Journal
CATALYSIS SCIENCE & TECHNOLOGY
Volume 4, Issue 3, Pages 738-745Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cy00859b
Keywords
-
Categories
Ask authors/readers for more resources
Pd nanoparticles supported on gamma-Fe2O3 (2 wt.%) were synthesized using the water-in-oil microemulsion method (using hydrazine as a reductant agent). Materials were characterized by N-2-BET at low temperature, XRD, XPS, Raman, and FTIR and tested in the gas phase reaction of oxidation of methanol. The direct formation of methyl formate (MF) from methanol was observed. Supported palladium catalysts produced methyl formate at low temperature (<150 degrees C) with a relatively high selectivity depending on the Fe+2/Fe+3 ratio (2 : 1, 1 : 1, 1 : 2) used for the preparation of the supports. Methyl formate is already formed at 50 degrees C with the maximum at about 80 degrees C. At higher temperature, methyl formate is no longer formed and the oxidation to CO2 and CO occurs. Raman studies indicated the changes in the structure of the Fe2O3 support in the case of the 1 : 2 sample after chemical reduction with hydrazine.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available