Journal
RSC ADVANCES
Volume 4, Issue 66, Pages 34793-34800Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4ra05555a
Keywords
-
Categories
Ask authors/readers for more resources
The influence of the charge anisotropy and platelet size on the formation of gel and glass states and nematic phases in suspensions of plate-like particles is investigated using Monte Carlo simulations in the canonical ensemble. The platelets are modeled as discs with charged sites distributed on a hexagonal lattice. The edge sites can carry a positive charge, while the remaining sites are negatively charged giving rise to a charge anisotropy. A screened Coulomb potential plus a short range repulsive potential are used to describe the interactions between the sites of the platelets. The liquid-gel transition is found to be favored by a high charge anisotropy and by large particles. Oppositely, the liquid-glass transition is favored for small particles without charge anisotropy, i.e., fully negatively charged. Finally, we find that the isotropic/nematic transition is disfavored by the charge anisotropy. For a strong charge anisotropy, the nematic phase does not form and, instead, a gel/columnar transition is found.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available