Article
Environmental Sciences
B. Rogalla, S. E. Allen, M. Colombo, P. G. Myers, K. J. Orians
Summary: Biogeochemical cycles in the Arctic Ocean are sensitive to the transport of materials from continental shelves into central basins by sea ice. Manganese (Mn) is an important micronutrient and tracer, and sea ice is the main source of Mn in the Canada Basin while rivers contribute less. The vulnerability of biogeochemical supply mechanisms in the Arctic Ocean and subpolar seas to climate change is highlighted.
GLOBAL BIOGEOCHEMICAL CYCLES
(2022)
Article
Environmental Sciences
B. Rogalla, S. E. Allen, M. Colombo, P. G. Myers, K. J. Orians
Summary: Climate change is causing rising temperatures and an acceleration of the hydrological cycle, leading to increased river discharge and resulting in permafrost thaw, glacial melt, and a shift to a groundwater-dominated system in the Arctic. These changes impact the distribution of nutrients and biogeochemical constituents in the coastal regions of the Arctic Ocean. This study investigates the effects of terrestrial runoff on marine biogeochemistry in the Canadian Arctic Archipelago, using ocean modeling experiments to explore the transport and modification of waters from the Arctic Ocean to the North Atlantic. The findings highlight the influence of continental and glacial runoff on the geochemical composition of the marine environment, and the potential impacts on the marine ecosystem.
JOURNAL OF GEOPHYSICAL RESEARCH-BIOGEOSCIENCES
(2023)
Article
Environmental Sciences
Stephan Krisch, Mark J. Hopwood, Stephane Roig, Loes J. A. Gerringa, Rob Middag, Michiel M. Rutgers van der Loeff, Mariia V. Petrova, Pablo Lodeiro, Manuel Colombo, Jay T. Cullen, Sarah L. Jackson, Lars-Eric Heimburger-Boavida, Eric P. Achterberg
Summary: The Arctic Ocean serves as a significant source of micronutrients to the Nordic Seas and the North Atlantic Ocean through the Fram Strait. However, limited data on trace elements across the Arctic Ocean gateways makes it difficult to understand the impact of Arctic and North Atlantic exchange on micronutrient availability. Recent research suggests that the Fram Strait is the most important gateway for dissolved micronutrient exchange, driven by the transport of Intermediate and Deep Water. Changes in shelf inputs and sea ice dynamics in the Arctic, particularly in Siberian shelf regions, affect micronutrient availability in the Fram Strait and the high latitude North Atlantic Ocean.
GLOBAL BIOGEOCHEMICAL CYCLES
(2022)
Article
Oceanography
Laramie T. Jensen, Jay T. Cullen, Sarah L. Jackson, Loes J. A. Gerringa, Dorothea Bauch, Rob Middag, Robert M. Sherrell, Jessica N. Fitzsimmons
Summary: Recent studies have revealed a unique linear relationship between dissolved copper (Cu) and nickel (Ni) in the Arctic Ocean, which differs from other oceans. This relationship is driven by river inputs and shows distinct distribution patterns in surface and deep waters. Cu and Ni mainly originate from rivers, but Ni is additionally influenced by biological processes and shelf sediment processes, while Cu is mostly affected by mixing.
JOURNAL OF GEOPHYSICAL RESEARCH-OCEANS
(2022)
Article
Environmental Sciences
Chris M. Marsay, William M. Landing, Devon Umstead, Claire P. Till, Robert Freiberger, Jessica N. Fitzsimmons, Nathan T. Lanning, Alan M. Shiller, Mariko Hatta, Rebecca Chmiel, Mak Saito, Clifton S. Buck
Summary: Atmospheric deposition is a major source of micronutrient trace elements in the surface ocean. This study assesses the contribution of sea spray aerosol (SSA) to aerosol trace element loading, finding that only vanadium has a significant SSA contribution. The study highlights the limitations in measuring trace elements in SSA and the potential for overestimating new trace element inputs from atmospheric deposition.
