4.6 Article

An efficient noble metal-free Ce-Sm/SiO2 nano-oxide catalyst for oxidation of benzylamines under ecofriendly conditions

Journal

RSC ADVANCES
Volume 4, Issue 86, Pages 46378-46382

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c4ra04397a

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Funding

  1. Council of Scientific and Industrial Research (CSIR), New Delhi

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A nanosized Ce-Sm/SiO2 catalyst was found to show an outstanding performance in the oxidation of benzylamines into valuable dibenzylimine products with almost 100% selectivity with O-2 as the green oxidant under solvent-free conditions, which is attributed to the presence of abundant strong acidic sites, enhanced oxygen vacancy concentration, and superior BET surface area.

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