Article
Materials Science, Ceramics
Yuanyuan Wang, Hongbo Liu, Tingnan Yan, Jianwei Zhao, Shifeng Guo, Rong Sun, Zhilun Lu, Dawei Wang
Summary: In this study, Nb-doped 0.75SrTiO(3)-0.25BiFeO(3) (ST-BF) lead-free ceramics were designed and synthesized, and the effects of Nb doping on microstructure, dielectric, and electrical properties were investigated. It was found that Nb doping led to changes in crystal structure, grain size, and improved dielectric properties, with the 0.03 Nb-doped ST-BF composition exhibiting low dielectric loss and stable dielectric constant. Impedance spectroscopy analysis showed that Nb doping increased the total resistivity, forming an electrically conductive core and a nonconductive shell with enhanced activation energy.
JOURNAL OF THE AMERICAN CERAMIC SOCIETY
(2022)
Article
Engineering, Electrical & Electronic
Md Abu Mosa, M. K. Das, F. Alam, M. N. Khan, S. C. Mazumdar
Summary: The role of co-doping with Ba and Sm in BiFeO3 has been studied, and it is found that co-doped samples have improved dielectric and electric polarization properties. Sm doping notably increases the real part of initial permeability and relative quality factor, as well as the coercivity of Bi0.85Ba0.15FeO3 ceramics. This study is of great importance for the fabrication of magnetoelectric devices.
JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS
(2022)
Article
Chemistry, Physical
Harry Peirson, Juncheng Pan, Yizhe Li, David A. Hall, Andy P. Brown, Rik M. Drummond-Brydson, Steven J. Milne
Summary: An unfilled tungsten bronze-structured ferroelectric ceramic, Ca0.28Ba0.72Nb2O6 (CBN28), was doped with Y3+ to create ceramics with various compositions (Ca0.28Ba0.72)1-3w/2YwNb2O6 [0 <= w <= 0.05]. The substitution of Y3+ for Ca2+/Ba2+ resulted in a minor reduction of the lattice parameter and unit cell volume. Doped ceramics showed changes in permittivity, polarization, and temperature stability, indicating potential for high temperature dielectrics.
JOURNAL OF ALLOYS AND COMPOUNDS
(2023)
Article
Chemistry, Physical
Ping Zhang, Xin Tian, Xinyue Fan
Summary: The effect of ionic substitution in pure Li3Mg4NbO8 ceramics was investigated for the first time. By replacing Mg2+ with appropriate amounts of Zn2+, a novel Li-3(Mg1-xZnx)(4)NbO8 ceramic with improved properties was successfully synthesized. The relationship between crystal structure and properties was established, and doping with Zn2+ was found to enhance the ceramic's properties.
JOURNAL OF ALLOYS AND COMPOUNDS
(2022)
Article
Chemistry, Physical
N. A. Zhuk, N. A. Sekushin, M. G. Krzhizhanovskaya, V. A. Belyy, R. Korolev
Summary: Ni-doped CaCu3Ti4O12 ceramics were synthesized with different compositions and their electrical properties were studied. The samples exhibited high dielectric constant and low dielectric loss, which was attributed to the mechanism of ionic charge transfer predominating at room temperature, leading to significant values of impedance phase at low frequencies.
SOLID STATE IONICS
(2021)
Article
Engineering, Electrical & Electronic
Longhai Yang, Wenjie Gao, Jiaxing Wang, Chunxiang He, Gaili Yue, Tao Zhang
Summary: Li-doped Bi2/3Cu3Ti4O12 ceramics were successfully prepared, and the effect of Li doping on the crystal structure and dielectric properties was investigated. Li doping improved the dielectric constant and reduced the dielectric loss in the mid-frequency range. The dielectric response at different frequencies was found to originate from different regions within the ceramics.
JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS
(2023)
Article
Chemistry, Physical
O. Z. Yanchevskii, O. V'yunov, A. G. Belous, L. L. Kovalenko
Summary: The resistances of grain boundary and interface between sample and electrode increase with the combined introduction of Al3+ and F- ions. After 12 hours of sintering, a decrease in dielectric properties was observed due to copper losses. Samples sintered for 10 hours at 1 kHz exhibit specific dielectric parameters.
JOURNAL OF ALLOYS AND COMPOUNDS
(2021)
Article
Engineering, Electrical & Electronic
Jiangting Wang, Shaoyang Shi, Xiang Liu, Huangtao Wu, Hua Wang, Jiwen Xu, Ling Yang, Wei Qiu
Summary: In this study, Er-doped transparent fluorescent ceramics were synthesized using the solid-phase method. The effects of Er3+ on the structure, optical, and electrical properties were investigated. The ceramics showed high transmittance, up-conversion luminescence, and relaxation ferroelectricity.
JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS
(2022)
Article
Materials Science, Ceramics
Jimei Xue, Fangyuan Ren, Yongpeng Dong, Hanjun Wei, Fan Yang, Laifei Cheng
Summary: SiCN-based ceramics with broadband and strong microwave absorption properties exhibit outstanding electromagnetic wave absorption performance through the unique hetero-interface of Si3N4-BN, Si3N4-SiCN, and BN-SiCN in the ceramics synthesized using the CVI method. This leads to an effective absorption bandwidth covering the entire X-band.
CERAMICS INTERNATIONAL
(2021)
Article
Biochemistry & Molecular Biology
Porntip Siriya, Pairot Moontragoon, Pornjuk Srepusharawoot, Prasit Thongbai
Summary: The effects of sintering temperature and doping level concentration on the microstructures, dielectric response, and electrical properties of W6+-doped TiO2 were investigated. The study found that increasing the doping level concentration led to increased grain size and improved low-temperature dielectric response.
Article
Materials Science, Ceramics
Hanjun Wei, Jimei Xue, Yujie Ma, Zexin Hou, Yongpeng Dong, Laifei Cheng
Summary: Doping transition metal elements in a crystal can improve the electromagnetic properties of materials. Fe doping in Sc2Si2O7 ceramics leads to defects and enhancement of magnetic properties, improving microwave absorption efficiency. Controlling Fe content can further optimize the absorption performance of the ceramics.
CERAMICS INTERNATIONAL
(2021)
Article
Chemistry, Physical
Kun Dai, Ruina Ma, Xing Wang, Zhaoyang Zheng, Yongzhe Fan, Xue Zhao, An Du, Xiaoming Cao
Summary: In this study, composite ceramics of BST-MgO were prepared, and significant improvements in the dielectric constant and dielectric loss were observed with MgO doping. The Curie temperature also showed a shift, providing new solutions for further improving the dielectric properties of the BT-MgO system.
Article
Materials Science, Ceramics
Fangyi Huang, Hua Su, Qin Zhang, Xiaohui Wu, Yulan Jing, Yuanxun Li, Xiaoli Tang
Summary: The effect of Ti substitution on the microwave dielectric properties and structural characteristics of CaMgSi2O6 ceramics was investigated. It was found that the increase in Ti content led to the formation of CaTiO3, and the permittivity was correlated with ionic polarizability. The quality factor and temperature coefficient of resonant frequency were significantly influenced by lattice stability. Lattice energy and cation bonding also affected the microwave dielectric properties, and adjusting these parameters improved the performance of the ceramics.
CERAMICS INTERNATIONAL
(2022)
Article
Materials Science, Ceramics
Renfen Zeng, Fen Ye, Xiangping Jiang, Chao Chen, Xiaokun Huang, Xin Nie
Summary: The microstructure and properties of Ce-doped BTTW-BITT ceramics were analyzed, and it was found that an appropriate amount of Ce ion doping could improve the performance, enhance the piezoelectric activity, and improve the thermal stability.
CERAMICS INTERNATIONAL
(2022)
Article
Materials Science, Ceramics
Zheng Sun, Wenxu Liu, Qiuyang Li, Zhi Tao, Yemei Han
Summary: Introducing Bi(Zn2/3Nb1/3)O-3 successfully improved the dielectric performance of (1-x) BZT20-xBZN composite ceramics, with sample 0.94BZT20-0.06BZN exhibiting enhanced dielectric constants and a higher degree of relaxor behavior (γ=1.91).
CERAMICS INTERNATIONAL
(2021)
Article
Materials Science, Multidisciplinary
ZongXiang Wang, Kai Sun, YunPeng Qu, JinYuan Qin, Jiahong Tian, Yaping Li, XiaoFeng Li, Xuai Wang, RunHua Fan
Summary: In this study, titanium nitride/copper calcium titanate (TiN/CCTO) composites were prepared by low-temperature sintering. It was found that when the TiN content exceeded 50 wt%, the composites exhibited negative permittivity, which was attributed to plasma oscillation phenomenon. The AC conduction behavior transitioned from hopping to metal-like with increasing TiN content, and equivalent circuit analysis showed a relationship between positive reactance values and negative permittivity.
