Metal-Free Access to (E/Z )-α-Fluorovinyl Phosphorus Compounds from gem -Difluorostyrenes

Synthesis of α-CF3 and α-CF2H amines via the aminofluorination of fluorinated alkenes

(2018) Ling Yang et al.   CHEMICAL COMMUNICATIONS

Petasis-Type gem-Difluoroallylation Reactions Assisted by the Neighboring Hydroxyl Group in Amines

(2018) Xing Yang et al.   ORGANIC LETTERS

Zinc-Mediated Decarboxylative Alkylation of Gem-difluoroalkenes

(2018) Liting Yu et al.   ORGANIC LETTERS

Nonepimerizing Alkylation of H–P Species to Stereospecifically Generate P-Stereogenic Phosphine Oxides: A Shortcut to Bidentate Tertiary Phosphine Ligands

(2017) Shao-Zhen Nie et al.   JOURNAL OF ORGANIC CHEMISTRY

C–H Trifluoromethylation of 2-Substituted/Unsubstituted Aminonaphthoquinones at Room Temperature with Bench-Stable (CF3SO2)2Zn: Synthesis and Antiproliferative Evaluation

(2017) Jing Li et al.   JOURNAL OF ORGANIC CHEMISTRY

Base Catalysis Enables Access to α,α-Difluoroalkylthioethers

(2017) Douglas L. Orsi et al.   ORGANIC LETTERS

Cu-Catalyzed Stereoselective Borylation of gem-Difluoroalkenes with B2pin2

(2017) Juan Zhang et al.   ORGANIC LETTERS

Direct Approach to N-Substituted-2-Fluoroindoles by Sequential Construction of C–N Bonds from gem-Difluorostyrenes

(2017) Bin Zhang et al.   ORGANIC LETTERS

Nickel-Catalyzed Hydroalkenylation of Alkynes through C–F Bond Activation: Synthesis of 2-Fluoro-1,3-dienes

(2017) Junji Ichikawa et al.   SYNTHESIS-STUTTGART

Recent advances in the synthesis and CF functionalization of gem-difluoroalkenes

(2017) Xuxue Zhang et al.   TETRAHEDRON LETTERS

Copper Salt-Controlled Divergent Reactivity of [Cu]CF2PO(OEt)2with α-Diazocarbonyl Derivatives

(2016) Maria V. Ivanova et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Visible-light-initiated difluoromethylation of arene diazonium tetrafluoroborates

(2016) Ye-bin Wu et al.   CHEMICAL COMMUNICATIONS

Mild and Copper-Free Stereoselective Cyanation of gem -Difluoroalkenes by Using Benzyl Nitrile as a Cyanating Reagent

(2016) Juan Zhang et al.   CHEMISTRY-A EUROPEAN JOURNAL

Synthesis of fluorovinyl pyrazolyl (thio)ethers by the reaction of gem -difluoroalkenes with pyrazolin-5-ones (thiones)

(2016) Tao Huang et al.   JOURNAL OF FLUORINE CHEMISTRY

Visible-Light-Driven, Radical-Triggered Tandem Cyclization of o-Hydroxyaryl Enaminones: Facile Access to 3-CF2 /CF3-Containing Chromones

(2016) Haoyue Xiang et al.   ORGANIC LETTERS

Cobalt(III)-Catalyzed Regio- and Stereoselective α-Fluoroalkenylation of Arenes with gem-Difluorostyrenes

(2016) Lingheng Kong et al.   ORGANIC LETTERS

Synthesis of fluorovinyl aryl ethers by a three-component reaction of gem-difluoroalkenes with arylboronic acids and oxygen

(2015) Mingjin Wang et al.   RSC Advances

A Facile and General Approach to 3-((Trifluoromethyl)thio)-4H-chromen-4-one

(2014) Haoyue Xiang et al.   ORGANIC LETTERS

 -Fluorophosphonates reveal how a phosphomutase conserves transition state conformation over hexose recognition in its two-step reaction

(2014) Y. Jin et al.   PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA

The use of methyl 2,2-difluoro-2-(fluorosulfonyl)acetate as the difluorocarbene source to generate an in situ source of difluoromethylene triphenylphosphonium ylide

(2013) Charles S. Thomoson et al.   JOURNAL OF FLUORINE CHEMISTRY

Copper-Mediated, Palladium-Catalyzed Cross-Coupling of 3-Iodochromones, Thiochromones, and Quinolones with Ethyl Bromodifluoroacetate

(2013) Xiaodong Han et al.   JOURNAL OF ORGANIC CHEMISTRY

Synthesis of Alkyl Aryl(heteroaryl)acetates from N-Oxides, 1,1-Difluorostyrenes, and Alcohols

(2013) Rafał Loska et al.   ORGANIC LETTERS

AgF-Mediated Fluorinative Homocoupling of gem-Difluoroalkenes

(2013) Bing Gao et al.   ORGANIC LETTERS

Review on Modern Advances of Chemical Methods for the Introduction of a Phosphonic Acid Group

(2011) Charles S. Demmer et al.   CHEMICAL REVIEWS

Ni(II)/Zn Catalyzed Reductive Coupling of Aryl Halides with Diphenylphosphine Oxide in Water

(2011) Xinghua Zhang et al.   ORGANIC LETTERS

Metal-catalyzed additions of H–P(O) bonds to carbon–carbon unsaturated bonds

(2010) Qing Xu et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Why did Nature select phosphate for its dominant roles in biology?

(2010) Matthew W. Bowler et al.   NEW JOURNAL OF CHEMISTRY

Efficient Helicene Synthesis: Friedel–Crafts-type Cyclization of 1,1-Difluoro-1-alkenes

(2008) Junji Ichikawa et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION