Review on photocatalytic and electrocatalytic artificial nitrogen fixation for ammonia synthesis at mild conditions: Advances, challenges and perspectives

Bismuth Subcarbonate with Designer Defects for Broad-Spectrum Photocatalytic Nitrogen Fixation

(2018) Chenmin Xu et al.   ACS Applied Materials & Interfaces

Electrochemical Ammonia Synthesis via Nitrogen Reduction Reaction on a MoS2 Catalyst: Theoretical and Experimental Studies

(2018) Ling Zhang et al.   ADVANCED MATERIALS

Promoted Fixation of Molecular Nitrogen with Surface Oxygen Vacancies on Plasmon-Enhanced TiO2 Photoelectrodes

(2018) Chengcheng Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Defect Engineering Metal-Free Polymeric Carbon Nitride Electrocatalyst for Effective Nitrogen Fixation under Ambient Conditions

(2018) Chade Lv et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Single-Nanoparticle Photoelectrochemistry at a Nanoparticulate TiO2 -Filmed Ultramicroelectrode

(2018) Yue-Yi Peng et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Highly efficient electrochemical ammonia synthesis via nitrogen reduction reactions on a VN nanowire array under ambient conditions

(2018) Xiaoping Zhang et al.   CHEMICAL COMMUNICATIONS

Electrochemical N2 fixation to NH3 under ambient conditions: Mo2N nanorod as a highly efficient and selective catalyst

(2018) Xiang Ren et al.   CHEMICAL COMMUNICATIONS

Rational design of electrocatalysts and photo(electro)catalysts for nitrogen reduction to ammonia (NH3) under ambient conditions

(2018) Chunxian Guo et al.   Energy & Environmental Science

Refining Defect States in W18O49 by Mo Doping: A Strategy for Tuning N2 Activation towards Solar-Driven Nitrogen Fixation

(2018) Ning Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

High-Efficiency “Working-in-Tandem” Nitrogen Photofixation Achieved by Assembling Plasmonic Gold Nanocrystals on Ultrathin Titania Nanosheets

(2018) Jianhua Yang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Quantifying Visible-Light-Induced Electron Transfer Properties of Single Dye-Sensitized ZnO Entity for Water Splitting

(2018) Hui Ma et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Spectroscopic Study on the Nitrogen Electrochemical Reduction Reaction on Gold and Platinum Surfaces

(2018) Yao Yao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ambient N2 fixation to NH3 electrocatalyzed by a spinel Fe3O4 nanorod

(2018) Qin Liu et al.   Nanoscale

Ambient ammonia synthesis via palladium-catalyzed electrohydrogenation of dinitrogen at low overpotential

(2018) Jun Wang et al.   Nature Communications

Anchoring PdCu Amorphous Nanocluster on Graphene for Electrochemical Reduction of N2 to NH3 under Ambient Conditions in Aqueous Solution

(2018) Miao-Miao Shi et al.   Advanced Energy Materials

A Review of Electrocatalytic Reduction of Dinitrogen to Ammonia under Ambient Conditions

(2018) Xiaoyang Cui et al.   Advanced Energy Materials

Nitrogen-doped porous carbon: highly efficient trifunctional electrocatalyst for oxygen reversible catalysis and nitrogen reduction reaction

(2018) Xiaoxuan Yang et al.   Journal of Materials Chemistry A

Efficient photocatalytic fixation of N2 by KOH-treated g-C3N4

(2018) Xiaoman Li et al.   Journal of Materials Chemistry A

MXene-derived TiO2@C/g-C3N4 heterojunctions for highly efficient nitrogen photofixation

(2018) Qiuxia Liu et al.   Journal of Materials Chemistry A

Surfactant-free atomically ultrathin rhodium nanosheet nanoassemblies for efficient nitrogen electroreduction