GLOBAL BIOGEOCHEMICAL CYCLES
(2022)
Article
Oceanography
Laramie T. Jensen, Nathan T. Lanning, Chris M. Marsay, Clifton S. Buck, Ana M. Aguilar-Islas, Robert Rember, William M. Landing, Robert M. Sherrell, Jessica N. Fitzsimmons
Summary: The surface waters of the Arctic Ocean include an important inventory of freshwater from rivers, sea ice melt, and glacial meltwaters. Different metals exhibit varying concentrations and impacts as colloids in different cryospheric reservoirs.
JOURNAL OF GEOPHYSICAL RESEARCH-OCEANS
(2021)
Article
Oceanography
L. J. A. Gerringa, M. J. A. Rijkenberg, H. A. Slagter, P. Laan, R. Paffrath, D. Bauch, M. Rutgers van der Loeff, R. Middag
Summary: During the PS94 expedition in summer 2015, sources and sinks of dissolved metals in the central Arctic Ocean were studied, revealing different concentrations of metals in various regions, highlighting the importance of different water sources in influencing metal distributions.
JOURNAL OF GEOPHYSICAL RESEARCH-OCEANS
(2021)
Article
Oceanography
Ronja Paffrath, Katharina Pahnke, Philipp Boening, Michiel Rutgers van der Loeff, Ole Valk, Sandra Gdaniec, Helene Planquette
Summary: In the central Arctic Ocean, dissolved rare earth element concentrations and the neodymium isotope compositions remain constant in the deep water column, indicating unique seawater-particle interactions. The consistent particulate rare earth element concentrations suggest that particle composition is the primary factor preventing certain elements from being released into the dissolved pool.
JOURNAL OF GEOPHYSICAL RESEARCH-OCEANS
(2021)
Article
Environmental Sciences
Manuel Colombo, Birgit Rogalla, Jingxuan Li, Susan E. Allen, Kristin J. Orians, Maria T. Maldonado
Summary: Research shows that the Canadian Arctic Archipelago region's sediment resuspension and sediment-water interactions result in the enrichment of iron in water bodies, which are then transported to Baffin Bay, providing crucial support for primary production and nitrogen fixation in the region and beyond.
GLOBAL BIOGEOCHEMICAL CYCLES
(2021)
Article
Environmental Sciences
Chris M. Marsay, David Kadko, William M. Landing, Clifton S. Buck
Summary: Atmospheric deposition of aerosols transported from the continents plays a significant role in supplying nutrient and pollutant trace elements to the surface ocean. This study focused on analyzing aerosol samples collected over the North Pacific and equatorial Pacific during the low dust season. The results showed higher enrichment factors of trace elements in equatorial Pacific aerosols compared to North Pacific aerosols, and higher bulk deposition velocities within the Intertropical Convergence Zone due to intense rainfall scavenging.
GLOBAL BIOGEOCHEMICAL CYCLES
(2022)
Article
Geosciences, Multidisciplinary
Y. Xiang, P. J. Lam, J. M. Lee
Summary: The study found that the oxidation state of particulate manganese in the surface Arctic Ocean is related to the sampling time, with AOS <2.4 during the day and >3.0 at night. It is hypothesized that a light-dependent redox cycle between dissolved and particulate manganese exists in the surface Arctic Ocean.
GEOPHYSICAL RESEARCH LETTERS
(2021)
Article
Oceanography
N. Lehmann, M. Kienast, J. Granger, J. -E. Tremblay
Summary: The Canadian Arctic Archipelago plays a crucial role in nutrient flow from the North Pacific to the North Atlantic. However, there is limited understanding of nutrient transport and cycling in this region. This study investigates the nitrogen and oxygen isotope ratios of nitrate in the Canadian Arctic Archipelago, providing insights into nutrient dynamics. The results show enhanced nitrate assimilation in the eastern part of the archipelago, characterized by high nitrate isotope values. Additionally, it reveals that a substantial fraction of nutrients in the central archipelago comes from the Atlantic, a larger proportion than previously estimated. Benthic denitrification has little influence on nutrient properties in this area.
