Journal
RSC ADVANCES
Volume 4, Issue 90, Pages 49165-49169Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4ra08669d
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Funding
- Beijing Natural Science Foundation [2144045]
- Beijing Municipal Education Commission Foundation [KM201410028007]
- National Natural Science Foundation of China [21402128]
- Scientific Research Base Development Program of the Beijing Municipal Commission of Education
- Capital Normal University
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An unprecedented thiolating system K2S2O8/arenesulfinate is described for selective sulfenylation of indoles in CH3CN/H2O. This metal-free strategy enables a simple, efficient and environment-benign approach to the pharmaceutically important candidates, 3-arylthioindoles. Catalytically reactive halogen and aryl groups are well tolerated.
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