Article
Chemistry, Multidisciplinary
Jakub Karcz, Natan Rychlowicz, Malgorzata Czarnecka, Antoni Kocot, Jakub Herman, Przemyslaw Kula
Summary: This article introduces a compound with unique physical properties, and reports on its design, synthesis, and physicochemical properties. It is the first example of a compound exhibiting an enantiotropic ferroelectric nematic phase.
CHEMICAL COMMUNICATIONS
(2023)
Article
Chemistry, Physical
Stevie Brown, Ewan Cruickshank, John M. D. Storey, Corrie T. Imrie, Damian Pociecha, Magdalena Majewska, Anna Makal, Ewa Gorecka
Summary: This study reports liquid-crystal materials with up to three nematic phases, each exhibiting different properties such as ferroelectric order, apolar order, and local antiferroelectric order. The modification of molecular structure through increasing lateral fluorine substituents leads to a direct isotropic-ferronematic phase transition in one of the materials.
Article
Chemistry, Multidisciplinary
A. Vahedi, R. Vafaie, M. S. Zakerhamidi, H. Tajalli
Summary: Recent progress in studying the effects of MgO nanoparticle doping on 6CHBT liquid crystals showed that adding a certain concentration of nanoparticles can decrease dielectric anisotropy and improve the temperature-dependent dielectric properties.
Article
Chemistry, Physical
Malek Fouzai, Philippe Dieudonne-George, Ahlem Guesmi, Naoufel Ben Hamadi, Youssef Arfaoui, Taoufik Soltani, Yves Chevalier
Summary: In order to investigate structure-activity relationships in hydrogen bonded liquid crystals, a new short-chained (7 carbon atoms) fluorinated hydrogen-bonded liquid crystal, 4-heptyloxy-2-fluorobenzoic acid (7OBAF), was prepared. The phase sequence of two crystalline, a nematic, and the isotropic phases was revealed by differential scanning calorimetry, polarized optical microscopy, and X-ray diffraction. Dielectric spectroscopy of the nematic phase in the frequency range of 1 Hz-6 MHz showed a low frequency mode related to ferroelectric clusters and induced a high polarization in agreement with the results of dielectric measurements. The DFT calculations using the Maier-Meier relationship were consistent with the dielectric measurements and revealed the parallel molecular distribution, dipole moment, polarization anisotropy, birefringence, and dielectric anisotropy. Intermolecular hydrogen bonds between the fluorine substituent and the aromatic hydrogen atoms were also identified.
JOURNAL OF MOLECULAR LIQUIDS
(2023)
Article
Multidisciplinary Sciences
Rodrigo C. Coelho, Nuno A. M. Araujo, Margarida M. Telo da Gama
Summary: This paper investigates the competition between interfacial alignment driven by the elastic anisotropy of passive nematics and active anchoring in active nematics. Simulation results show that active anchoring dominates in most cases, with elastic anisotropy affecting the active length but not the dynamics.
PHILOSOPHICAL TRANSACTIONS OF THE ROYAL SOCIETY A-MATHEMATICAL PHYSICAL AND ENGINEERING SCIENCES
(2021)
Article
Chemistry, Physical
A. Benali, M. Bejar, E. Dhahri, M. P. F. Graca, M. A. Valente, E. K. Hlil, B. F. O. Costa
Summary: Two nanoparticle orthoferrite materials were successfully synthesized, and the insertion of Bismuth and Titanium ions in A and B-sites was found to affect structural, dielectric, and magnetic properties. Both compounds showed a giant dielectric constant and low dielectric loss tangent, with two relaxation processes observed at different temperature ranges. Introduction of Titanium ions in B-site enhanced magnetization and decreased the Curie Weis temperature.
JOURNAL OF ALLOYS AND COMPOUNDS
(2021)
Article
Chemistry, Physical
Tuhin Samanta, Dmitry V. Matyushov
Summary: This study confirms the Kivelson-Madden equation connecting single-particle and collective dielectric relaxation times through the Kirkwood factor using molecular dynamics simulations of two water models, SPC/E and TIP3P. It is found that the electric field primarily affects the rotational dynamics of individual water molecules, while the alteration of the Kirkwood factor has insignificant impact on water. Nonlinear dielectric relaxation theories should mainly account for the effect of the electric field on the rotation of single dipoles in a polar liquid.
