Reaction of Nitrogen-Radicals with Organometallics Under Ni-Catalysis: N-Arylations and Amino-Functionalization Cascades

Recent advances in radical-based C–N bond formation via photo-/electrochemistry

(2018) Yating Zhao et al.   CHEMICAL SOCIETY REVIEWS

Hydroxylamine Derivatives as Nitrogen-Radical Precursors in Visible-Light Photochemistry

(2018) Jacob Davies et al.   CHEMISTRY-A EUROPEAN JOURNAL

Long-Lived Charge-Transfer States of Nickel(II) Aryl Halide Complexes Facilitate Bimolecular Photoinduced Electron Transfer

(2018) Benjamin J. Shields et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Remote C–H Functionalization via Selective Hydrogen Atom Transfer

(2018) David Nagib et al.   SYNTHESIS-STUTTGART

Photoredox-catalyzed C(sp 2 )–N coupling reactions

(2018) Xiao-De An et al.   TETRAHEDRON LETTERS

Copper-Catalyzed Radical Cross-Coupling of Redox-Active Oxime Esters, Styrenes, and Boronic Acids

(2018) Xiao-Ye Yu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Spectroscopic Studies of the Chan–Lam Amination: A Mechanism-Inspired Solution to Boronic Ester Reactivity

(2017) Julien C. Vantourout et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Site-Selective Copper-Catalyzed Amination and Azidation of Arenes and Heteroarenes via Deprotonative Zincation

(2017) Charles E. Hendrick et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nickel-Catalyzed 1,2-Aminoarylation of Oxime Ester-Tethered Alkenes with Boronic Acids

(2017) Hai-Bin Yang et al.   ACS Catalysis

Photochemical Generation of Nitrogen-Centered Amidyl, Hydrazonyl, and Imidyl Radicals: Methodology Developments and Catalytic Applications

(2017) Markus D. Kärkäs   ACS Catalysis

The merger of transition metal and photocatalysis

(2017) Jack Twilton et al.   Nature Reviews Chemistry

Highly Chemoselective Iridium Photoredox and Nickel Catalysis for the Cross-Coupling of Primary Aryl Amines with Aryl Halides

(2016) Martins S. Oderinde et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Visible light photoredox-controlled reactions of N-radicals and radical ions

(2016) Jia-Rong Chen et al.   CHEMICAL SOCIETY REVIEWS

Visible-Light-Mediated Synthesis of Amidyl Radicals: Transition-Metal-Free Hydroamination and N-Arylation Reactions

(2016) Jacob Davies et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Visible-Light-Mediated Generation of Nitrogen-Centered Radicals: Metal-Free Hydroimination and Iminohydroxylation Cyclization Reactions

(2015) Jacob Davies et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Nickel-Catalyzed Cross-Coupling of Photoredox-Generated Radicals: Uncovering a General Manifold for Stereoconvergence in Nickel-Catalyzed Cross-Couplings

(2015) Osvaldo Gutierrez et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Transition-metal free umpolung carbon–nitrogen versus carbon–chlorine bond formation

(2015) John J. Sirois et al.   TETRAHEDRON LETTERS

Nickel: The “Spirited Horse” of Transition Metal Catalysis

(2015) Valentine P. Ananikov   ACS Catalysis

Rings in Drugs

(2014) Richard D. Taylor et al.   JOURNAL OF MEDICINAL CHEMISTRY

Analysis of the Structural Diversity, Substitution Patterns, and Frequency of Nitrogen Heterocycles among U.S. FDA Approved Pharmaceuticals

(2014) Edon Vitaku et al.   JOURNAL OF MEDICINAL CHEMISTRY

Recent advances in homogeneous nickel catalysis

(2014) Sarah Z. Tasker et al.   NATURE

Copper catalyzed Heck-like cyclizations of oxime esters

(2014) Adele Faulkner et al.   Chemical Science

Visible Light Photoredox Catalysis with Transition Metal Complexes: Applications in Organic Synthesis

(2013) Christopher K. Prier et al.   CHEMICAL REVIEWS

Cobalt-Catalyzed Electrophilic Amination of Arylzincs withN-Chloroamines

(2013) Xin Qian et al.   CHEMISTRY-A EUROPEAN JOURNAL

Copper-Catalyzed Electrophilic Amination of Organolithiums Mediated by Recoverable Siloxane Transfer Agents

(2013) Minh H. Nguyen et al.   ORGANIC LETTERS

Synthesis of Hindered Anilines: Copper-Catalyzed Electrophilic Amination of Aryl Boronic Esters

(2012) Richard P. Rucker et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Elusive Metal-Free Primary Amination of Arylboronic Acids: Synthetic Studies and Mechanism by Density Functional Theory

(2012) Chen Zhu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Transition-Metal-Free Electrophilic Amination of Arylboroxines

(2012) Qing Xiao et al.   ORGANIC LETTERS

Copper-Catalyzed Electrophilic Amination of Arylsilanes with Hydroxylamines

(2012) Yuya Miki et al.   ORGANIC LETTERS

Copper Catalyzed N-Arylation of Amidines with Aryl Boronic Acids and One-Pot Synthesis of Benzimidazoles by a Chan–Lam–Evans N-Arylation and C–H Activation/C–N Bond Forming Process

(2012) Jihui Li et al.   ORGANIC LETTERS

Recent Developments in Palladium-Catalyzed Alkene Aminoarylation Reactions for the Synthesis of Nitrogen Heterocycles

(2012) John Wolfe et al.   SYNTHESIS-STUTTGART

Transition-Metal-Free Electrophilic Amination between Aryl Grignard Reagents andN-Chloroamines

(2010) Takuji Hatakeyama et al.   ORGANIC LETTERS

Sex-Related Differences in Alkaloid Chemical Defenses of the Dendrobatid FrogOophaga pumiliofrom Cayo Nancy, Bocas del Toro, Panama⊥

(2009) Ralph A. Saporito et al.   JOURNAL OF NATURAL PRODUCTS

Umpolung Amination: Nickel-Catalyzed Coupling Reactions ofN,N-Dialkyl-N-chloroamines with Diorganozinc Reagents

(2009) Timothy J. Barker et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Aryl Halide Tolerated Electrophilic Amination of Arylboronic Acids withN-Chloroamides Catalyzed by CuCl at Room Temperature

(2008) Chuan He et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Recent progress in the generation and use of nitrogen-centred radicals

(2008) Samir Z. Zard   CHEMICAL SOCIETY REVIEWS

Why Does Fluoride Anion Accelerate Transmetalation between Vinylsilane and Palladium(II)−Vinyl Complex? Theoretical Study

(2008) Akihiro Sugiyama et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY