Article
Chemistry, Physical
Yoonho Ahn, Jong Yeog Son
Summary: Epitaxial BTO/PTO multilayer thin films exhibit ferroelectric polarization switching characteristics with an imprint phenomenon, which can be utilized for developing high-density ferroelectric-based storage media.
JOURNAL OF ALLOYS AND COMPOUNDS
(2022)
Article
Chemistry, Multidisciplinary
Ran Ding, Yongxin Lyu, Zehan Wu, Feng Guo, Weng Fu Io, Sin-Yi Pang, Yuqian Zhao, Jianfeng Mao, Man-Chung Wong, Jianhua Hao
Summary: 2D hybrid perovskite ferroelectrics, such as EA(4)Pb(3)Br(10) SCFs, exhibit in-plane multiaxial ferroelectricity and effective piezoelectric coefficient, showing great potential for enhancing photodetector performance through the observation of the piezo-phototronic effect. Under external strains, the responsivity of flexible photodetectors based on EA(4)Pb(3)Br(10) SCFs can be remarkably enhanced by up to 284%. These findings shed light on piezo-phototronic devices and offer a promising avenue to broaden functionalities of hybrid perovskite ferroelectrics.
ADVANCED MATERIALS
(2021)
Article
Chemistry, Physical
Xingchen Zhang, Hongying Chen, Guo Tian, Wenda Yang, Zhen Fan, Zhipeng Hou, Deyang Chen, Min Zeng, Minghui Qin, Jinwei Gao, Xingsen Gao, Jun -Ming Liu
Summary: We have successfully achieved controllable creation and erasure of polar bubble states in PbTiO3 (PTO) multilayers triggered by mechanical stress and light illumination. Applying AFM tip force induced the formation of nanoscale bubble domains from the initial monodomain state, while ultraviolet or infrared light illumination eliminated the created bubble domains. These results can be explained by the modulation of depolarization screening charges and bias fields, and provide a good example for the multi-field manipulation of polar topologies.
JOURNAL OF MATERIOMICS
(2023)
Article
Engineering, Electrical & Electronic
Jihwan Jeong, Junsik Mun, Saikat Das, Jinkwon Kim, Jeong Rae Kim, Wei Peng, Miyoung Kim, Tae Won Noh
Summary: In this study, BWO thin films were grown on substrates using pulsed laser deposition, with the ferroelectric properties characterized using STEM and PFM techniques. It was found that the oxygen gas pressure during growth mainly determined the phase stability of the films, while the growth temperature had a minor influence. Atomically resolved STEM study revealed a collective in-plane polar off-centering displacement of W atoms, with the estimated spontaneous polarization value in good agreement with the bulk value. The study also identified the presence of type-I and type-II domains in the pristine film, forming a multidomain state.
ACS APPLIED ELECTRONIC MATERIALS
(2021)
Article
Materials Science, Ceramics
Hyun Wook Shin, Jong Yeog Son
Summary: In this study, the ferroelectric switching and current characteristics of BFO nanocubes were investigated, revealing their potential as storage media for ferroelectric polarization information.
CERAMICS INTERNATIONAL
(2022)
Article
Chemistry, Multidisciplinary
Swati Deswal, Rishukumar Panday, Dipti R. Naphade, Pierre-Andre Cazade, Sarah Guerin, Jan K. Zareba, Alexander Steiner, Satishchandra Ogale, Thomas D. Anthopoulos, Ramamoorthy Boomishankar
Summary: Cyclophosphazenes have been found to be a versatile platform for various functional systems, and this study reports the first supramolecular ferroelectric compound based on an organophosphazene. The compound exhibits multiaxial polarization and shows potential for piezoelectric energy harvesting applications. The high performance of the compound is attributed to the flexible layered supramolecular assembly, which allows for mechanical stress-induced distortions.
Article
Chemistry, Multidisciplinary
Song Zhou, Lei Liao, Lan Chen, Baojie Feng, Xiaoyue He, Xuedong Bai, Chuangye Song, Kehui Wu
Summary: This study demonstrates the possibility of maintaining stable in-plane polarization in an extremely thin Bi2WO6 film by using a perfectly lattice-matched NdGaO3 (110) substrate. The residual polarization in this ultrathin film is attributed to the crystal stability of the Bi-O octahedral framework against structural distortions. These findings suggest the potential of the Bi2WO6/NdGaO3 (110) system as a platform for designing low-energy consumption, nonvolatile ferroelectric memories.