(2018) Hui-Min Liu et al.   Journal of Materials Chemistry A

MoO3 nanosheets for efficient electrocatalytic N2 fixation to NH3

(2018) Jingrui Han et al.   Journal of Materials Chemistry A

Metal-organic framework-derived nitrogen-doped highly disordered carbon for electrochemical ammonia synthesis using N 2 and H 2 O in alkaline electrolytes

(2018) Shreya Mukherjee et al.   Nano Energy

Enhancing the rate of electrochemical nitrogen reduction reaction for ammonia synthesis under ambient conditions using hollow gold nanocages

(2018) Mohammadreza Nazemi et al.   Nano Energy

Photocatalytic fixation of nitrogen to ammonia: state-of-the-art advancements and future prospects

(2018) Xingzhu Chen et al.   Materials Horizons

Enabling Effective Electrocatalytic N2 Conversion to NH3 by the TiO2 Nanosheets Array under Ambient Conditions

(2018) Rong Zhang et al.   ACS Applied Materials & Interfaces

Achieving a Record-High Yield Rate of 120.9 μgNH3  mgcat.−1  h−1 for N2 Electrochemical Reduction over Ru Single-Atom Catalysts

(2018) Zhigang Geng et al.   ADVANCED MATERIALS

Ammonia Synthesis from Electrocatalytic N2 Reduction under Ambient Conditions by Fe2 O3 Nanorods

(2018) Xiaojiao Xiang et al.   ChemCatChem

Mechanistic Insights into Electrochemical Nitrogen Reduction Reaction on Vanadium Nitride Nanoparticles

(2018) Xuan Yang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

High-performance artificial nitrogen fixation at ambient conditions using a metal-free electrocatalyst

(2018) Weibin Qiu et al.   Nature Communications

High-Performance Electrohydrogenation of N2 to NH3 Catalyzed by Multishelled Hollow Cr2O3 Microspheres under Ambient Conditions

(2018) Ya Zhang et al.   ACS Catalysis

TiO2 nanoparticles–reduced graphene oxide hybrid: an efficient and durable electrocatalyst toward artificial N2 fixation to NH3 under ambient conditions

(2018) Xiaoxue Zhang et al.   Journal of Materials Chemistry A

Ambient N2 fixation to NH3 at ambient conditions: Using Nb2O5 nanofiber as a high-performance electrocatalyst

(2018) Jingrui Han et al.   Nano Energy

Intrinsic Electrocatalytic Activity of Gold Nanoparticles Measured by Single Entity Electrochemistry

(2018) Yue-Yi Peng et al.   ChemElectroChem

Single Mo Atom Supported on Defective Boron Nitride Monolayer as an Efficient Electrocatalyst for Nitrogen Fixation: A Computational Study

(2017) Jingxiang Zhao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ammonia Electrosynthesis with High Selectivity under Ambient Conditions via a Li+ Incorporation Strategy

(2017) Gao-Feng Chen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Photocatalytic Conversion of Nitrogen to Ammonia with Water on Surface Oxygen Vacancies of Titanium Dioxide

(2017) Hiroaki Hirakawa et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ionic Exchange of Metal–Organic Frameworks to Access Single Nickel Sites for Efficient Electroreduction of CO2

(2017) Changming Zhao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Combining theory and experiment in electrocatalysis: Insights into materials design

(2017) Zhi Wei Seh et al.   SCIENCE

Single-Atom Catalysts: Emerging Multifunctional Materials in Heterogeneous Catalysis

(2017) Huabin Zhang et al.   Advanced Energy Materials

Room-Temperature Electrocatalytic Synthesis of NH3 from H2O and N2 in a Gas–Liquid–Solid Three-Phase Reactor

(2017) Shiming Chen et al.   ACS Sustainable Chemistry & Engineering

Efficient photocatalytic reduction of dinitrogen to ammonia on bismuth monoxide quantum dots

(2017) Songmei Sun et al.   Journal of Materials Chemistry A

Graphitic carbon nitride (g-C3N4)-based photocatalysts for solar hydrogen generation: recent advances and future development directions

(2017) Amene Naseri et al.   Journal of Materials Chemistry A

Electrochemical reduction of aqueous nitrogen (N2) at a low overpotential on (110)-oriented Mo nanofilm

(2017) Dashuai Yang et al.   Journal of Materials Chemistry A

Interplay between Theory and Experiment for Ammonia Synthesis Catalyzed by Transition Metal Complexes

(2016) Hiromasa Tanaka et al.   ACCOUNTS OF CHEMICAL RESEARCH

Solar Water Splitting and Nitrogen Fixation with Layered Bismuth Oxyhalides

(2016) Jie Li et al.   ACCOUNTS OF CHEMICAL RESEARCH

Facet-Dependent Photocatalytic N2 Fixation of Bismuth-Rich Bi5O7I Nanosheets

(2016) Yang Bai et al.   ACS Applied Materials & Interfaces

Electrochemical Reduction of N2under Ambient Conditions for Artificial N2Fixation and Renewable Energy Storage Using N2/NH3Cycle

(2016) Di Bao et al.   ADVANCED MATERIALS

Electrocatalytic Efficiency Analysis of Catechol Molecules for NADH Oxidation during Nanoparticle Collision

(2016) Li-Jun Zhao et al.   ANALYTICAL CHEMISTRY

Single Cobalt Atoms with Precise N-Coordination as Superior Oxygen Reduction Reaction Catalysts

(2016) Peiqun Yin et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Large-scale production of graphitic carbon nitride with outstanding nitrogen photofixation ability via a convenient microwave treatment

(2016) Huiqiang Ma et al.   APPLIED SURFACE SCIENCE

Template-free method for synthesizing sponge-like graphitic carbon nitride with a large surface area and outstanding nitrogen photofixation ability induced by nitrogen vacancies

(2016) Guang Wu et al.   CERAMICS INTERNATIONAL

Graphitic Carbon Nitride (g-C3N4)-Based Photocatalysts for Artificial Photosynthesis and Environmental Remediation: Are We a Step Closer To Achieving Sustainability?

(2016) Wee-Jun Ong et al.   CHEMICAL REVIEWS

Efficient Solar-Driven Nitrogen Fixation over Carbon-Tungstic-Acid Hybrids

(2016) Xiaoman Li et al.   CHEMISTRY-A EUROPEAN JOURNAL

Hydrogenated Bismuth Molybdate Nanoframe for Efficient Sunlight-Driven Nitrogen Fixation from Air

(2016) Yuchen Hao et al.   CHEMISTRY-A EUROPEAN JOURNAL

Promising prospects for 2D d2–d4 M3C2 transition metal carbides (MXenes) in N2 capture and conversion into ammonia

(2016) Luis Miguel Azofra et al.   Energy & Environmental Science

CO2 photo-reduction: insights into CO2 activation and reaction on surfaces of photocatalysts

(2016) Xiaoxia Chang et al.   Energy & Environmental Science

Preparation of graphitic carbon nitride with large specific surface area and outstanding N 2 photofixation ability via a dissolve-regrowth process

(2016) Huiqiang Ma et al.   JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS

Communication—Electrochemical Reduction of Nitrogen to Ammonia in 2-Propanol under Ambient Temperature and Pressure

(2016) Kwiyong Kim et al.   JOURNAL OF THE ELECTROCHEMICAL SOCIETY

Advances and challenges in chemistry of two-dimensional nanosheets

(2016) Wenlong Yang et al.   Nano Today

Facet-dependent solar ammonia synthesis of BiOCl nanosheets via a proton-assisted electron transfer pathway

