Article
Chemistry, Physical
Suresh Muninathan, Sivasamy Arumugam
Summary: Semiconductor nanoparticles have been extensively studied for a decade for photocatalytic hydrogen production and remediation of toxic pollutants due to their better activities at nano regime and quantum efficiency. The present study reports the synthesis of NiS nanoparticles decorated reduced-graphene oxide nanocomposite as an effective visible photo-catalyst for H2 production and toxic organic dye degradation. The nanocomposite shows good structural and optical properties, with high photocatalytic activities in dye degradation and hydrogen production.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2021)
Article
Materials Science, Ceramics
Lucas Portela Oliveira, Camila Cristina de Foggi, Bruna Natalia Alves da Silva Pimentel, Marcelo Assis, Juan Andres, Elson Longo, Carlos Eduardo Vergani
Summary: The study demonstrates the excellent photocatalytic and antifungal properties of silver phosphate microcrystals under visible light, which remain stable even after 4 cycles. Combining with visible light irradiation can significantly enhance its antifungal effectiveness.
CERAMICS INTERNATIONAL
(2021)
Article
Chemistry, Physical
Xiangjiu Guan, Shichao Zong, Li Tian, Yazhou Zhang, Jinwen Shi
Summary: In this study, SrTiO3-LaCrO3 continuous solid solutions were prepared using a polymerized complex method. The introduction of LaCrO3 effectively adjusted the bandgap of SrTiO3, leading to improved light absorption ability and significantly enhanced photocatalytic activities. The optimized H-2 evolution rate reached 1368 mu mol h(-1) g(-1) with 0.10 LaCrO3 content, and the improved photocatalytic performance was attributed to the hybridization of Cr 3d, Ti 3d, and O 2p orbitals, as well as the distortion of TiO6 octahedra.
Article
Chemistry, Inorganic & Nuclear
Ran Wang, Qi Wang, Jun Qian, Xiaoxiang Xu
Summary: Solid solutions between LaNbON2 and LaMg2/3Nb1/3O3 have been investigated for water oxidation under visible light illumination, showing improved photocatalytic activity. The formation of solid solutions provides a useful tool to steer photocatalytic performance and opens new opportunities for efficient photocatalysts development for solar energy conversions.
INORGANIC CHEMISTRY FRONTIERS
(2021)
Article
Chemistry, Physical
Xiaowei Jia, Xianchun Liu, Ruyu Zhang, Anqi Xie, Yueran Li, Xiaodan Yu, Min Yu, Yunfeng Li, Zhan Shi, Yan Xing
Summary: A series of Fe-doped KCuTa3O9 (FKCTO-x) oxides were synthesized via one-step high-temperature solid-state reaction. Fe atoms were successfully incorporated into the lattice of KCuTa3O9. The FKCTO-x samples showed enhanced photocatalytic hydrogen evolution activities, with FKCTO-2 exhibiting an optimal hydrogen production rate of 5.51 mu mol h-1 under visible light irradiation, far exceeding that of the pure KCTO. This work provides a simple and effective strategy to design and prepare highly efficient visible-light-driven PLMOs for photocatalytic water splitting.
JOURNAL OF ALLOYS AND COMPOUNDS
(2023)
Article
Chemistry, Physical
Yuehu Wan, Shiwen Du, Congrong Lu, Kuankuan Ren, Biyun Shi, Shiyan Liu, Chunhe Li, Weidong Dou, Ping Fang, Na Ye
Summary: Visible-light-driven photocatalysis using novel CuS nanoparticles/CdS nanowires Schottky heterojunctions shows outstanding H-2 generation rates. Experimental characterizations and theoretical calculations reveal that the Schottky junction between CuS NPs and CdS NWs accelerates photoinduced electron drift, improving water splitting activities. This work provides a simple route for synthesizing CdS-based nanocomposites for efficient visible-light driven energy conversion.