Article
Chemistry, Multidisciplinary
Yongtao Liu, Anna N. Morozovska, Ayana Ghosh, Kyle P. Kelley, Eugene A. Eliseev, Jinyuan Yao, Ying Liu, Sergei Kalinin
Summary: In this study, the local curvature and strain effects on polarization in CIPS were investigated using piezoresponse force microscopy and spectroscopy. The finite element Landau-Ginzburg-Devonshire model was introduced to explain the observed behaviors and decouple the curvature and strain effects in 2D CIPS. The results showed that bending induced ferrielectric domains in CIPS and the polarization-voltage hysteresis loops differed in bending and nonbending regions. These studies provide important insights into the fabrication of curvature-engineered nanoelectronic devices.
Article
Chemistry, Multidisciplinary
Yongtao Liu, Patrick Trimby, Liam Collins, Mahshid Ahmadi, Aimo Winkelmann, Roger Proksch, Olga S. Ovchinnikova
Summary: Metal halide perovskite (MHP) solar cells have gained global attention in research. Understanding the crystal orientation and ferroic properties of MHP twin stripes is essential to comprehend the impact of ferroic behavior on the optoelectronic properties. Investigating these aspects provides insight into the influence of subgrain structures in MHPs.
Article
Materials Science, Ceramics
Ruoyu Wang, Yixiao Jiang, Neng He, Xiang Li, Tingting Yao, Limei Zheng, Chunlin Chen, Lianlong He, Hengqiang Ye
Summary: This study systematically investigates the ferroelectric domain structure and atomic-scale phase distribution in lead-based relaxor ferroelectric crystals, revealing the differences in ferroelectric properties of different phases at the nanoscale.
CERAMICS INTERNATIONAL
(2022)
Article
Computer Science, Artificial Intelligence
N. Creange, K. P. Kelley, C. Smith, D. Sando, O. Paull, N. Valanoor, S. Somnath, S. Jesse, S. Kalinin, R. K. Vasudevan
Summary: Multi-dimensional spectral-imaging is essential in various microscopies and chemical imaging techniques, where utilizing spatial and spectral neighborhood information can significantly improve the reliability and speed of functional fits.
MACHINE LEARNING-SCIENCE AND TECHNOLOGY
(2021)
Article
Chemistry, Multidisciplinary
Ping Li, Apoorva Chaturvedi, Hailin Zhou, Gaojun Zhang, Qiankun Li, Jinshuo Xue, Ziwen Zhou, Shun Wang, Kun Zhou, Yuyan Weng, Fengang Zheng, Zhenwu Shi, Edwin Hang Tong Teo, Liang Fang, Lu You
Summary: Ferroelectric van der Waals (vdW) heterostructures combine the diversity of 2D materials with the memory nature of ferroelectrics, making them a low-power, versatile device paradigm. This study investigates the electrostatic coupling phenomena in vdW heterostructures and provides insight into the mutual electrostatic interactions, which has broad implications for ferroelectric field-effect applications.
ADVANCED FUNCTIONAL MATERIALS
(2022)
Article
Chemistry, Physical
Andre Marino Goncalves, Rolando Placeres Jimenez, Jose Antonio Eiras
Summary: This study investigated the role of domain structure and relative domain-electric field orientations in the polarization reorientation process in polycrystalline ferroelectric thin films by combining macroscopic and nanoscopic analyses. The results show that the relative polarization orientation of the domains significantly impacts the reorientation process, affecting the stability and efficiency of polarization switching. Through a phenomenological model, macroscopic parameters related to the polarization reorientation, domain structure, and domain wall mobility were obtained, allowing for a better understanding and explanation of the observed responses.
