Enediynes, enyne-allenes, their reactions, and beyond

Spin-state control of thermal and photochemical Bergman cyclization

(2013) Leigh J. K. Boerner et al.   CHEMICAL COMMUNICATIONS

Concerted Reactions That Produce Diradicals and Zwitterions: Electronic, Steric, Conformational, and Kinetic Control of Cycloaromatization Processes

(2013) Rana K. Mohamed et al.   CHEMICAL REVIEWS

How to Lose a Bond in Two Ways ― The Diradical/Zwitterion Dichotomy in Cycloaromatization Reactions

(2013) Paul W. Peterson et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Nonstatistical Dynamic Effects in the Thermal C2–C6 Diels–Alder Cyclization of Enyne–Allenes

(2013) Debabrata Samanta et al.   JOURNAL OF ORGANIC CHEMISTRY

Utilizing Redox-Mediated Bergman Cyclization toward the Development of Dual-Action Metalloenediyne Therapeutics

(2013) Sarah E. Lindahl et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Assembly of fused indenesvia Au(i)-catalyzed C1–C5 cyclization of enediynes bearing an internal nucleophile

(2012) Qiwen Hou et al.   CHEMICAL COMMUNICATIONS

A Total Synthesis Trilogy: Calicheamicin γ1I, Taxol®, and Brevetoxin A

(2012) K. C. Nicolaou et al.   CHEMICAL RECORD

Recent Developments in Enediyne Chemistry

(2012) Mukesh C. Joshi et al.   CHEMISTRY & BIODIVERSITY

Nucleophilic cyclizations of enediynes as a method for polynuclear heterocycle synthesis

(2012) A. V. Gulevskaya et al.   Chemistry of Heterocyclic Compounds

Functionalization of Pristine Graphene with Conjugated Polymers through Diradical Addition and Propagation

(2012) Xiaowei Ma et al.   Chemistry-An Asian Journal

Syntheses, Thermal Reactivities, and Computational Studies of Aryl-Fused Quinoxalenediynes: Effect of Extended Benzannelation on Bergman Cyclization Energetics

(2012) John D. Spence et al.   JOURNAL OF ORGANIC CHEMISTRY

Mechanistic Investigation of Enediyne-Connected Amino Ester Rearrangement. Theoretical Rationale for the Exclusive Preference for 1,6- or 1,5-Hydrogen Atom Transfer Depending on the Substrate. A Potential Route to Chiral Naphthoazepines

(2012) Damien Campolo et al.   JOURNAL OF ORGANIC CHEMISTRY

Hybrids of amino acids and acetylenic DNA-photocleavers: optimising efficiency and selectivity for cancer phototherapy

(2012) Boris Breiner et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

When the nine-membered enediynes play hide and seek

(2012) Mickaël Jean et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Ambient Schmittel Cyclization Promoted by Chemoselective Triazole-Gold Catalyst

(2012) Qiaoyi Wang et al.   ORGANIC LETTERS

The Role of Gold Acetylides as a Selectivity Trigger and the Importance of gem-Diaurated Species in the Gold-Catalyzed Hydroarylating-Aromatization of Arene-Diynes

(2012) A. Stephen K. Hashmi et al.   ORGANOMETALLICS

Cyclizations of Alkynes: Revisiting Baldwin’s Rules for Ring Closure

(2011) Kerry Gilmore et al.   CHEMICAL REVIEWS

Conformational and Electronic Consequences in Crafting Extended, π-Conjugated, Light-Harvesting Macrocycles

(2011) Leigh J. K. Boerner et al.   CHEMISTRY-A EUROPEAN JOURNAL

Structural and conformational features relevant to the anti-tumor activity of calicheamicin γ 1I

(2011) George A. Ellestad   CHIRALITY

Pilot applications of internally contracted multireference coupled cluster theory, and how to choose the cluster operator properly

(2011) Matthias Hanauer et al.   JOURNAL OF CHEMICAL PHYSICS

The bergman cyclizations of the enediyne and its N-substituted analogs using multiconfigurational second-order perturbation theory

(2011) Hua Dong et al.   JOURNAL OF COMPUTATIONAL CHEMISTRY

Engineering pH-Gated Transitions for Selective and Efficient Double-Strand DNA Photocleavage in Hypoxic Tumors

(2011) Wang-Yong Yang et al.   JOURNAL OF MEDICINAL CHEMISTRY

Cytotoxic 1,2-Dialkynylimidazole-Based Aza-Enediynes: Aza-Bergman Rearrangement Rates Do Not Predict Cytotoxicity

(2011) Christophe Laroche et al.   JOURNAL OF MEDICINAL CHEMISTRY

The thermal C2-C6 (Schmittel)/ene cyclization of enyne-allenes - crossing the boundary between classical and nonstatistical kinetics

(2011) Michael Schmittel et al.   JOURNAL OF PHYSICAL ORGANIC CHEMISTRY

Synthesis of dendronized polymers through bergman cyclization of enediyne-containing Frechet-type dendrimers

(2011) Jianguo Ma et al.   JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY

Experimental and Computational Evidence for Gold Vinylidenes: Generation from Terminal Alkynes via a Bifurcation Pathway and Facile C–H Insertions

(2011) Longwu Ye et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Bergman Cyclization in Polymer Chemistry and Material Science

(2011) Yuli Xiao et al.   MACROMOLECULAR RAPID COMMUNICATIONS

Synthesis of the Carboline Disaccharide Domain of Shishijimicin A

(2011) K. C. Nicolaou et al.   ORGANIC LETTERS

Selectivity in Garratt−Braverman Cyclization: An Experimental and Computational Study