Article
Materials Science, Composites
Guohua Fan, Zhongyang Wang, Guodong Zhang, Yao Liu, Runhua Fan
Summary: The study found that percolative nickel/yttrium iron garnet cermets exhibit negative permittivity and negative permeability, showing potential for electromagnetic shielding and cloaking applications.
COMPOSITES COMMUNICATIONS
(2021)
Article
Materials Science, Ceramics
X. T. Song, Guangyue Shi, Guohua Fan, Yao Liu, Runhua Fan
Summary: Percolative graphite/barium titanate (GR/BaTiO3) composite prepared using hotpressing sintered process exhibits negative permittivity behaviors when the graphene content exceeds 2 wt%, along with metallic-like behavior in AC conductivity. Equivalent circuit analysis reveals the relationship between capacitive-inductive transition and the change of permittivity from positive to negative.
CERAMICS INTERNATIONAL
(2022)
Article
Materials Science, Ceramics
Yuanhui Liu, Chuanbing Cheng, Wenjun Sun, Zemeng Zhang, Rongwei Ma, Jingxu Zhou, Jia Wang, Tailin Wang, Qiuju Zheng, Yi Du, Jianxing Shen, Runhua Fan
Summary: This paper prepared ceramic composites with carbon fibers homogeneously dispersed in an alumina matrix using hot press sintering process, investigated the impact of carbon fiber content on the microscopic morphology, electrical conductivity, and negative permittivity behavior, and found that both conductivity and negative permittivity increased with increasing carbon fiber content.
CERAMICS INTERNATIONAL
(2022)
Article
Engineering, Manufacturing
Licheng Ju, Zongxiang Wang, Kai Sun, Huaxin Peng, Runhua Fan, Faxiang Qin
Summary: In this study, a percolation network of silver nanowires was constructed in a polyimide matrix, resulting in a transformation of permittivity from positive to negative when the amount of nanowires exceeded the percolation threshold. By controlling the content of silver nanowires, a metacomposite with a weak negative permittivity of -16 and low dielectric loss was successfully prepared, featuring an ultralow percolating concentration.
COMPOSITES PART A-APPLIED SCIENCE AND MANUFACTURING
(2022)
Article
Materials Science, Composites
Yunpeng Qu, Zhongyang Wang, Peitao Xie, Zongxiang Wang, Runhua Fan
Summary: Metacomposites have recently been a focus of attention due to their potential in electronic and dielectric devices, but they have faced challenges with extremely high negative permittivity. This study introduces a novel strategy to suppress plasma oscillation in Metacomposites and control the value of negative permittivity by incorporating semiconductive polyaniline into PANI/Ni metacomposites. The resulting materials exhibit weakly negative permittivity with fine-tuning capabilities, offering promising applications in electromagnetic shielding, microwave absorption, and novel electromagnetic sensors.
COMPOSITES SCIENCE AND TECHNOLOGY
(2022)
Article
Engineering, Electrical & Electronic
Licheng Ju, Qifa He, Faxiang Qin, Huaxin Peng, Runhua Fan
Summary: This study finds that the positive and negative real permittivity can be effectively modulated using low-cost copper microwire epoxy composites, which is of great significance in applications.
JOURNAL OF ELECTRONIC MATERIALS
(2022)
Article
Nanoscience & Nanotechnology
Kelan Yan, Liming Shen, Feng Yin, Guicun Qi, Xiaohong Zhang, Runhua Fan, Ningzhong Bao
Summary: This paper introduces a facile method for synthesizing La0.5Sr0.5MnO3 with negative properties, which can achieve negative permittivity and permeability simultaneously within a certain frequency range. By adjusting factors such as electron concentration, lattice symmetry, and magnetic resonance, the performance of this material can be controlled.
ADVANCED ELECTRONIC MATERIALS
(2022)
Article
Nanoscience & Nanotechnology
Ziyu Zhang, Yehao Zhao, Zihao Li, Lujie Zhang, Zixuan Liu, Zhenkun Long, Yunjia Li, Yao Liu, Runhua Fan, Kai Sun, Zidong Zhang
Summary: This study investigates the absorbing mechanism of carbon-based nanofibers and synthesizes composite nanofibers with Co-Fe nanoparticles and SiO2, showing excellent microwave absorption performance. The optimized nanofibers provide effective ideas for high-performance microwave absorption materials synthesis.
