Journal
RSC ADVANCES
Volume 8, Issue 58, Pages 33059-33064Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8ra06576d
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Funding
- USDA-NIFA Specialty Crop Research Initiative Award [2016-51181-25403]
- USDA-ARS Specific Corporative Agreement [S51600000035794]
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A facile and template-free solvothermal method was developed as a bottom-up approach to synthesize mesoporous/macroporous MOF nanosheets in a simple and scalable way. It was found that starting coordination complexes of different copper(II)-ligand compounds mediated the controlled growth and morphology of MOF crystals. By controlling the size and shape of the MOF crystals, the possibility to adjust and tailor the structure and performances of the assemblies was demonstrated. This work provides a bottom-up approach to synthesize MOF films and nanosheets in a simple and scalable way, which may have potential in energy and biomedical applications.
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