JOURNAL OF MOLECULAR LIQUIDS
(2022)
Article
Materials Science, Multidisciplinary
Shirsendu Mitra, Mitali Basak
Summary: Substantial advancements have been made in the research and development of Localized Surface Plasmon Resonance (LSPR), particularly in the field of anisotropic plasmonic nanoparticles. These nanoparticles have a wide range of applications in biosensors, photothermal therapies, photocatalysis, and various other fields. Despite the abundance of literature available, there is a need for a comprehensive review focusing on recent advances in plasmonic particle anisotropy, plasmonic nanostructures, and their applications in biosensing.
Article
Chemistry, Physical
Amid Ranjkesh, Neda Ebrahimpour, Mohammad Sadegh Zakerhamidi, Seyed Masoud Seyedahmadian
Summary: In this study, the temperature-dependent dielectric constants and dielectric anisotropy of tungsten oxide nanoparticles doped into a nematic liquid crystal were investigated. The shape and concentration of the nanoparticles were found to significantly impact the temperature-dependent dielectric properties in the nanoparticle-nematic liquid crystal systems.
JOURNAL OF MOLECULAR LIQUIDS
(2022)
Article
Chemistry, Multidisciplinary
Shweta Mishra, V. Manjuladevi, R. K. Gupta, Sandeep Kumar
Summary: By incorporating CdS nanowires into nematic liquid crystal, the weakly first-order discontinuous isotropic-nematic phase transition evolves into a continuous phase transition, affecting the dielectric permittivity and bulk conductivity. In addition, the nanocomposites show increased ionic conductivity with higher concentrations of CdS nanowires.
Article
Crystallography
Alexander Tkach, Sebastian Zlotnik, Paula M. Vilarinho
Summary: Our study found that both lithium and manganese doping in KTaO3 induce strong low-frequency dielectric relaxations, following the Arrhenius law with activation energy values of approximately 77 and 107 meV, respectively. The relaxation dynamics were attributed to dipoles formed by off-centre Li-K(+) and Mn-K(2+) ions.
Article
Chemistry, Physical
Xuzhong Zuo, Enjie He, Yanfu Qin, Banggui Guan, Gaochao Zhao, Jie Wu, Zhenzhen Hui, Jie Yang, Xuebin Zhu, Jianming Dai
Summary: In this paper, the structural, multiferroic, dielectric, and optical properties of Aurivillius Bi6Fe1.5Co0.5Ti3-xWxO18 (0 <= x <= 0.07) ceramics were investigated. The doping of W6+ ions promoted grain growth and induced c-axis orientation. The magnetic and ferroelectric properties were affected by the doping level, Fe2+-O-Fe3+ exchange, oxygen vacancy, grain size, and orientation. The dielectric and optical properties were also influenced by the doping.
JOURNAL OF ALLOYS AND COMPOUNDS
(2022)
Article
Chemistry, Physical
Anu, Depanshu Varshney, Kamlesh Yadav, Jai Prakash, Harikesh Meena, Gautam Singh
Summary: In this study, ferroelectric layered perovskite Bi4Ti3O12 (BT4) nanoparticles were synthesized and their temperature-dependent dielectric and electro-optical properties in 4-pentyl-4'-cyanobiphenyl (5CB) nematic liquid crystal were investigated. The BT4 nanoparticles were uniformly dispersed in the 5CB matrix without agglomeration. The optical memory of the 5CB-BT4 composite was decreased compared to 5CB, and the dielectric parameters were estimated using dielectric spectroscopy. The anisotropy of the dielectric properties decreased in the 5CB-BT4 composite, and the DC conductivity increased four times compared to 5CB. This study demonstrates the tunability of the dielectric and optical memory features of the 5CB matrix by doping BT4 nanoparticles.