ADVANCED COMPOSITES AND HYBRID MATERIALS
(2022)
Article
Materials Science, Ceramics
Kai Sun, Pengtao Yang, Qifa He, Runhua Fan, Zongxiang Wang, Jiahong Tian, Xuechun Yang, Wenxin Duan, Xinfeng Wu, Zhongyang Wang
Summary: In this study, La1-xSrxMnO3 (LSMO) ceramic was successfully fabricated and both Lorentz-like and Drude-like negative permittivity were observed by adjusting the content of Sr2+. With the increase of Sr2+ content, the amplitude of dielectric resonance decreased and the resonance frequency shifted to a lower frequency region. When the Sr2+ content reached 0.7, the Drude-like negative permittivity dominated. The low tand value of LSMO was also observed. The generation and regulation mechanism of negative permittivity were clarified.
CERAMICS INTERNATIONAL
(2022)
Article
Engineering, Manufacturing
Kai Sun, Wenxin Duan, Yanhua Lei, Zongxiang Wang, Jiahong Tian, Pengtao Yang, Qifa He, Min Chen, Haikun Wu, Zheng Zhang, Runhua Fan
Summary: Flexible composites with weakly negative permittivity were prepared by using polyvinylidene fluoride (PVDF) as the flexible matrix and modified multi-walled carbon nanotubes (MWCNTs) as functional fillers. The composites exhibited low frequency dispersion behavior with a negative permittivity conforming to Drude model when the content of MWCNTs exceeded 13wt%. This study provides guidance for the development and application of flexible metamaterials.
COMPOSITES PART A-APPLIED SCIENCE AND MANUFACTURING
(2022)
Article
Engineering, Manufacturing
Chuanbing Cheng, Yuanhui Liu, Rongwei Ma, Runhua Fan
Summary: The recent advancement of metacomposites with negative permittivity provides a new research approach for the design and construction of electromagnetic shielding materials. In this study, Ni/YIG metacomposites were fabricated using a liquid impregnation approach and their electromagnetic properties were explored at MHz and Ku bands. With an increase in Ni content, isolated Ni particles formed interconnected networks in the composites, resulting in changes in conducting mechanism and reactance characteristic. The composites with high Ni contents exhibited a negative permittivity behavior, attributed to low-frequency plasma state of free electrons in the completed Ni networks. The dispersion of negative permittivity at frequencies below 10 MHz was influenced by isolated metal particles and could be well described by the Drude-Lorentz model. A notable shielding effectiveness of 33.1 dB was achieved at Ku band, primarily due to the impedance mismatch caused by the negative permittivity. The inductive conducting networks were crucial building blocks for achieving negative permittivity and improving electromagnetic shielding performance. This work provides guidance for designing electromagnetic shielding metacomposites and promotes further development in this field.
COMPOSITES PART A-APPLIED SCIENCE AND MANUFACTURING
(2022)
Article
Materials Science, Multidisciplinary
Zaixin Wei, Zhongyang Wang, Ciqun Xu, Guohua Fan, Xiaoting Song, Yao Liu, Runhua Fan
Summary: This study achieved temperature-stable negative permittivity in the kHz region by preparing specific ceramic materials and elaborated on the underlying mechanisms. The zero-crossing behavior of the real permittivity observed in the sample provides a promising alternative for designing epsilon-near-zero materials.
JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY
(2022)
Article
Materials Science, Multidisciplinary
Shuimiao Xia, Zhicheng Shi, Liang Sun, Shengbiao Sun, Davoud Dastan, Runhua Fan
Summary: A layered structure is designed to effectively suppress the loss and enhance the breakdown strength of high dielectric materials.
Article
Nanoscience & Nanotechnology
Zhipeng Wang, Kuan Yin, Yuliang Zhang, Kai Sun, Longjie Xie, Mengyang Cong, Shengjia Cao, Yanhua Lei, Xiaofeng Li, Runhua Fan
Summary: In this paper, Ti3C2Tx/carbonized wood composites with weakly negative permittivity were successfully prepared. The composites demonstrated the formation of three-dimensional conductive networks and a change in permittivity values from positive to negative, indicating a unique phenomenon and potential applications.
ADVANCED COMPOSITES AND HYBRID MATERIALS
(2022)