Article
Materials Science, Multidisciplinary
D. Murguia-Ortiz, I. Cordova, M. E. Manriquez, E. Ortiz-Islas, R. Cabrera-Sierra, J. L. Contreras, B. Alcantar-Vazquez, M. Trejo-Rubio, J. T. Vazquez-Rodriguez, L. V. Castro
Summary: Mexican dolomites doped with sodium nitrate were calcined to generate mixed metal oxides for catalytic transesterification of canola oil. Among all catalysts, Na-CaO/MgO exhibited the highest conversion rate of 95.4% and the optimal theoretical conversion rate of 97.46% was obtained through nonlinear programming.
Article
Materials Science, Multidisciplinary
R. F. Botti, M. D. M. Innocentini, T. A. Faleiros, M. F. Mello, D. L. Flumignan, L. K. Santos, G. Franchin, P. Colombo
Summary: In this study, non-stochastic (lattice) scaffolds were successfully manufactured using Direct Ink Writing for catalytic fluid flow applications. Three different geopolymer compositions were tested for ink rheology and printed into lattices for catalytic reactions in biodiesel processing. High catalytic activity and biodiesel yield were achieved for the fabricated lattices with different sodium, potassium or mixed compositions.
APPLIED MATERIALS TODAY
(2021)
Review
Energy & Fuels
Indira Tobio-Perez, Yosvany Diaz Dominguez, Lizet Rodriguez Machin, Sven Pohl, Magin Lapuerta, Ramon Piloto-Rodriguez
Summary: Biodiesel production has increasingly shifted towards using heterogeneous catalysts derived from biomass, due to their sustainability, economical and eco-friendly nature, ease of recovery, and the potential to eliminate biomass residues. The review discusses various biomass sources as precursors for heterogeneous catalysts, different methods for preparation, their advantages and drawbacks, as well as their performance in biodiesel production. The use of biomass ash or biochar-based catalysts shows promise in biodiesel synthesis, but requires improvements in catalyst load, reaction time, temperature, and methanol-to-oil ratio.
INTERNATIONAL JOURNAL OF ENERGY RESEARCH
(2022)
Review
Chemistry, Physical
Somasundaram Chandra Kishore, Suguna Perumal, Raji Atchudan, Ashok K. K. Sundramoorthy, Muthulakshmi Alagan, Sambasivam Sangaraju, Yong Rok Lee
Summary: The scientific community is exploring alternative renewable fuels like biodiesel due to the high price of petroleum and increased demand for petroleum-derived products. Transesterification, a technique for creating biodiesel, utilizes a variety of oils and fats, with the choice of catalyst determined by the free fatty acid content in the oil. Heterogeneous catalysts, obtained from biomass and biowaste resources, have solved the issues associated with homogeneous catalysts and have been used to produce high-quality biodiesel efficiently.
Article
Chemistry, Physical
Ieva Gaide, Violeta Makareviciene, Egle Sendzikiene, Kiril Kazancev
Summary: This study investigated the use of natural catalysts such as dolomite in biodiesel synthesis and determined the optimal conditions for the process. It was found that dolomite is the most effective catalyst in heterogeneous biodiesel synthesis, with the optimal preparation conditions being heating at 850 degrees C for 5 hours. The optimized transesterification of rapeseed oil using dolomite as catalyst resulted in the best conditions for production of rapeseed methyl esters.
Article
Environmental Sciences
Rujeeluk Khumho, Kitvara Tocuweang, Prissana Sangkhum, Prapan Kuchonthara, Veeramuthu Ashokkumar, Chawalit Ngamcharussrivichai
Summary: This study focuses on upgrading glycerol from biodiesel plants into short-chain polyglycerols, which are used as intermediates for producing emulsifiers in consumer products. The researchers used a nanocomposite catalyst synthesized from mixed oxides to perform the etherification of glycerol. The results showed that the nanocomposite catalyst exhibited excellent catalytic performance and selectivity.
Article
Chemistry, Multidisciplinary
Emine Emel Cakirca, Ayse Nilgun Akin
Summary: In this study, Ca-riched Hydrotalcite like compounds were successfully synthesized for the conversion of microalgae oil into biodiesel. By changing the calcium-magnesium molar ratio, significant effects on the structure and catalytic activity of HLCs were observed, leading to higher FAME yield of biodiesel.
SUSTAINABLE CHEMISTRY AND PHARMACY
(2021)
Review
Chemistry, Physical
Haris Mahmood Khan, Tanveer Iqbal, Saima Yasin, Chaudhry Haider Ali, Muhammad Mujtaba Abbas, Muhammad Asif Jamil, Abrar Hussain, Manzoore Elahi M. Soudagar, Muhammad Muhitur Rahman
Summary: With the increasing population and consumption of agricultural products, there is a rise in agricultural waste generation. This study focuses on utilizing agricultural waste-derived catalysts for biodiesel production, emphasizing their effectiveness, low cost, and eco-friendliness. The research encourages exploring unexplored agricultural waste for potential conversion into valuable materials.
Article
Chemistry, Applied
Abdullajon Odilov, Yin Liu, Tianwen Hu, Xiangrui Jiang, Jin Suo, Guanghui Tian, Feipu Yang, Jingshan Shen
Summary: An improved synthesis method for simmerafil, a potent PDE5 inhibitor as a clinical candidate, was described with a 38.1% overall yield and 99.7% purity, starting from the safe and inexpensive salicylamide. The key intermediate 2-propoxybenzimidamide was effectively obtained, which optimizes the subsequent process from intermediate to simmerafil, making it more amenable to scale-up.
ORGANIC PROCESS RESEARCH & DEVELOPMENT
(2021)
Review
Chemistry, Physical
Martin N. Gatti, Federico M. Perez, Gerardo F. Santori, Nora N. Nichio, Francisco Pompeo
Summary: Research on the utilization of biomass resources for energy and chemical compounds attracts worldwide attention. The biodiesel industry, as it grows, generates a parallel market for glycerol, its major by-product. Glycerol, with its wide availability and low cost, becomes a fundamental component for the production of various chemical products, thus enabling the development of a biorefinery around biodiesel plants through the integration of different production processes. This study offers a comprehensive review of the hydrogenolysis of glycerol to 1,2-propylene glycol, a reaction of interest in the biorefinery context. The article analyzes over 300 references spanning approximately 20 years, focusing on the heterogeneous catalysts employed for glycol production.
Article
Chemistry, Physical
Xiaotian Liu, Yongli Yin, Kai Xiong, Mingyu Li
Summary: A novel high-efficiency Fe-based catalyst Fe3C-NP-PCFs with excellent HER activity and long-term stability was designed and tested, showing superior performance compared to commercially available Pt/C catalysts in electrochemical tests.
JOURNAL OF ALLOYS AND COMPOUNDS
(2021)
Article
Energy & Fuels
Haris Mahmood Khan, Tanveer Iqbal, M. A. Mujtaba, Manzoore Elahi M. Soudagar, Ibham Veza, I. M. Rizwanul Fattah
Summary: Biodiesel, a promising renewable fuel, has gained global attention for replacing fossil fuels using heterogeneous catalysts to accelerate reactions. Research shows that utilizing microwave technology in heterogeneously catalysed transesterification greatly reduces reaction times while maintaining or improving catalytic activity.
Review
Thermodynamics
Dhnyaneshwar Raising Rathod, Sandesh Suresh Karkal, Akil Salim Jamadar, Aliaa M. A. Hashem, P. Suresh, S. S. Mamatha, Tanaji G. Kudre
Summary: This review focuses on various catalysts, such as heterogeneous catalysts, nanocatalysts, biocatalysts, bifunctional catalysts, metal-organic frameworks (MOF), and covalent organic frameworks (COF), for biodiesel production. The use of homogeneous catalysts in commercial biodiesel production has limitations, such as toxicity, corrosion, soap formation, and non-reusability. As alternatives, heterogeneous acid and base catalysts have been introduced, which are less sensitive to moisture and FFAs, easily separated and recovered, and reusable. Novel catalysts, including waste biomass-derived mesoporous heterogeneous catalysts, chemically synthesized heterogeneous catalysts, metal ion-doped heterogeneous catalysts, bifunctional acid-base catalysts, and carbonaceous char-supported hetero catalysts, nanocatalysts, MOF and COF catalysts, show potential for sustainable and cost-effective biodiesel production. This review provides insights into catalyst advancements, preparation and operations, catalyst types and suitability, efficiency, life cycle assessment, challenges, and prospects for biodiesel production.
INTERNATIONAL JOURNAL OF GREEN ENERGY
(2023)
Review
Chemistry, Multidisciplinary
Manish Kumar Bharti, Sonia Chalia, Preeti Thakur, S. N. Sridhara, Atul Thakur, P. B. Sharma
Summary: The depletion and pollution of fossil fuels are prompting the use of alternative, renewable energies such as biofuels. Nanoferrites heterogeneous catalysts have been reviewed for producing biodiesel efficiently. Using transesterification, high conversion yields, low cost, and reusable catalysts can be achieved, with over 90% conversion yields possible with moderate alcohol/oil ratios.
ENVIRONMENTAL CHEMISTRY LETTERS
(2021)
Review
Thermodynamics
Xiaoling Ma, Fengsheng Liu, Yaxin Helian, Chaorui Li, Zhongjie Wu, Hui Li, Huijun Chu, Yongbo Wang, Yangyang Wang, Wanpeng Lu, Min Guo, Mingzhi Yu, Shoujun Zhou
Summary: Biodiesel is a green and renewable energy source, and the use of heterogeneous catalysts like metal organic frameworks (MOFs) in its production process is gaining attention due to the difficulties of recovery and reuse associated with traditional homogeneous catalysts. The unique structure and advantages of MOFs make them a promising candidate for catalyzing biodiesel production.
ENERGY CONVERSION AND MANAGEMENT
(2021)
Article
Biochemistry & Molecular Biology
Puying Qi, Na Wang, Taihong Zhang, Yumei Feng, Xiang Zhou, Dan Zeng, Jiao Meng, Liwei Liu, Linhong Jin, Song Yang
Summary: Anti-virulence strategies are effective for controlling bacterial diseases by targeting virulence factors. In this study, a series of dehydroabietic acid derivatives were synthesized and evaluated for their antibacterial activity. Compound 2b showed promising antibacterial activity against Xanthomonas oryzae pv. oryzae and effective control of bacterial leaf blight in rice. It also suppressed various virulence factors. These compounds can serve as lead compounds for developing novel bactericides.
INTERNATIONAL JOURNAL OF MOLECULAR SCIENCES
(2023)
Article
Agriculture, Multidisciplinary
Dan Zeng, Shuai-Shuai Liu, Wu-Bin Shao, Tai-Hong Zhang, Pu-Ying Qi, Hong-Wu Liu, Xiang Zhou, Li-Wei Liu, Heng Zhang, Song Yang
Summary: This study synthesized 35 new 1,3,4-oxadiazole derivatives and evaluated their anti-phytopathogenic activities. Compound C-7 showed excellent antibacterial activity in vitro and acceptable activity in vivo against rice bacterial leaf blight. Moreover, C-7 could indirectly reduce the inducible expression of host SWEET genes, alleviating nutrient supply in the infection process of phytopathogenic bacteria. The study highlights the potential of 1,3,4-oxadiazole-based agrochemicals in controlling plant bacterial diseases.
JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY
(2023)
Article
Agriculture, Multidisciplinary
Lihui Shao, Su Zhao, Song Yang, Xiang Zhou, Yan Li, Chengpeng Li, Danping Chen, Zhuirui Li, Guiping Ouyang, Zhenchao Wang
Summary: To discover novel antibacterial agents, two series of quinazolinone derivatives with novel structures were synthesized and their bioactivity against plant bacteria was tested. Compound D32 was identified as a potent antibacterial inhibitor against Xanthomonas oryzae pv. Oryzae (Xoo), with better inhibitory capacity compared to the commercial drugs. Further investigation revealed the mechanism of action of D32, which provides clues for the development of new therapeutic strategies.
JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY
(2023)
Article
Agronomy
Wu-Bin Shao, Yan-Mei Liao, Rong-Shuang Luo, Jin Ji, Wan-Lin Xiao, Xiang Zhou, Li-Wei Liu, Song Yang
Summary: In this study, new phenothiazine derivatives were synthesized and evaluated for their inhibitory activity against tobacco mosaic virus (TMV). Compound A(8) exhibited the highest protective activity against TMV, with an EC50 of 115.67 μg/mL, which was significantly superior to the positive controls ningnanmycin and ribavirin. Biochemical assays demonstrated that compound A(8) could inhibit TMV replication by disrupting its self-assembly and also enhance the defense responses of tobacco plants. This research provides valuable insights for the discovery of new agrochemicals to control plant viral diseases.
PEST MANAGEMENT SCIENCE
(2023)
Article
Agronomy
Jiao-Jiao Zhang, Yu-Mei Feng, Jun-Rong Zhang, Wan-Lin Xiao, Shuai-Shuai Liu, Xiang Zhou, Heng Zhang, Pei-Yi Wang, Li-Wei Liu, Song Yang
Summary: A series of simple triclosan derivatives containing isopropanolamine moiety were designed and assessed for their antibacterial behavior. Some compounds showed excellent bioactivity against three destructive bacteria. Compound C-8 displayed high bioactivities towards Xoo and Xac.
PEST MANAGEMENT SCIENCE
(2023)
Article
Agriculture, Multidisciplinary
Wu-Bin Shao, Rong-Shuang Luo, Jiao Meng, Xiao-Kang Lv, Hong-Mei Xiang, Wan-Lin Xiao, Xiang Zhou, Li-Wei Liu, Zhi-Bing Wu, Song Yang
Summary: Phenothiazine derivatives showed excellent bioactivity against different bacteria and demonstrated potential as pesticide candidates for plant diseases. Compound C-2 had high effectiveness against rice leaf blight, outperforming commonly used pesticides.
JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY
(2023)
Review
Chemistry, Physical
Wenfeng Zhao, Hu Li, Heng Zhang, Song Yang, Anders Riisager
Summary: Ammonia borane (AB) is a promising material for hydrogen storage and has attracted much attention in reductive organic transformations. This review summarizes the recent progress of AB-mediated transfer hydrogenation reactions of various substrates and discusses the synthesis protocols, reaction parameters, product distribution, and reactivity. The mechanism involving the action mode of AB and structure-activity relationships are also discussed, and the challenges and opportunities for AB-enabled transfer hydrogenation reactions are highlighted.
GREEN ENERGY & ENVIRONMENT
(2023)
Article
Chemistry, Multidisciplinary
Ye Meng, Jinshu Huang, Jie Li, Yumei Jian, Song Yang, Hu Li
Summary: By mimicking the key active species of hemoglobin p450 heme monooxygenase, a Fe-N-4 single atom-doped sulfur-containing carbon nitride photocatalyst was prepared and demonstrated to efficiently convert bio-based alcohols and NH2OH dot HCl to nitriles. The Fe-N-4 sites in the catalyst directly capture photogenerated electrons and molecular oxygen to generate superoxide radicals, while the surrounding S atoms confine photogenerated holes. This strategy of constructing atomic sites enhances the photocatalytic activity and selectivity for biomass valorization.
Article
Chemistry, Multidisciplinary
Feng Xu, Zao Li, Li-Long Zhang, Shengqi Liu, Hu Li, Yuhe Liao, Song Yang
Summary: Upgrading biomass-derived platforms to functionalized aromatics by a tandem Diels-Alder (DA) cycloaddition-aromatization strategy has attracted attention. Three challenges exist: improving the equilibrium of DA cycloaddition, controlling the regioselectivity of DA adducts, and increasing the stability of the cycloadduct. In this study, an intramolecular cycloaromatization strategy was developed using a defective Zn-BTC-SA catalyst and an acidic ionic liquid to achieve efficient and selective conversion of bio-furfurals to isoindolinones under liquid phase conditions. The protocol showed high yields and scalability.
Article
Chemistry, Multidisciplinary
Pei-dong Wu, Lanyun Li, Keping Wang, Hu Li, Zhen Fang
Summary: In this study, a Mo-BVO-TiCoNO-CoFeOxy photoanode with a nanowire structure was prepared for the first time, which efficiently converted bio-based benzyl alcohol to benzoic acid in water while coupling H-2 production. The nanowire structure increased the exposed active sites on the photoelectrode surface and enhanced the benzyl alcohol oxidation capacity. Additionally, the aspect ratio of the nanowires increased visible light absorption and the thermal effect increased H-2 production.
Article
Chemistry, Inorganic & Nuclear
Li-Long Zhang, Yaqiong Su, Dandan Chen, Hongguo Wu, Feng Xu, Hu Li, Song Yang
Summary: NOx is used as an oxidant for direct selective conversion of methane into methanol, but the interconversion of NOx compounds and the easy formation of O-2 have posed challenges in determining its effectiveness. This study proposes a new cooperative multi-functional mechanism strategy using dual oxidants (NO and N2O) to enhance catalytic performance. Compared with normal mechanisms, this strategy shows stronger CH4 adsorption and thermodynamic favorability. It is expected to inspire further research in DSCMM and other catalytic systems.
INORGANIC CHEMISTRY FRONTIERS
(2023)
Article
Energy & Fuels
Jinshu Huang, Jiasheng Chen, Zhuochun Huang, Tengyu Liu, Yan Ding, Hu Li, Chao He
Summary: A novel photothermal catalytic strategy was developed using a bio-based SO3H-functionalized graphenelike catalyst, which can efficiently upgrade biomass into high-quality biofuels under solvent-free and room-temperature conditions, and exhibits good stability and recyclability.
Article
Chemistry, Physical
Zi-Ye Liu, Qian-Yu Wang, Ji-Ming Hu
Summary: In this study, a layered carbon dot composite catalyst (NiFe LDH@CDs) was prepared using a one-step coprecipitation method, without the need for heating or hydrothermal treatment. The CD-functionalized catalyst facilitated rapid charge transfer and accelerated the oxygen evolution reaction. Additionally, the heterojunction structure formed between NiFe LDH and CDs efficiently suppressed photoelectron-hole recombination.
CATALYSIS SCIENCE & TECHNOLOGY
(2024)
Article
Chemistry, Physical
Rohit Kumar, Ankit Kumar Srivastava, Palaniyappan Nagarasu, Vedichi Madhu, Ekambaram Balaraman
Summary: We designed and synthesized a NN-CoII bidentate complex and used it for the amination of alcohols under mild and solventless conditions. The complex exhibited good reactivity towards both primary and sterically hindered secondary alcohols, providing high yields of amines. The pyrazole moiety in the ligand played a crucial role in the reaction. Furthermore, we demonstrated the reusability of the complex as a homogeneous cobalt catalyst.
CATALYSIS SCIENCE & TECHNOLOGY
(2024)
Article
Chemistry, Physical
Shivanand Chettri, Liang-Ting Wu, Sagarmani Rasaily, Debesh Sharma, Bikram Gurung, Rajani Dewan, Sudarsan Tamang, Jyh-Chiang Jiang, Anand Pariyar
Summary: Replicating the enzymatic surface microenvironment in vitro is challenging, but constructing an analogous model could facilitate our understanding of surface effects and aid in developing an efficient bioinspired catalytic system. In this study, five unique Cu2O morphologies were generated, and the surface morphology variations were found to be a consequence of differences in the exposure of low-index facets. The reactivity of Cu2O was found to be influenced by the proportion of {110} planes, with r-Cu2O exhibiting the highest reactivity.