JOURNAL OF MOLECULAR LIQUIDS
(2023)
Article
Chemistry, Multidisciplinary
Zhen Zhang, Fang Chen, Jiwen Feng, Junfei Chen, Li Chen, Zhi Zhang, Huijuan Wang, Xin Cheng, Maili Liu, Chaoyang Liu
Summary: The study investigated the surface properties of nanodiamond (ND) using electron spin resonance (ESR) and Raman methods, and explored the enhancement of H-1 Overhauser DNP (ODNP) using ND as a polarizer with different nanoparticle sizes and concentrations. The results showed a negative correlation between nanoparticle sizes and the Raman peak intensity ratio of sp(2)/sp(3) hybridization, and a positive correlation with enhancement. Additionally, a significant -22.5-fold H-1 ODNP enhancement was achieved with ND in-situ liquid at room temperature, indicating potential for ND as an efficient enhancer.
CHINESE CHEMICAL LETTERS
(2021)
Article
Chemistry, Multidisciplinary
Pratibha Tripathi, Rahul Uttam, Sandeep Kumar, Roman Dabrowski, Ravindra Dhar
Summary: This study examines the thermodynamic, dielectric, and electro-optical properties of a room temperature nematic liquid crystal mixed with surface-stabilized gold nanoparticles. The results show that the addition of nanoparticles decreases the transition temperature of the liquid crystal and enhances its dielectric anisotropy. The study also identifies a relaxation mode in the dielectric behavior, caused by the flip-flop motion of the nematic molecules.
Article
Astronomy & Astrophysics
C. J. Nelson, S. Krishna Prasad, M. Mathioudakis
ASTRONOMY & ASTROPHYSICS
(2020)
Article
Chemistry, Physical
Rajalaxmi Sahoo, D. S. Shankar Rao, U. S. Hiremath, C. Yelamaggad, S. Krishna Prasad
JOURNAL OF PHYSICAL CHEMISTRY C
(2020)
Editorial Material
Materials Science, Multidisciplinary
Kamlendra Awasthi, Rabibrata Mukherjee, S. Krishna Prasad
BULLETIN OF MATERIALS SCIENCE
(2020)
Article
Chemistry, Physical
Marlin Baral, S. Krishna Prasad, Sachin A. Bhat, Rashmi A. Nayak, C. V. Yelamaggad
Editorial Material
Chemistry, Physical
S. Krishna Prasad, Marlin Baral, Sachin A. Bhat, C. V. Yelamaggad, Rashmi A. Nayak
Article
Chemistry, Multidisciplinary
Sutapa Chakraborty, Abhijit Shyam, Paritosh Mondal, S. Krishna Prasad, D. S. Shankar Rao, Chira R. Bhattacharjee
Summary: Three new series of hemi-discoid oxovanadium(IV) and copper(II) complexes based on halogen-substituted 'salphen' type ligands were synthesized and studied for their mesomorphic properties. While the fluoro and chloro substituted oxovanadium(IV) complexes exhibited thermotropic columnar rectangular mesophases, the bulky bromo substituted oxovanadium(IV) complexes decomposed at high temperature. The copper(II) complexes did not show mesomorphic behavior. The molecular arrangements in the mesophases were proposed, and the influence of metal coordination and spacer substituent on the mesomorphic properties was discussed. Density functional theory calculations revealed the geometric structures of the complexes.
Article
Chemistry, Physical
G. V. Varshini, D. S. Shankar Rao, Uma S. Hiremath, C. Yelamaggad, S. Krishna Prasad
Summary: This study explores the dielectric and viscoelastic behavior of a binary system consisting of rigid core and soft-bent nematogens, highlighting the propensity of soft-bent materials towards twist-bend structures. The research reveals various concentration-dependent changes in elastic constants, viscosity, and thermal variation of permittivity, attributed to conformational changes and cluster formations unique to bent structures exhibiting liquid crystallinity.
JOURNAL OF MOLECULAR LIQUIDS
(2021)
Article
Astronomy & Astrophysics
S. Krishna Prasad, T. Van Doorsselaere
Summary: The study utilizing high-resolution EUV imaging observations reveals that sloshing oscillations can transform into standing waves, confirming recent numerical studies. By introducing a new analytical expression, the oscillation properties were successfully extracted, showing substantial plasma cooling during the oscillation.