JOURNAL OF ALLOYS AND COMPOUNDS
(2021)
Article
Chemistry, Multidisciplinary
Yongtao Liu, Kyle P. Kelley, Rama K. Vasudevan, Wanlin Zhu, John Hayden, Jon-Paul Maria, Hiroshi Funakubo, Maxim A. Ziatdinov, Susan Trolier-McKinstry, Sergei Kalinin
Summary: An automated experiment is developed to investigate structural, chemical, and functional behaviors in complex materials and uncover the primary physical mechanisms that control device function. By exploring non-linear electromechanical responses in piezoresponse force microscopy (PFM), it is discovered that different materials exhibit different non-linear behavior patterns, and automated experiments have the potential to distinguish between competing physical mechanisms.
Article
Chemistry, Multidisciplinary
Sabine M. Neumayer, Nora Bauer, Sergey Basun, Benjamin S. Conner, Michael A. Susner, Maxim O. Lavrentovich, Petro Maksymovych
Summary: The polarization dynamics in ferroelectric materials depends on the potential energy landscape of the order parameter. Ferroelectrics have the unique property of having more than two potential wells, resulting in complex energy landscapes. In this study, the presence of a triple-well potential in the Sn2P2S6 compound was revealed using scanning probe microscopy and theoretical simulations. The metastable zero polarization state in Sn2P2S6 was accessed through a gradual switching process and was found to be stabilized over a wide range of electric fields. The observed zero polarization state originated from the kinetic stabilization of the nonpolar state of the triple-well.
ADVANCED MATERIALS
(2023)
Article
Multidisciplinary Sciences
Jing-Jing Xian, Cong Wang, Jin-Hua Nie, Rui Li, Mengjiao Han, Junhao Lin, Wen-Hao Zhang, Zhen-Yu Liu, Zhi-Mo Zhang, Mao-Peng Miao, Yangfan Yi, Shiwei Wu, Xiaodie Chen, Junbo Han, Zhengcai Xia, Wei Ji, Ying-Shuang Fu
Summary: Researchers have successfully fabricated monolayers of CrTe2 and demonstrated antiferromagnetic ordering with spin reorientation under finite magnetic fields. This study enriches our understanding of two-dimensional magnetic materials and provides a foundation for further analysis.
NATURE COMMUNICATIONS
(2022)
Article
Chemistry, Physical
Si-Rui Zhang, Mei-Xiong Zhu, Jagadeesh Suriyaprakash, Jin-Mei Liu, Tao Du, Yu-Jia Wang, Chang-Bai Long, Min Liao
Summary: The study reveals that different flux-closure domain structures can be easily created by controlling the thickness ratio of the bottom and top films. This finding opens up possibilities for creating and constructing novel nanoscale ferroelectric devices with exotic properties.
JOURNAL OF PHYSICAL CHEMISTRY C
(2022)
Article
Chemistry, Multidisciplinary
Wan-Rong Geng, Yun-Long Tang, Yin-Lian Zhu, Yu-Jia Wang, Bo Wu, Li-Xin Yang, Yan-Peng Feng, Min-Jie Zou, Tong-Tong Shi, Yi Cao, Xiu-Liang Ma
Summary: This study demonstrates the existence of multi-field-driven magnetoelectric-optical coupling mediated by ferroelastic switching at room temperature. It provides a framework for designing potential multifunctional magnetoelectric devices.
ADVANCED MATERIALS
(2022)
Review
Materials Science, Multidisciplinary
Y. J. Wang, Y. L. Tang, Y. L. Zhu, X. L. Ma
Summary: Ferroelectric crystals with switchable polar structures have potential applications in information storage. Nanoscale ferroelectrics exhibit various exotic domain configurations and polar topologies, which can result in high-density memory bits. However, stabilizing polar topologies in ferroelectric materials, especially in nanoscale, is a significant challenge due to the pronounced coupling between polarizations and spontaneous strains.
Article
Chemistry, Multidisciplinary
Kangdi Niu, Guotao Qiu, Chuanshou Wang, Daiyue Li, Yutao Niu, Songge Li, Lixing Kang, Yongqing Cai, Mengjiao Han, Junhao Lin
Summary: This study focuses on 2D magnetic heterojunctions which have attracted considerable interest due to their potential applications in spintronics. By using CrTe2 as the backbone framework and self-intercalated 2D chromium telluride (CrxTey), the researchers obtained various lateral and vertical magnetic heterojunctions. They demonstrated a Cr2Te3-Cr5Te8 lateral heterojunction prototype that can manipulate magnetic moments under different magnitudes of magnetic excitation, showing a sharply stepped hysteresis loop with a dual spin-flip transition at high Curie temperatures up to 150 and 210 K by magneto-optical Kerr measurement. The overall structural rigidity of chromium-telluride heterostructure with magnetic phase decoupled behaviors is promising for 2D spintronic devices.
