4.6 Article

A chemical sensor based on a photonic-crystal L3 nanocavity defined in a silicon-nitride membrane

Journal

JOURNAL OF MATERIALS CHEMISTRY C
Volume 2, Issue 41, Pages 8700-8706

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c4tc01320d

Keywords

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Funding

  1. European Commission via the Marie Curie Initial Training Network ICARUS [FP7-PEOPLE-ITN-2008-237900]
  2. UK EPSRC [EP/I028641/1]
  3. Kurdistan Regional Government
  4. EPSRC [EP/I028641/1] Funding Source: UKRI
  5. Engineering and Physical Sciences Research Council [EP/I028641/1] Funding Source: researchfish

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The application of a silicon-nitride based L3 optical nanocavity as a chemical sensor is explored. It is shown that by adjusting the thickness of an ultra-thin Lumogen Red film deposited onto the nanocavity surface, the fundamental optical mode undergoes a progressive red-shift as the layer-thickness increases, with the cavity being able to detect the presence of a single molecular monolayer. The optical properties of a nanocavity whose surface is coated with a thin layer of a porphyrin-based polymer are also explored. On exposure of the cavity to an acidic-vapour, it is shown that changes in the optical properties of the porphyrin-film (thickness and refractive index) can be detected through a reversible shift in the cavity mode wavelength. Such effects are described using a finite difference time-domain model.

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