(2016) Hao Li et al.   Nanoscale

On the mechanism of electrochemical ammonia synthesis on the Ru catalyst

(2016) Seoin Back et al.   PHYSICAL CHEMISTRY CHEMICAL PHYSICS

Thermally stable single-atom platinum-on-ceria catalysts via atom trapping

(2016) J. Jones et al.   SCIENCE

Bismuth oxyhalides: synthesis, structure and photoelectrochemical activity

(2016) Davinder S. Bhachu et al.   Chemical Science

Nanostructured photoelectrochemical solar cell for nitrogen reduction using plasmon-enhanced black silicon

(2016) Muataz Ali et al.   Nature Communications

Electrochemical Ammonia Synthesis—The Selectivity Challenge

(2016) Aayush R. Singh et al.   ACS Catalysis

Effect of sulfur vacancies on the nitrogen photofixation performance of ternary metal sulfide photocatalysts

(2016) Shaozheng Hu et al.   Catalysis Science & Technology

Photofixation of atmospheric nitrogen to ammonia with a novel ternary metal sulfide catalyst under visible light

(2016) Yuhui Cao et al.   RSC Advances

Electrocatalytic Nitrogen Fixation for Distributed Fertilizer Production?

(2016) Michael Jewess et al.   ACS Sustainable Chemistry & Engineering

The Challenge of Electrochemical Ammonia Synthesis: A New Perspective on the Role of Nitrogen Scaling Relations

(2015) Joseph H. Montoya et al.   ChemSusChem

Efficient Visible Light Nitrogen Fixation with BiOBr Nanosheets of Oxygen Vacancies on the Exposed {001} Facets

(2015) Hao Li et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enabling electrochemical reduction of nitrogen to ammonia at ambient conditions through rational catalyst design

(2015) Younes Abghoui et al.   PHYSICAL CHEMISTRY CHEMICAL PHYSICS

Galvanic deposition of Rh and Ru on randomly structured Ti felts for the electrochemical NH3 synthesis

(2015) Kurt Kugler et al.   PHYSICAL CHEMISTRY CHEMICAL PHYSICS

Identification of active sites in CO oxidation and water-gas shift over supported Pt catalysts

(2015) K. Ding et al.   SCIENCE

Electroreduction of N2 to Ammonia at Ambient Conditions on Mononitrides of Zr, Nb, Cr, and V: A DFT Guide for Experiments

(2015) Younes Abghoui et al.   ACS Catalysis

Selective photocatalytic N2 fixation dependent on g-C3N4 induced by nitrogen vacancies

(2015) Guohui Dong et al.   Journal of Materials Chemistry A

Plasmon-Induced Ammonia Synthesis through Nitrogen Photofixation with Visible Light Irradiation

(2014) Tomoya Oshikiri et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Mechanism of Nitrogen Fixation by Nitrogenase: The Next Stage

(2014) Brian M. Hoffman et al.   CHEMICAL REVIEWS

Challenges in reduction of dinitrogen by proton and electron transfer

(2014) Cornelis J. M. van der Ham et al.   CHEMICAL SOCIETY REVIEWS

Recent advances in semiconductors for photocatalytic and photoelectrochemical water splitting

(2014) Takashi Hisatomi et al.   CHEMICAL SOCIETY REVIEWS

A highly efficient visible-light driven photocatalyst: two dimensional square-like bismuth oxyiodine nanosheets

(2014) Yan Mi et al.   DALTON TRANSACTIONS

The Haber-Bosch Process Revisited: On the Real Structure and Stability of “Ammonia Iron” under Working Conditions

(2013) Timur Kandemir et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enhanced nitrogen photofixation on Fe-doped TiO2 with highly exposed (101) facets in the presence of ethanol as scavenger

(2013) Weirong Zhao et al.   APPLIED CATALYSIS B-ENVIRONMENTAL

Mechanistic aspects of dinitrogen cleavage and hydrogenation to produce ammonia in catalysis and organometallic chemistry: relevance of metal hydride bonds and dihydrogen

