Journal
RSC ADVANCES
Volume 3, Issue 36, Pages 15600-15603Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3ra42374c
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- DST-India
- CSIR-India
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Doubly activated electron deficient alkenes react with ethyl diazoacetate in a Michael Initiated Ring Closure (MIRC) fashion to yield highly diastereoselective cyclopropanes even without any added base or metal catalyst. Following the strategy, a one-pot, two-step, three-component reaction of aldehydes, malononitrile/ethyl cyanoacetate, and ethyl diazoacetate was successfully developed.
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