ADVANCED FUNCTIONAL MATERIALS
(2023)
Article
Nanoscience & Nanotechnology
Jiaqi Liu, Yi Cao, Yun-Long Tang, Yin-Lian Zhu, Yujia Wang, Nan Liu, Min-Jie Zou, Tong-Tong Shi, Fang Liu, Fenghui Gong, Yan-Peng Feng, Xiu-Liang Ma
Summary: By using multiple nano-engineering, we have achieved room-temperature ferroelectricity in (SrTiO3)0.65/(CeO2)0.35 films. The CeO2 nanocolumns induce large out-of-plane strains and Sr/O deficiency in the SrTiO3 matrix, forming a clear tetragonal structure and resulting in an apparent room-temperature ferroelectric polarization of up to 2.5 mu C/cm2. Our work provides a pathway for architecting functional systems in perovskite oxides using multiple nano-design.
ACS APPLIED MATERIALS & INTERFACES
(2023)
Article
Nanoscience & Nanotechnology
Yi Cao, Yun-Long Tang, Yin-Lian Zhu, Yujia Wang, Nan Liu, Min-Jie Zou, Jiaqi Liu, Yan-Peng Feng, Wan-Rong Geng, Xiu-Liang Ma
Summary: This study reports a new type of single-phase multiferroic material in which high-temperature magnetism and voltage-switchable ferroelectricity are coupled. The material exhibits switchable ferroelectric properties and moderate magnetic interaction, with the magnetic order persisting even above 500 K, which is higher than previous potential multiferroic candidates. The strategy of merging a spin-ordered sublattice into inherent ferroelectrics via atomic occupancy engineering provides an available pathway for highly thermally stable multiferroic and spintronic applications.
ACS APPLIED MATERIALS & INTERFACES
(2023)
Article
Materials Science, Multidisciplinary
S. J. Chen, Y. L. Tang, F. H. Gong, J. H. Wang, X. D. Lv, R. J. Jiang, S. Z. Liu, Y. J. Wang, Y. L. Zhu, X. L. Ma
Summary: Strain engineering in low dimensional ferroelectrics has made significant progress in the discovery of various ferroelectric topologies. However, the difficulty in preparing high-quality single-crystal substrates has hindered the exploration of these structures. This study proposes a practical method to prepare REScO3 buffer layers using precision pulsed laser deposition and controlled post-annealing. The obtained PrScO3 films exhibit high quality, and periodic flux-closure arrays in PbTiO3 layers have been successfully achieved on the PrScO3-buffered SrTiO3 substrates.
Article
Materials Science, Multidisciplinary
D. Chen, Y. J. Wang, Y. L. Zhu, X. L. Ma
Summary: In this work, the effects of doping Fe and Cr ions on the Ne'el temperature in hexagonal YMnO3 were studied using first-principles calculations. It was found that the variations of electronic structures and the extents of orbital coupling overlaps play important roles in determining the magnetic interaction strength and Ne'el temperature for YMn1-x(Fe,Cr)xO3 (0 <= x < 0.3). Additionally, doping rare earth element (La) at the non-magnetic Y-site also influences the Ne'el temperature. These findings provide valuable insights into the performance of multiferroic materials.
COMPUTATIONAL MATERIALS SCIENCE
(2023)
Article
Chemistry, Multidisciplinary
Ru-Jian Jiang, Yi Cao, Wan-Rong Geng, Mei-Xiong Zhu, Yun-Long Tang, Yin-Lian Zhu, Yujia Wang, Fenghui Gong, Su-Zhen Liu, Yu-Ting Chen, Jiaqi Liu, Nan Liu, Jing-Hui Wang, Xiao-Dong Lv, Shuang-Jie Chen, Xiu-Liang Ma
Summary: Based on atomic-resolution transmission electron microscopy, the phase transition pathway and lattice details in lead zirconate thin films were elucidated. A new type of ferrielectric-like dipole configuration was discovered as a precursor for the antiferroelectric to ferroelectric transformation. The phase transition pathways driven by the phase boundary were revealed. This study provides new insights into the consecutive phase transformation in low-dimensional lead zirconate and promotes the development of potential antiferroelectric-based multifunctional devices.
Article
Chemistry, Multidisciplinary
Jia-Qi Liu, Yun-Long Tang, Yi Cao, Yin-Lian Zhu, Yu-Jia Wang, Nan Liu, Tong-Tong Shi, Min-Jie Zou, Yan-Peng Feng, Xiu-Liang Ma
Summary: By engineering oxygen vacancies, robust ferromagnetism with high Curie temperatures (TC) was achieved in stable and stoichiometric iron-zirconate perovskite oxide films. The presence of a mixture of Fe4+ and Fe3+ cations, mediated by the oxygen vacancies, was identified as the cause for the robust magnetism. This study suggests that spin-state ordering can be manipulated in simple perovskite oxides by engineering oxygen stoichiometry, opening up possibilities for future technological applications.
CELL REPORTS PHYSICAL SCIENCE
(2023)
Article
Materials Science, Multidisciplinary
S. Z. Liu, W. R. Geng, Y. L. Tang, Y. L. Zhu, Y. J. Wang, Y. Cao, R. J. Jiang, N. Liu, F. H. Gong, J. H. Wang, X. D. Lv, S. J. Chen, X. L. Ma
Summary: Tailoring ferroelectric-antiferroelectric phase transitions allows for strategic advantages in applications such as digital displacement transducers and ultrathin ferroelectric capacitors. By introducing antiferroelectric PbZrO3 layers into intrinsic ferroelectric BiFeO3 films, a dedicated control of the phase transition is achieved. The resulting modulated superlattice exhibits improved piezoelectric performance and enriches the understanding of structure-functionality correlations in oxide heterosystems.
Article
Multidisciplinary Sciences
Feng-Hui Gong, Yun-Long Tang, Yu-Jia Wang, Yu-Ting Chen, Bo Wu, Li-Xin Yang, Yin-Lian Zhu, Xiu-Liang Ma
Summary: The relationship between the period of polar skyrmions and the thickness of the PbTiO3 layer in superlattices follows a hyperbolic function, rather than the previously believed square root law. This study reveals the failure of the classical Kittel's law in the case of polar skyrmions and the persistence of skyrmions in ultrathin superlattices. The findings have important implications for the design of nanoscale ferroelectric devices in the post-Moore era.
NATURE COMMUNICATIONS
(2023)
Article
Physics, Applied
Zhong Fang, Xiang-Wei Guo, Heng Zhang, Yu-Jia Wang, Yun-Long Tang, Yin-Lian Zhu, Xiu-Liang Ma
Summary: The monoclinic phases of high-index-oriented PbTiO3 films can be modulated through anisotropic strain, resulting in significantly enhanced piezoelectric performance. This is mainly attributed to the polarization rotation due to the flatter energy landscapes in the monoclinic phases.
APPLIED PHYSICS LETTERS
(2023)
Article
Physics, Applied
Long Cheng, Heng Zhang, Ran Xu, Kevin Co, Nicolas Guiblin, Mojca Otonicar, Charles Paillard, Yujia Wang, Brahim Dkhil
Summary: The interaction between domain structure and defects in ferroelectric thin films has been a focus of research. This study demonstrates the role of dislocations in stabilizing the domains of PbTiO3 films on a SrTiO3 substrate during post-annealing above 550 degrees C. The effects of single dislocations and dislocation pairs on domain formation were also explored.
APPLIED PHYSICS LETTERS
(2023)
Article
Materials Science, Multidisciplinary
Y. Liu, K. Zweiacker, C. Liu, J. T. McKeown, J. M. K. Wiezorek
Summary: The evolution of rapid solidification microstructure and solidification interface velocity of hypereutectic Al-20at.%Cu alloy after laser melting has been studied experimentally. It was found that the formation of microstructure was dominated by eutectic, alpha-cell, and banded morphology grains, and the growth modes changed with increasing interface velocity.