JOURNAL OF GEOPHYSICAL RESEARCH-OCEANS
(2022)
Article
Geosciences, Multidisciplinary
S. M. Niklasson, M. Veneziani, C. A. Rowe, P. F. Worcester, M. A. Dzieciuch, S. L. Bilek, S. F. Price, A. F. Roberts
Summary: The hydroacoustic environment in the rapidly warming Arctic Ocean is affected by changes in the physical environment and increased human activity. It is necessary to update previous acoustic calculations to reflect current and future conditions. Earth System Models are important for projecting changes in physical processes under future climates. We compare Arctic acoustic travel times based on the Energy Exascale Earth System Model, measured travel times from the Canada Basin Acoustic Propagation Experiment, and travel times predicted by empirical temperature and salinity observations, in order to test the impact of changes in Arctic sound speed profiles on acoustic travel times and connect Arctic hydroacoustics with the changing Arctic environment as described by a climate model.
GEOPHYSICAL RESEARCH LETTERS
(2023)
Article
Oceanography
Bianca T. P. Liguori, Claudia Ehlert, Eva-Maria Noethig, Jan C. van Ooijen, Katharina Pahnke
Summary: In the ice-covered Central Arctic Ocean, diatom production is limited by light availability and nutrient supply, with higher production at the sea ice edge and over partially ice-free shelf areas. The Transpolar Drift transports terrestrial-derived material across the CAO, impacting the Si cycle. Si isotopes help understand the differences in biological production areas and the potential influence of the TPD.
JOURNAL OF GEOPHYSICAL RESEARCH-OCEANS
(2021)
Article
Oceanography
E. Chamizo, M. Christl, M. Lopez-Lora, N. Casacuberta, A. -M. Wefing, T. C. Kenna
Summary: This study explores the potential of using the U-233/U-236 atom ratio to distinguish Atlantic and Pacific waters in the Arctic Ocean. Samples from the 2015 GN01 GEOTRACES expedition were analyzed, revealing that water masses can be differentiated based on their U-233/U-236 signatures. The study also found relatively high U-233/U-236 ratios in deep waters, potentially indicating an increase in naturally occurring U-233 and U-236.
JOURNAL OF GEOPHYSICAL RESEARCH-OCEANS
(2022)
Article
Environmental Sciences
Chris M. Marsay, David Kadko, William M. Landing, Clifton S. Buck
Summary: Atmospheric deposition of aerosols transported from the continents plays a significant role in supplying nutrient and pollutant trace elements to the surface ocean. This study focused on analyzing aerosol samples collected over the North Pacific and equatorial Pacific during the low dust season. The results showed higher enrichment factors of trace elements in equatorial Pacific aerosols compared to North Pacific aerosols, and higher bulk deposition velocities within the Intertropical Convergence Zone due to intense rainfall scavenging.
GLOBAL BIOGEOCHEMICAL CYCLES
(2022)
Article
Chemistry, Multidisciplinary
Michael H. Ihde, Joshua Tropp, Miguel Diaz, Alan M. Shiller, Jason D. Azoulay, Marco Bonizzoni
Summary: Metal cations are potent environmental pollutants, and their simultaneous detection and discrimination at sub-nanomolar concentrations in complex analytical matrices remain a major challenge. In this study, highly emissive conjugated polyelectrolytes functionalized with metal chelates were developed for the detection and differentiation of nine divalent metal cations. These sensors exhibited unprecedented sensitivity and improved differentiation, making them highly useful for environmental and biological applications.
