Rapid Construction of Structurally Diverse Quinolizidines, Indolizidines, and Their Analogues via Ruthenium-Catalyzed Asymmetric Cascade Hydrogenation/Reductive Amination

Intramolecular Aza-Diels-Alder Reactions of ortho -Quinone Methide Imines: Rapid, Catalytic, and Enantioselective Assembly of Benzannulated Quinolizidines

(2018) Martin Kretzschmar et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Iridium-Catalyzed Intramolecular Asymmetric Allylic Alkylation of Hydroxyquinolines: Simultaneous Weakening of the Aromaticity of Two Consecutive Aromatic Rings

(2018) Ze-Peng Yang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis of the diarylindolizidine alkaloid (+)-Fistulopsine B: Application of an organocatalytic Michael addition reaction

(2018) N.V.G. Moorthy et al.   TETRAHEDRON

Enantioselective Total Synthesis of (+)-Gephyrotoxin 287C

(2017) Miriam Piccichè et al.   ORGANIC LETTERS

Iridium-catalyzed asymmetric hydrogenation of cyclic iminium salts

(2017) Yue Ji et al.   Organic Chemistry Frontiers

Nickel-Catalyzed Enantioselective Reductive Amination of Ketones with Both Arylamines and Benzhydrazide

(2016) Peng Yang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Stereoselective Synthesis of Tetrahydroindolizines through the Catalytic Formation of Pyridinium Ylides from Diazo Compounds

(2016) Jonathan Day et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Oxidative Rearrangement via in Situ Generated N-Chloroamine: Synthesis of Fused Tetrahydroisoquinolines

(2016) Kenichi Murai et al.   ORGANIC LETTERS

N-Heterocyclic Carbenes in Asymmetric Hydrogenation

(2016) Dongbing Zhao et al.   ACS Catalysis

Enantioselective Total Synthesis of (+)-Gephyrotoxin 287C

(2015) Tetsuhiro Nemoto et al.   ADVANCED SYNTHESIS & CATALYSIS

Substrate Activation in the Catalytic Asymmetric Hydrogenation ofN-Heteroarenes

(2015) Bugga Balakrishna et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Iridium-Catalyzed Intramolecular Asymmetric Allylic Dearomatization Reaction of Pyridines, Pyrazines, Quinolines, and Isoquinolines

(2015) Ze-Peng Yang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Dynamic Kinetic Asymmetric Amination of Alcohols: From A Mixture of Four Isomers to Diastereo- and Enantiopure α-Branched Amines

(2015) Zi-Qiang Rong et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Cascade Strategy Enables a Total Synthesis of (−)-Gephyrotoxin

(2014) Shuyu Chu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A highly efficient asymmetric synthesis of quaternary stereocenter-containing indolizidine and quinolizidine alkaloids using aldehydes, nitroalkenes, and unactivated cyclic ketimines

(2014) Yu Tan et al.   CHEMICAL COMMUNICATIONS

Strategies towards the synthesis of calyciphylline A-type Daphniphyllum alkaloids

(2014) Baldip Kang et al.   NATURAL PRODUCT REPORTS

Highly Enantioselective Synthesis of Chiral Tetrahydroquinolines and Tetrahydroisoquinolines by Ruthenium-Catalyzed Asymmetric Hydrogenation in Ionic Liquid

(2013) Zi-Yuan Ding et al.   ADVANCED SYNTHESIS & CATALYSIS

Ruthenium-NHC-Catalyzed Asymmetric Hydrogenation of Indolizines: Access to Indolizidine Alkaloids

(2013) Nuria Ortega et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Converting Cycloalkanones into N-Heterocycles: Formal Synthesis of (−)-Gephyrotoxin 287C

(2013) Simon Pichette et al.   JOURNAL OF ORGANIC CHEMISTRY

Catalytic Asymmetric Syntheses of Quinolizidines by Dirhodium-Catalyzed Dearomatization of Isoquinolinium/Pyridinium Methylides–The Role of Catalyst and Carbene Source

(2013) Xichen Xu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Formal Aza-Diels–Alder Reactions of Enones with Cyclic Imines Catalyzed by Primary Aminothioureas

(2013) Mathieu P. Lalonde et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric Hydrogenation of Heteroarenes and Arenes

(2011) Duo-Sheng Wang et al.   CHEMICAL REVIEWS

Highly Enantioselective Hydrogenation of Quinolines Using Phosphine-Free Chiral Cationic Ruthenium Catalysts: Scope, Mechanism, and Origin of Enantioselectivity

(2011) Tianli Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Convergent Asymmetric Disproportionation Reactions: Metal/Brønsted Acid Relay Catalysis for Enantioselective Reduction of Quinoxalines

(2011) Qing-An Chen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric Hydrogenation of 2- and 2,3-Substituted Quinoxalines with Chiral Cationic Ruthenium Diamine Catalysts

(2011) Jie Qin et al.   ORGANIC LETTERS

Highly Effective Asymmetric Hydrogenation of CyclicN-Alkyl Imines with Chiral Cationic Ru-MsDPEN Catalysts‡

(2011) Fei Chen et al.   ORGANIC LETTERS

Enantioselective Synthesis of Quinolizidines and Indolizidines via a Catalytic Asymmetric Hydrogenation Cascade

(2011) Magnus Rueping et al.   SYNLETT

Enantioselective access to (−)-indolizidines 167B, 209D, 239AB, 195B and (−)-monomorine from a common chiral synthon

(2011) Chada Raji Reddy et al.   TETRAHEDRON

Enantioselective Organocatalytic C−H Bond Functionalization via Tandem 1,5-Hydride Transfer/Ring Closure: Asymmetric Synthesis of Tetrahydroquinolines

(2010) Young Ku Kang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Total Synthesis of Indolizidine Alkaloid (−)-209D: Overriding Substrate Bias in the Asymmetric Rhodium-Catalyzed [2+2+2] Cycloaddition

(2009) Robert T. Yu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Asymmetric Hydrogenation of 5-Membered Heteroaromatics

(2009) Ryoichi Kuwano   HETEROCYCLES

Highly Enantioselective Iridium-Catalyzed Hydrogenation of 2-Benzylquinolines and 2-Functionalized and 2,3-Disubstituted Quinolines

(2009) Da-Wei Wang et al.   JOURNAL OF ORGANIC CHEMISTRY

Intramolecular Schmidt Reaction Involving Primary Azidoalcohols under Nonacidic Conditions: Synthesis of Indolizidine (−)-167B

(2009) Ajoy Kapat et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Convergent Stereoselective Synthesis of Quinolizidines and Indolizidines: Chemoselective Coupling of 2-Hydroxymethyl-Substituted Allylic Silanes with Imines

(2009) Dexi Yang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Enantioselective Intramolecular Redox Reactions: Ring-Fused Tetrahydroquinolines

(2009) Sandip Murarka et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Metal−Brønsted Acid Cooperative Catalysis for Asymmetric Reductive Amination

(2009) Chaoqun Li et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Hydrogenation of Quinolines Using a Recyclable Phosphine-Free Chiral Cationic Ruthenium Catalyst: Enhancement of Catalyst Stability and Selectivity in an Ionic Liquid

(2008) Haifeng Zhou et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Formal Total Synthesis of (+)-Gephyrotoxin

(2008) Marco Santarem et al.   JOURNAL OF ORGANIC CHEMISTRY

Iminium ion cascade reactions: stereoselective synthesis of quinolizidines and indolizidines

(2008) Shawn M. Amorde et al.   TETRAHEDRON

Indolizidine and quinolizidine alkaloids

(2007) Joseph P. Michael   NATURAL PRODUCT REPORTS