The thermal C2-C6 (Schmittel)/ene cyclization of enyne-allenes - crossing the boundary between classical and nonstatistical kinetics

Synthesis of 5-(2-methoxy-1-naphthyl)- and 5-[2-(methoxymethyl)-1-naphthyl]-11H-benzo[b]fluorene as 2,2'-disubstituted 1,1'-binaphthyls via benzannulated enyne–allenes

(2011) Yu-Hsuan Wang et al.   Beilstein Journal of Organic Chemistry

Nucleophilic Cycloaromatization of Ynamide-Terminated Enediynes

(2010) Andrei Poloukhtine et al.   JOURNAL OF ORGANIC CHEMISTRY

Theoretical Studies on Myers−Saito and Schmittel Cyclization Mechanisms of Hepta-1,2,4-triene-6-yne

(2010) Shogo Sakai et al.   JOURNAL OF PHYSICAL CHEMISTRY A

Experimental Evidence for Heavy-Atom Tunneling in the Ring-Opening of Cyclopropylcarbinyl Radical from Intramolecular12C/13C Kinetic Isotope Effects

(2010) Ollie M. Gonzalez-James et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Design and synthesis of bisenediyne bissulfones and their reactivity under basic condition

(2009) Sanket Das et al.   BIOORGANIC & MEDICINAL CHEMISTRY LETTERS

Dual reactivity of a photochemically-generated cyclic enyne–allene

(2009) Alexander V. Kuzmin et al.   CHEMICAL COMMUNICATIONS

The Photochemical C2−C6Cyclization of Enyne−Allenes: Interception of the Fulvene Diradical with a Radical Clock Ring Opening

(2009) Götz Bucher et al.   JOURNAL OF ORGANIC CHEMISTRY

Bifurcations on Potential Energy Surfaces of Organic Reactions

(2008) Daniel H. Ess et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Internal amide-triggered cycloaromatization of maduropeptin-like nine-membered enediyne

(2008) Yutaro Norizuki et al.   CHEMICAL COMMUNICATIONS

Structure Modulated Electronic Contributions to Metalloenediyne Reactivity: Synthesis and Thermal Bergman Cyclization of MLX2Compounds

(2008) Sibaprasad Bhattacharyya et al.   INORGANIC CHEMISTRY

Thermal C2−C6Cyclization of Enyne−Carbodiimides:  Experimental Evidence Contradicts a Diradical and Suggests a Carbene Intermediate

(2008) Michael Schmittel et al.   JOURNAL OF ORGANIC CHEMISTRY

Photochemical C2−C6Cyclization of Enyne−Allenes: Detection of a Fulvene Triplet Diradical in the Laser Flash Photolysis

(2008) Götz Bucher et al.   JOURNAL OF ORGANIC CHEMISTRY

Efficient and Accurate Characterization of the Bergman Cyclization for Several Enediynes Including an Expanded Substructure of Esperamicin A1

(2008) Edward C. Sherer et al.   JOURNAL OF PHYSICAL CHEMISTRY B

Design of a New Warhead for the Natural Enediyne Dynemicin A. An Increase of Biological Activity

(2008) Elfi Kraka et al.   JOURNAL OF PHYSICAL CHEMISTRY B

Enhancement of the Reactivity of Photochemically Generated Enediynes via Keto−Enol Tautomerization

(2008) Grigori Karpov et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Thermal C1−C5Diradical Cyclization of Enediynes

(2008) Chandrasekhar Vavilala et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Photochemical Generation and Reversible Cycloaromatization of a Nine-Membered Ring Cyclic Enediyne

(2008) Dinesh R. Pandithavidana et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis and aromatisation of cyclic enediyne-containing amino acids

(2008) Jasper Kaiser et al.   ORGANIC & BIOMOLECULAR CHEMISTRY