ASTROPHYSICAL JOURNAL
(2021)
Article
Chemistry, Physical
Priyanka Kanth, D. S. Shankar Rao, S. Krishna Prasad, Bachcha Singh
Summary: A series of substituted aroylhydrazones with different positions and quantities of alkoxy chains have been synthesized, and the transition of different columnar mesophases during the self-assembly process has been observed. The substitution pattern has an influence on photophysical properties and gel formation, indicating the potential application of these molecules in organic optoelectronic functional materials and devices.
JOURNAL OF MOLECULAR LIQUIDS
(2022)
Article
Chemistry, Physical
Pragnya Satapathy, Navyashree Vasudeva, James Oinam, Subbarao Krishna Prasad
Summary: It is demonstrated that dispersing CdSeS gradient quantum dots in a nematic liquid crystal and confining them in a polymer network leads to ordered linear assembly, enhancing the photoluminescence and introducing anisotropy in emission magnitude. The presence of a high frequency AC field and photoisomerizable azobenzene derivative further enables on-demand and light-driven modulation of photoluminescence.
JOURNAL OF MOLECULAR LIQUIDS
(2022)
Article
Chemistry, Multidisciplinary
G. V. Varshini, Pragnya Satapathy, D. S. Shankar Rao, S. Krishna Prasad
Summary: The study highlights the importance of liquid crystals as model materials for observing re-entrant phases, and discusses recent results and new research on stabilizing liquid crystal phases through additives and photoisomerisation associated shape change. The combination of nanophase segregation mechanism and the frustrated spin gas model can explain most observations, but additional mechanisms may be needed to fully understand the phase diagram obtained in temperature - intensity of actinic light phase spaces.
Article
Chemistry, Multidisciplinary
Pragnya Satapathy, Raghavendra Adiga, Monish Kumar, Gurumurthy Hegde, S. Krishna Prasad
Summary: Incorporating porous carbon nanoparticles (PCNs) into polydimethylsiloxane (PDMS) films has shown better near infrared-driven photomechanical actuation than films containing carbon nanostructures like carbon nanotubes and graphene. The specific surface area of the pores and the quantity of the curing agent polymerizing the PDMS play important roles in influencing the actuation magnitude. Additionally, backing the PDMS film with an ultrathin gold layer can enhance actuation and control the direction of actuation.
JOURNAL OF NANOSTRUCTURE IN CHEMISTRY
(2022)
Article
Chemistry, Physical
Indrajit Mondal, S. Kiruthika, Mukhesh K. Ganesha, Marlin Baral, Ankush Kumar, S. Vimala, P. Lakshmi Madhuri, Geetha G. Nair, S. Krishna Prasad, Ashutosh K. Singh, Giridhar U. Kulkarni
Summary: This study successfully developed LC smart windows using a low-cost hybrid TCE as an alternative to traditional ITO, showing no compromise in device performance. The theoretical modeling supported the construction of a uniform electric field, enhancing the operation efficiency of LC devices. The technology demonstrated high transparency modulation and long-term stability, suitable for scalable commercial applications.
JOURNAL OF MATERIALS CHEMISTRY A
(2021)
Article
Chemistry, Multidisciplinary
Sachin A. Bhat, D. S. Shankar Rao, S. Krishna Prasad, Channabasaveshwar Yelamaggad
Summary: Recent research has focused on the potential of chiral plasmonic superstructures resulting from directed self-assembly of optically active metal nanoparticles (MNPs) for various technological applications. Strategic efforts have led to the successful realization of monodisperse LC-gold NPs (LC-GNPs) self-assembling into a fluid/frozen lamellar structure exhibiting CD activity, which could play a crucial role in the development of metamaterials in the visible region.
NANOSCALE ADVANCES
(2021)
Article
Chemistry, Multidisciplinary
Sumana Mandal, Ravindra Kumar Gupta, Suraj Kumar Pathak, D. S. Shankar Rao, S. Krishna Prasad, Achalkumar Ammathnadu Sudhakar, Chandan K. Jana
Summary: This study reports the synthesis and evaluation of a new class of pyrrolinium-based ionic liquid crystals, which were prepared through functionalization of pyrrolidine and found to stabilize numerous mesophases over a wide thermal range including room temperature.
NEW JOURNAL OF CHEMISTRY
(2021)