(2011) Manasi Maji et al.   ORGANIC LETTERS

Design strategy of enediynes and enyne-allenes

(2011) I. A. Maretina   RUSSIAN JOURNAL OF GENERAL CHEMISTRY

The Cope rearrangement-the first born of a great family

(2011) Nicole Graulich   Wiley Interdisciplinary Reviews-Computational Molecular Science

Møller-Plesset perturbation theory: from small molecule methods to methods for thousands of atoms

(2011) Dieter Cremer   Wiley Interdisciplinary Reviews-Computational Molecular Science

Thermochemical Properties of the Benzynes

(2010) Paul G. Wenthold   AUSTRALIAN JOURNAL OF CHEMISTRY

The Benzyne Story

(2010) Curt Wentrup   AUSTRALIAN JOURNAL OF CHEMISTRY

Multireference general-model-space state-universal and state-specific coupled-cluster approaches to excited states

(2010) Xiangzhu Li et al.   JOURNAL OF CHEMICAL PHYSICS

Bergman Cyclization of Acyclic Amino Acid Derived Enediynes Leads to the Formation of 2,3-Dihydrobenzo[f]isoindoles

(2010) Matija Gredičak et al.   JOURNAL OF ORGANIC CHEMISTRY

Theoretical Studies on Myers−Saito and Schmittel Cyclization Mechanisms of Hepta-1,2,4-triene-6-yne

(2010) Shogo Sakai et al.   JOURNAL OF PHYSICAL CHEMISTRY A

Total Synthesis of Sporolide B and 9-epi-Sporolide B

(2010) K. C. Nicolaou et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Complexity and simplicity in the biosynthesis of enediyne natural products

(2010) Zhao-Xun Liang   NATURAL PRODUCT REPORTS

Pharmacology and Therapeutic Applications of Enediyne Antitumor Antibiotics

(2010) Rong-Guang Shao   Current Molecular Pharmacology

Carbocyclisation of alkynes with external nucleophiles catalysed by gold, platinum and other electrophilic metals

(2009) Shariar Md. Abu Sohel et al.   CHEMICAL SOCIETY REVIEWS

The art of total synthesis through cascade reactions

(2009) K. C. Nicolaou et al.   CHEMICAL SOCIETY REVIEWS

Heuristic thinking makes a chemist smart

(2009) Nicole Graulich et al.   CHEMICAL SOCIETY REVIEWS

Synthesis of a Core Carbon Framework of Cyanosporasides A and B

(2009) Daisuke Aburano et al.   JOURNAL OF ORGANIC CHEMISTRY

Inspirations, Discoveries, and Future Perspectives in Total Synthesis

(2009) K. C. Nicolaou   JOURNAL OF ORGANIC CHEMISTRY

Molecular dynamics simulations investigation of neocarzinostatin chromophore-releasing pathways from the holo-NCS protein

(2009) Xi Zhao et al.   JOURNAL OF STRUCTURAL BIOLOGY

Total Synthesis and Structure Revision of the (−)-Maduropeptin Chromophore

(2009) Kazuo Komano et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Production of Octaketide Polyenes by the Calicheamicin Polyketide Synthase CalE8: Implications for the Biosynthesis of Enediyne Core Structures

(2009) Katherine Belecki et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Antitumor Compounds from Marine Actinomycetes

(2009) Carlos Olano et al.   Marine Drugs

Structural basis for biosynthetic programming of fungal aromatic polyketide cyclization

(2009) Jason M. Crawford et al.   NATURE

The self-interaction error and the description of non-dynamic electron correlation in density functional theory

(2009) Jürgen Gräfenstein et al.   THEORETICAL CHEMISTRY ACCOUNTS

Sodium-coupled Monocarboxylate Transporters in Normal Tissues and in Cancer

(2008) Vadivel Ganapathy et al.   AAPS Journal

Total Synthesis of the C-1027 Chromophore Core: Extremely Facile Enediyne Formation through SmI2-Mediated 1,2-Elimination

(2008) Masayuki Inoue et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

From nature to the laboratory and into the clinic

(2008) K.C. Nicolaou et al.   BIOORGANIC & MEDICINAL CHEMISTRY

Towards Photoswitchable Enediyne Antibiotics: Single and Two-Photon Triggering of Bergman Cyclization

(2008) Andrei Polukhtine et al.   CURRENT TOPICS IN MEDICINAL CHEMISTRY

Biosynthesis of Enediyne Antitumor Antibiotics

(2008) Steven Van Lanen et al.   CURRENT TOPICS IN MEDICINAL CHEMISTRY

Efficient and Accurate Characterization of the Bergman Cyclization for Several Enediynes Including an Expanded Substructure of Esperamicin A1

(2008) Edward C. Sherer et al.   JOURNAL OF PHYSICAL CHEMISTRY B

Design of a New Warhead for the Natural Enediyne Dynemicin A. An Increase of Biological Activity

(2008) Elfi Kraka et al.   JOURNAL OF PHYSICAL CHEMISTRY B

Thermal C1−C5Diradical Cyclization of Enediynes

(2008) Chandrasekhar Vavilala et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Deconstruction of Iterative Multidomain Polyketide Synthase Function

(2008) J. M. Crawford et al.   SCIENCE

Preparation of enediyne-crosslinked networks and their reactivity under thermal and mechanical conditions

(2008) Charles R. Hickenboth et al.   TETRAHEDRON