Article
Materials Science, Multidisciplinary
Bharat Gwalani, Julian Escobar, Miao Song, Jonova Thomas, Joshua Silverstein, Andrew Chihpin Chuang, Dileep Singh, Michael P. Brady, Yukinori Yamamoto, Thomas R. Watkins, Arun Devaraj
Summary: Castable alumina forming austenitic alloys exhibit superior creep life and oxidation resistance at high temperatures. This study reveals the mechanism behind the enhanced creep performance of these alloys by suppressing primary carbide formation and offers a promising alloy design strategy for high-temperature applications.
Article
Materials Science, Multidisciplinary
Jian Song, Qi Zhang, Songsong Yao, Kunming Yang, Houyu Ma, Jiamiao Ni, Boan Zhong, Yue Liu, Jian Wang, Tongxiang Fan
Summary: Recent studies have shown that achieving an atomically flat surface for metals can greatly improve their oxidation resistance and enhance their electronic-optical applications. Researchers have explored the use of graphene as a covering layer to achieve atomically flat surfaces. They found that high-temperature deposited graphene on copper surfaces formed mono-atomic steps, while annealed copper and transferred graphene on copper interfaces formed multi-atomic steps.
Article
Materials Science, Multidisciplinary
Jennifer A. Glerum, Jon-Erik Mogonye, David C. Dunand
Summary: Elemental powders of Al, Ti, Sc, and Zr are blended and processed via laser powder-bed fusion to create binary and ternary alloys. The microstructural analysis and mechanical testing show that the addition of Ti results in the formation of primary precipitates, while the addition of Sc and Zr leads to the formation of fine grain bands. The Al-0.25Ti-0.25Zr alloy exhibits comparable strain rates to Al-0.5Zr at low stresses, but significantly higher strain rates at higher stresses during compressive creep testing. Finite element modeling suggests that the connectivity of coarse and fine grain regions is a critical factor affecting the creep resistance of the alloys.
Article
Materials Science, Multidisciplinary
P. Jannotti, B. C. Hornbuckle, J. T. Lloyd, N. Lorenzo, M. Aniska, T. L. Luckenbaugh, A. J. Roberts, A. Giri, K. A. Darling
Summary: This work characterizes the thermo-mechanical behavior of bulk nanocrystalline Cu-Ta alloys under extreme conditions. The experiments reveal that the alloys exhibit unique mechanical properties, behaving differently from conventional nanocrystalline Cu. They do not undergo grain coarsening during extrusion and exhibit behavior similar to coarse-grained Cu.
Article
Materials Science, Multidisciplinary
Yiqing Wei, Jingwei Li, Daliang Zhang, Bin Zhang, Zizhen Zhou, Guang Han, Guoyu Wang, Carmelo Prestipino, Pierric Lemoine, Emmanuel Guilmeau, Xu Lu, Xiaoyuan Zhou
Summary: This study proposes a new strategy to modify microstructure by phase regulation, which can simultaneously enhance carrier mobility and reduce lattice thermal conductivity. The addition of Cu in layered SnSe2 induces a phase transition that leads to increased grain size and reduced stacking fault density, resulting in improved carrier mobility and lower lattice thermal conductivity.
Article
Materials Science, Multidisciplinary
Jia Chen, Zhengyu Zhang, Eitan Hershkovitz, Jonathan Poplawsky, Raja Shekar Bhupal Dandu, Chang-Yu Hung, Wenbo Wang, Yi Yao, Lin Li, Hongliang Xin, Honggyu Kim, Wenjun Cai
Summary: In this study, the structural origin of the pH-dependent repassivation mechanisms in multi-principal element alloys (MPEA) was investigated using surface characterization and computational simulations. It was found that selective oxidation in acidic to neutral solutions leads to enhanced nickel enrichment on the surface, resulting in reduced repassivation capability and corrosion resistance.
Article
Materials Science, Multidisciplinary
X. Y. Xu, C. P. Huang, H. Y. Wang, Y. Z. Li, M. X. Huang
Summary: The limited slip systems of magnesium (Mg) and its alloys hinder their wide applications. By conducting tensile straining experiments, researchers discovered a rate-dependent transition in the dislocation mechanisms of Mg alloys. At high strain rates, glissile dislocations dominate, while easy-glide dislocations dominate at low strain rates. Abundant glissile dislocations do not necessarily improve ductility.
