Journal
RSC ADVANCES
Volume 4, Issue 101, Pages 57869-57874Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4ra10573g
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Funding
- 973 Program of China [2013CBA01602, 2014CB239701, 2013CB328804]
- Natural Science Foundation of China [61235007, 61171037, 21174083, 21102091, 21372155]
- Ph.D. Programs Foundation of Ministry of Education of China for Young Scholars [20110073120039]
- Shanghai Leading Academic Discipline Project [J51503]
- ShuGuang Project [11SG54]
- Shanghai Talent Development Funding [201335]
- Program for Professor of Special Appointment (Eastern Scholar)
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Two-dimensional graphene/SnO2/graphene (G/SnO2/G) hybrids with SnO2 nanoparticles sandwiched in graphene sheets have been constructed by a facile ionic self-assembly process. The resulting G/SnO2/G hybrids possessed flexible and ultrathin graphene shells that effectively enwrapped the SnO2 nanoparticles. When the hybrids were used as the anode materials in lithium-ion batteries (LIBs), their unique core-shell architecture provided double protection against the aggregation and volume changes of SnO2 nanoparticles, and ensured favorable transport kinetics for charge carriers. As a result, the hybrids exhibited a superior cycling stability (600 mA h g(-1) over 60 cycles) and excellent rate capability (120 mA h g(-1) at 5.0 A g(-1)).
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