CATALYSIS SCIENCE & TECHNOLOGY
(2024)
Article
Chemistry, Physical
Yong Tang, Jianhao Qiu, Dingliang Dai, Guanglu Xia, Lu Zhang, Jianfeng Yao
Summary: Defect engineering has been shown to improve the photocatalytic performance. This study investigated the use of defect-rich UiO-66-NH2 wrapped by ZnIn2S4 as a catalyst for photocatalytic H2O2 production. The defects in UiO-66-NH2 enhanced O-2 adsorption and charge separation, leading to higher H2O2 yield. The insights from this work can advance the research in defect engineering of MOFs and photocatalytic H2O2 synthesis.
CATALYSIS SCIENCE & TECHNOLOGY
(2024)
Article
Chemistry, Physical
Ruiyang Qu, Shuxin Mao, Jana Weiss, Vita A. Kondratenko, Evgenii V. Kondratenko, Stephan Bartling, Haifeng Qi, Annette-Enrica Surkus, Kathrin Junge, Matthias Beller
Summary: The hydrogenation of amides, a challenging reaction usually performed at high temperatures, has been achieved under milder conditions using a new Pt-MoOx/TiO2 catalyst. This catalyst system enables the selective hydrogenation of various amides and imides.
CATALYSIS SCIENCE & TECHNOLOGY
(2024)
Article
Chemistry, Physical
Xiaoran Niu, Ao Wang, Lei Tong, Lei Wang, Yuan Kong, Chenliang Su, Hai-Wei Liang
Summary: This study introduces a novel intermetallic PdCu3 catalyst supported on defective nanodiamond-graphene (ND@G), which exhibits high selectivity (95%) and remarkable activity (turnover frequency: 2940 h(-1)), six times higher than that of the commercial Lindlar catalyst.
CATALYSIS SCIENCE & TECHNOLOGY
(2024)
Review
Chemistry, Physical
Zhiyuan Zheng, Yiming Yue, Hongying Zhuo, Qinggang Liu, Yanqiang Huang
Summary: This review presents the recent research advances on single-atom catalysis for deep reduction of CO2. Detailed introductions and summaries were classified into three categories based on proton-coupled multi-electron transfer approaches: strengthening metal-support interaction, rational design and regulation of coordination environment, and development of SACs with multi-atom active sites. The challenges and future research directions in the field of SACs for CO2 reduction are also proposed.
CATALYSIS SCIENCE & TECHNOLOGY
(2024)
Article
Chemistry, Physical
Shiv Kumar, Paramita Datta, Anup Bhunia, Swadhin K. Mandal
Summary: This article reports a transition-metal-free process for in situ denitrogenation of tosylhydrazones, resulting in the production of various sulfones. The authors used a phenalenyl-based odd alternant hydrocarbon as a photoredox catalyst, which acted as a potent oxidant to facilitate the denitrogenation reaction. The method showed wide functional-group tolerance and high yields, making it suitable for late-stage modification of natural products.
CATALYSIS SCIENCE & TECHNOLOGY
(2024)
Article
Chemistry, Physical
L. A. Luque-Alvarez, J. Gonzalez-Arias, F. Romero-Sarria, T. R. Reina, L. F. Bobadilla, J. A. Odriozola
Summary: Currently, the production of acetic acid through the carbonylation reaction of methanol has limitations, leading to the exploration of alternative methods using heterogeneous catalysts. This study investigates the methanol carbonylation reaction over a Cu-H-MOR catalyst and proposes a reaction mechanism based on the catalytic behavior and performance of the catalyst. The results provide insights into the reaction mechanism and the involvement of acid and redox centers.
CATALYSIS SCIENCE & TECHNOLOGY
(2024)