Article
Materials Science, Multidisciplinary
M. S. Szczerba, M. J. Szczerba
Summary: Inverse temperature dependences of the detwinning stress were observed in face-centered cubic deformation twins in Cu-8at.%Al alloy. The detwinning stress increased with temperature when the pi detwinning mode was involved, but decreased when the pi/3 mode was involved. The dual effect of temperature on the detwinning stress was due to the reduction of internal stresses pre-existing within the deformation twins. The complete reduction of internal stresses at about 530 degrees C led to the equivalence of the critical stresses of different detwinning modes and a decrease in the yield stress anisotropy of the twin/matrix structure.
Article
Materials Science, Multidisciplinary
Taowen Dong, Tingting Qin, Wei Zhang, Yaowen Zhang, Zhuoran Feng, Yuxiang Gao, Zhongyu Pan, Zixiang Xia, Yan Wang, Chunming Yang, Peng Wang, Weitao Zheng
Summary: The interaction between the electrode and the electric double layer (EDL) significantly influences the energy storage mechanism. By studying the popular alpha-Fe2O3 electrode and the EDL interaction, we find that the energy storage mechanism of the electrode can be controlled by modulating the EDL.
Article
Materials Science, Multidisciplinary
Matthew R. Barnett, Jun Wang, Sitarama R. Kada, Alban de Vaucorbeil, Andrew Stevenson, Marc Fivel, Peter A. Lynch
Summary: The elastic-plastic transition in magnesium alloy Mg-4.5Zn exhibits bursts of deformation, which are characterized by sudden changes in grain orientation. These bursts occur in a coordinated manner among nearby grains, with the highest burst rate observed at the onset of full plasticity. The most significant burst events are associated with twinning, supported by the observation of twinned structures using electron microscopy. The bursts are often preceded and followed by a stasis in peak movement, indicating a certain "birth size" for twins upon formation and subsequent growth at a later stage.
Article
Materials Science, Multidisciplinary
Vaidehi Menon, Sambit Das, Vikram Gavini, Liang Qi
Summary: Understanding solute segregation thermodynamics is crucial for investigating grain boundary properties. The spectral approach and thermodynamic integration methods can be used to predict solute segregation behavior at grain boundaries and compare with experimental observations, thus aiding in alloy design and performance control.
Article
Materials Science, Multidisciplinary
Feiyu Qin, Lei Hu, Yingcai Zhu, Yuki Sakai, Shogo Kawaguchi, Akihiko Machida, Tetsu Watanuki, Yue-Wen Fang, Jun Sun, Xiangdong Ding, Masaki Azuma
Summary: This study reports on the negative and zero thermal expansion properties of Cd2Re2O7 and Cd1.95Ni0.05Re2O7 materials, along with their ultra-low thermal conductivity. Through investigations of their structures and phonon calculations, the synergistic effect of local structure distortion and soft phonons is revealed as the key to achieving these distinctive properties.
Article
Materials Science, Multidisciplinary
Thomas Beerli, Christian C. Roth, Dirk Mohr
Summary: A novel testing system for miniature specimens is designed to characterize the plastic response of materials for which conventional full-size specimens cannot be extracted. The system has an automated operation process, which reduces the damage to specimens caused by manual handling and improves the stability of the test results. The experiments show that the miniature specimens extracted from stainless steel and aluminum have high reproducibility, and the results are consistent with those of conventional-sized specimens. A correction procedure is provided to consider the influence of surface roughness and heat-affected zone caused by wire EDM.
Article
Materials Science, Multidisciplinary
Rani Mary Joy, Paulius Pobedinskas, Nina Baule, Shengyuan Bai, Daen Jannis, Nicolas Gauquelin, Marie-Amandine Pinault-Thaury, Francois Jomard, Kamatchi Jothiramalingam Sankaran, Rozita Rouzbahani, Fernando Lloret, Derese Desta, Jan D'Haen, Johan Verbeeck, Michael Frank Becker, Ken Haenen
Summary: This study investigates the influence of film microstructure and composition on the Young's modulus and residual stress in nanocrystalline diamond thin films. The results provide insights into the mechanical properties and intrinsic stress sources of these films, and demonstrate the potential for producing high-quality nanocrystalline diamond films under certain conditions.