(2013) Hong-Peng Jia et al.   CHEMICAL SOCIETY REVIEWS

Developing more sustainable processes for ammonia synthesis

(2013) Yoshiaki Tanabe et al.   COORDINATION CHEMISTRY REVIEWS

Review of electrochemical ammonia production technologies and materials

(2013) S. Giddey et al.   INTERNATIONAL JOURNAL OF HYDROGEN ENERGY

Mechanism of N2 Reduction to NH3 by Aqueous Solvated Electrons

(2013) Jeffrey R. Christianson et al.   JOURNAL OF PHYSICAL CHEMISTRY B

Vacancy Associates Promoting Solar-Driven Photocatalytic Activity of Ultrathin Bismuth Oxychloride Nanosheets

(2013) Meili Guan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Photo-illuminated diamond as a solid-state source of solvated electrons in water for nitrogen reduction

(2013) Di Zhu et al.   NATURE MATERIALS

Electro-reduction of nitrogen on molybdenum nitride: structure, energetics, and vibrational spectra from DFT

(2013) Ivana Matanović et al.   PHYSICAL CHEMISTRY CHEMICAL PHYSICS

Electrochemical synthesis of ammonia directly from air and water using a Li+/H+/NH4+ mixed conducting electrolyte

(2013) Rong Lan et al.   RSC Advances

Synthesis of ammonia directly from air and water at ambient temperature and pressure

(2013) Rong Lan et al.   Scientific Reports

A Review of Surface Plasmon Resonance-Enhanced Photocatalysis

(2012) Wenbo Hou et al.   ADVANCED FUNCTIONAL MATERIALS

Nano-architecture and material designs for water splitting photoelectrodes

(2012) Hao Ming Chen et al.   CHEMICAL SOCIETY REVIEWS

Progress, challenge and perspective of heterogeneous photocatalysts

(2012) Yongquan Qu et al.   CHEMICAL SOCIETY REVIEWS

Photoelectrochemical cells for solar hydrogen production: current state of promising photoelectrodes, methods to improve their properties, and outlook

(2012) Zhaosheng Li et al.   Energy & Environmental Science

New Pathways and Processes in the Global Nitrogen Cycle

(2011) Bo Thamdrup   Annual Review of Ecology Evolution and Systematics

Advanced Nanoarchitectures for Solar Photocatalytic Applications

(2011) Anna Kubacka et al.   CHEMICAL REVIEWS

A theoretical evaluation of possible transition metal electro-catalysts for N2reduction

(2011) Egill Skúlason et al.   PHYSICAL CHEMISTRY CHEMICAL PHYSICS

Semiconductor-based Photocatalytic Hydrogen Generation

(2010) Xiaobo Chen et al.   CHEMICAL REVIEWS

Dinitrogen photofixation at ruthenium-modified titania films

(2010) Oksana P. Linnik et al.   MENDELEEV COMMUNICATIONS

The Evolution and Future of Earth’s Nitrogen Cycle

(2010) Donald E. Canfield et al.   SCIENCE

Climbing Nitrogenase: Toward a Mechanism of Enzymatic Nitrogen Fixation

(2009) Brian M. Hoffman et al.   ACCOUNTS OF CHEMICAL RESEARCH

DFT Study on Chemical N2Fixation by Using a Cubane-Type RuIr3S4Cluster: Energy Profile for Binding and Reduction of N2to Ammonia via Ru−N−NHx(x= 1−3) Intermediates with Unique Structures

(2008) Hiromasa Tanaka et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

An Earth-system perspective of the global nitrogen cycle

(2008) Nicolas Gruber et al.   NATURE

How a century of ammonia synthesis changed the world

(2008) Jan Willem Erisman et al.   Nature Geoscience

Dinitrogen photofixation properties of different titanium oxides in conducting polymer/titanium oxide hybrid systems

(2007) K. Hoshino et al.   APPLIED CATALYSIS B-ENVIRONMENTAL