacitors (NICs) with high energy and power densities.
ADVANCED COMPOSITES AND HYBRID MATERIALS
(2023)
Article
Chemistry, Physical
X. Song, T. H. Zhang, R. Z. Fan, J. Biao, S. H. Huang, J. Travas-Sejdic, W. Gao, P. Cao
Summary: In this work, a composite solid-state electrolyte (CSSE) was developed by blending highly ionically conductive LLZTNO fillers with a poly(ethylene oxide) matrix. The LLZTNO fillers decreased the crystallinity of the PEO and provided additional pathways for lithium-ion transport. The CSSE exhibited improved ionic conductivity due to the immobilization of TFSI- anions and increased mobility of Li ions. The PEO-LiTFSI-10% LLZTNO CSSE showed the highest conductivity and a wide voltage window. Symmetric cells using the CSSE demonstrated long-term stability, and solid-state LFP/PL-LLZTNO10%/Li cells showed good performance at elevated temperatures.
SOLID STATE IONICS
(2023)
Article
Engineering, Electrical & Electronic
Harshlata Verma, Kuldeep Mishra, D. K. Rai
Summary: A study was conducted on a porous PMMA/PVDF blend-based gel polymer electrolyte, showing high ion conductivity and electrochemical stability. The optimized membrane in a prototype battery demonstrated high discharge capacity and low electrolyte leakage rate.
JOURNAL OF ELECTRONIC MATERIALS
(2022)