Journal
MRS COMMUNICATIONS
Volume 4, Issue 4, Pages 171-175Publisher
CAMBRIDGE UNIV PRESS
DOI: 10.1557/mrc.2014.30
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Funding
- Natural Science and Engineering Research Council (NSERC) of Canada
- Canada Foundation for Innovation (CFI)
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Here we report a general method for the synthesis of layered inorganic nanocrystalline materials using graphene oxide (GO) film as the template. Free-standing three-dimensional (3D) lamellar ZnO, alpha-Fe2O3, and reduced GO/ZnO hybrid structures were synthesized as examples. Such layered structures could also be exfoliated to obtain 2D assembled nanocrystal microsheets. The abundant nucleation sites on the GO surface and the compact stacking of GO platelets made it possible to tightly control metal oxide crystal size (similar to 15 nm), alter preferential crystal growth direction, and assemble the nanocrystals into sheets, as confirmed by multiple characterization techniques.
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