ADVANCED FUNCTIONAL MATERIALS
(2022)
Article
Environmental Sciences
Shaily Rahman, Alan M. Shiller, Robert F. Anderson, Matthew A. Charette, Christopher T. Hayes, Melissa Gilbert, Karen R. Grissom, Phoebe J. Lam, Daniel C. Ohnemus, Frank J. Pavia, Benjamin S. Twining, Sebastian M. Vivancos
Summary: Processes controlling dissolved barium concentrations were investigated along two transects in the North Atlantic and Eastern Tropical Pacific. Conservative mixing and nonconservative processes were found to contribute to the variability of dissolved barium. Particulate excess barium formation and dissolution rates showed subsurface maxima, and the burial efficiency of particulate excess barium did not seem to depend on barite saturation indices. Revising river and shelf barium inputs may help balance the marine barium isotope budget.
GLOBAL BIOGEOCHEMICAL CYCLES
(2022)
Article
Chemistry, Analytical
Shuo-En Wu, Alan Shiller, Andrew Barnard, Jason D. Azoulay, Tse Nga Ng
Summary: This study demonstrates a compact microfluidic device that removes interfering chloride ions through electrochemical desalination to improve the detection limit of a nitrate sensor. The device has been fabricated using a low-cost approach and has achieved high sensitivity.
Article
Oceanography
Laura M. Whitmore, Alan M. Shiller, Tristan J. Horner, Yang Xiang, Maureen E. Auro, Dorothea Bauch, Frank Dehairs, Phoebe J. Lam, Jingxuan Li, Maria T. Maldonado, Chantal Mears, Robert Newton, Angelica Pasqualini, Helene Planquette, Robert Rember, Helmuth Thomas
Summary: This study investigates the distribution of barium (Ba) in the Arctic Ocean and finds that margins are a substantial source of Ba to the water column. Nonconservative inputs account for about 50% of the Ba inventory in the upper 500 m of the Arctic water column. The study also identifies the mixing of Arctic Ocean-derived waters and Baffin Bay-derived waters in the Canadian Arctic Archipelago.
JOURNAL OF GEOPHYSICAL RESEARCH-OCEANS
(2022)
Article
Environmental Sciences
Ziran Wei, J. Kirk Cochran, Evan Horowitz, Patrick Fitzgerald, Christina Heilbrun, David Kadko, Mark Stephens, Chris M. Marsay, Clifton S. Buck, William M. Landing
Summary: Deposition of aerosols to the surface ocean is an important factor affecting primary production in the surface ocean. This study collected data on aerosol Pb-210, Po-210, and Be-7 fluxes during a research cruise in the Pacific Ocean. The results showed that Pb-210 fluxes were low near the Alaskan margin, increased at around 43 degrees N, and then decreased. The study also found good agreement between Pb-210 fluxes and long-term land-based fluxes, as well as data from another research cruise in the East Pacific Ocean.
GLOBAL BIOGEOCHEMICAL CYCLES
(2022)
Article
Chemistry, Analytical
Melissa Gilbert, Peng Ho, Laura Whitmore, Alan Shiller
Summary: There is a growing interest in dissolved gallium (Ga) in natural waters for tracking water masses, but current analytical methods are time-consuming and labor-intensive. In this study, an automated isotope dilution method was developed to determine Ga in seawater using commercially available equipment. The method addressed challenges such as sample volume and pre-concentration, instrumental interferences, sample carryover, sample recovery variability, and improved detection limits, accuracy, and precision. The new automated method showed comparable Ga concentrations to traditional methods but with greater precision and a lower detection limit.
ANALYTICA CHIMICA ACTA
(2023)
Article
Environmental Sciences
Matthias Sieber, Nathan T. Lanning, Zachary B. Bunnell, Xiaopeng Bian, Shun-Chung Yang, Chris M. Marsay, William M. Landing, Clifton S. Buck, Jessica N. Fitzsimmons, Seth G. John, Tim M. Conway
Summary: This study investigates the distribution and controlling factors of cadmium in the surface and deep waters of the Pacific region. The results show a significant disparity between Cd-rich high-nutrient low-chlorophyll waters in the north and Cd-depleted waters in the subtropical and equatorial Pacific. Southern Ocean processes and water mass mixing are found to be the dominant control on Pacific Cd distributions.
