Journal
RSC ADVANCES
Volume 4, Issue 77, Pages 40782-40787Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4ra07201d
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Funding
- Ministry of Science and Technology of China [2011ZX02703]
- Natural Science Foundation of China (NSFC) [21374131]
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A new polymer with low dielectric constant is reported here. This polymer contains a trifluoromethyl-substituted phenyl unit and a binaphthyl unit, and shows high thermostability with a glass transition temperature of 244 degrees C and a 5 wt% loss at temperature 518 degrees C under nitrogen. The polymer also exhibits good film-forming ability, and the formed films exhibit high hydrophobicity with a contact angle of 103.6 degrees with water. In a range of frequencies from 1 to 25 MHz, the polymer reveals an average dielectric constants of about 2.56. In regard to the mechanical properties, the polymer film shows an average hardness of 0.37 GPa and a Young's modulus of 15.07 GPa. These results indicate that the polymer could be used as a varnish for enameled wire, sizing agents for high-performance carbon fiber, and the matrix resin for the production of laminated composites utilized in the printed-circuit-board (PCB) industry.
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