Journal
RSC ADVANCES
Volume 4, Issue 58, Pages 30712-30717Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4ra02426e
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- CSIR, New Delhi, India
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1,2,2,4-Tetramethyldihydroquinoline (TMDQ) is formylated at the 6-position and the resulting quinoline aldehyde is condensed with 3-methyl-1-phenyl-1H-pyrazol-5(4H)-one to obtain a merocyanine 6-pyrazolinyl TMDQ. The merocyanine is a selective and sensitive sensor for hydrazine hydrate in aqueous ethanolic medium and also for hydrazine gas. The merocyanine detects hydrazine hydrate selectively in less than 5 s over other amines, anions, and metals. The detection can be done simply by the naked eye and quantification can be done by absorbance/fluorescence spectroscopy. Hydrazine hydrate as well as hydrazine gas can be detected by the TLC plate technique.
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