GLOBAL BIOGEOCHEMICAL CYCLES
(2023)
Article
Multidisciplinary Sciences
Nathan T. Lanning, Shuo Jiang, Vinicius J. Amaral, Katherine Mateos, Janelle M. Steffen, Phoebe J. Lam, Edward A. Boyle, Jessica N. Fitzsimmons
Summary: Reversible scavenging is the process by which dissolved metals exchange onto and off sinking particles and are transported to deeper depths. This process deepens the distribution of adsorptive elements and shortens their residence times in the ocean. Understanding which metals undergo reversible scavenging and under what conditions is important.
PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA
(2023)
Article
Oceanography
M. Sieber, N. T. Lanning, X. Bian, S. -C. Yang, S. Takano, Y. Sohrin, T. S. Weber, J. N. Fitzsimmons, S. G. John, T. M. Conway
Summary: This study investigates the distribution of dissolved zinc and its isotopes in the North Pacific, and finds a tight linear correlation between zinc and silicon in the southern region (<20°N), while an excess of zinc relative to silicon is observed in the northern region (>20°N) due to regeneration processes. A mechanistic model suggests that reversible scavenging is an additional process that transfers zinc from the upper to the deep ocean, explaining the deep zinc maximum below the phosphate maximum. This mechanism also provides an explanation for the observed zinc isotope distribution.
JOURNAL OF GEOPHYSICAL RESEARCH-OCEANS
(2023)
Article
Environmental Sciences
Evgenii Salganik, Christian Katlein, Benjamin A. Lange, Ilkka Matero, Ruibo Lei, Allison A. Fong, Steven W. Fons, Dmitry Divine, Marc Oggier, Giulia Castellani, Deborah Bozzato, Emelia J. Chamberlain, Clara J. M. Hoppe, Oliver Mueller, Jessie Gardner, Annette Rinke, Patric Simoes Pereira, Adam Ulfsbo, Chris Marsay, Melinda A. Webster, Soenke Maus, Knut Hoyland, Mats A. Granskog
Summary: Low-salinity meltwater from Arctic sea ice and snow cover forms under-ice meltwater layers that can create false ice bottoms. A study conducted as part of the MOSAiC project revealed that the areal coverage of false bottoms in a specific area was 21%. The presence of false bottoms reduced bottom ice melt by up to 8%, primarily due to a decrease in ocean heat flux. The thickness of under-ice meltwater layers varied depending on ice age and thickness. The study also highlighted the role of thick ice and ridge keels in confining the accumulation of meltwater. While a thermodynamic model could explain false bottom growth, it couldn't accurately predict observed bottom melt rates.
ELEMENTA-SCIENCE OF THE ANTHROPOCENE
(2023)
Article
Chemistry, Multidisciplinary
Shuo-En Wu, Napasorn Phongphaew, Yichen Zhai, Lulu Yao, Hsun-Hao Hsu, Alan Shiller, Jason D. Azoulay, Tse Nga Ng
Summary: This study presents a new sensor tag for marine species that allows non-intrusive monitoring of the impacts of environmental changes on their behaviors and well-being, specifically focusing on the effects of dissolved oxygen and salinity on bivalve gape movement. The sensors, fabricated using low-cost techniques, offer an economical and convenient platform for aquaculture studies.
Article
Chemistry, Multidisciplinary
Morgane Leon, Pieter van Beek, Virginie Sanial, Marc Souhaut, Paul Henderson, Matthew A. Charette
Summary: The analysis of radium and actinium isotopes in seawater requires the collection of large volumes of water and the use of high sensitivity instruments. To concentrate these isotopes, filters impregnated with MnO2 are typically used. However, the extraction efficiency of these filters for the target isotopes needs to be determined.