JOURNAL OF ALLOYS AND COMPOUNDS
(2021)
Article
Engineering, Environmental
Yonggang Lei, Kim Hoong Ng, Yingzhen Zhang, Zengxing Li, Shen Xu, Jianying Huang, Yuekun Lai
Summary: In this study, a facile synthesis method for CdS/WC photocatalyst was reported. The incorporation of WC improved the activity and quantum efficiency of the photocatalyst, leading to enhanced hydrogen production. This research provides high reliability for industrial scale hydrogen production.
CHEMICAL ENGINEERING JOURNAL
(2022)
Article
Chemistry, Physical
Yuwei Chen, Yongfeng Jiang, Bingyan Chen, Huidong Tang, Longzhu Li, Yujie Ding, Huaqiang Duan, Dongming Wu
Summary: In this study, an O-g-C3N4 (OCN) and SnO2 (SO) coupled photocatalyst was synthesized and evaluated for the degradation of RhB and reduction of Cr(IV) under simulated sunlight irradiation. The 30-SO/OCN nanocomposites exhibited higher catalytic activity than 30-SO/CN nanocomposites, attributed to the special surface of OCN and the formation of a heterojunction between SO and OCN.
JOURNAL OF ALLOYS AND COMPOUNDS
(2022)
Article
Chemistry, Physical
Caili Yang, Yanjia Cui, Yingshi Su, Yonghui Cheng, Defu Yao, Yuting Liao, Suyao Liu, Yiwen Fang, Yuqi Wu, Xiaoming Wang, Yibing Song, Gongxuan Lu, Zhen Li
Summary: In this study, Rh2O3 nanoparticles were implanted on the surface of reduced graphene oxide (RGO) by a hydrothermal reaction. Sensitized by Eosin Y, Rh2O3 was converted into metal Rh, forming a strong interaction interface between Rh NPs and RGO. The fabricated Rh/RGO catalyst showed high performance for photocatalytic H-2 evolution under visible light irradiation, with a H-2 evolution rate of 98.1 mmol center dot g(-1)center dot h(-1) and a maximum apparent quantum efficiency of 79.3% at 520 nm. The enhanced performance was attributed to the excellent electron conduction ability of RGO and the strong interaction between Rh NPs and RGO, which accelerated electron transfer and prolonged charge lifetime. The strong interaction also ensured the strong anchoring and excellent stability of the Rh/RGO catalyst.
ACS APPLIED ENERGY MATERIALS
(2023)
Article
Chemistry, Multidisciplinary
Jinsoo Yoon, Seong-Geun Oh
Summary: ZnO nanoparticles exhibit strong photocatalytic activity in aqueous micellar solutions, and their performance can be significantly enhanced by surface modification. Cationic micelles can improve the photocatalytic activity of ZnO particles, while anionic and nonionic micelles have a detrimental effect on their photocatalytic performance.
JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY
(2021)
Article
Environmental Sciences
Mojtaba Yeganeh, Hamid Reza Sobhi, Ali Esrafili
Summary: In this study, the efficient degradation of metronidazole (MNZ) using Co/g-C3N4/Fe3O4 nanocomposite under visible light irradiation was achieved. The synthesized photocatalyst was characterized and the operational parameters were optimized. The degradation process followed a pseudo-first-order kinetic model.
ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH
(2022)
Article
Chemistry, Inorganic & Nuclear
L. Diaz, V. D. Rodriguez, M. Gonzalez-Rodriguez, E. Rodriguez-Castellon, M. Algarra, P. Nunez, E. Moretti
Summary: Low-cost M/TiO2 semiconductor catalysts were prepared by impregnating five different first row transition metals on a commercial titania support, with Cu/TiO2 showing the best photocatalytic activity for hydrogen production under both UV and visible light. Ni/TiO2 and Co/TiO2 also exhibited significant photocatalytic activity under UV light. The Cu/TiO2 catalyst was characterized by TEM and XPS measurements, showing the dispersion of copper species on TiO2 and the oxidation-reduction process during the hydrogen production reaction. Impregnated TiO2 showed higher H-2 production rates compared to non-impregnated TiO2, making Cu/TiO2 a cost-effective alternative to Pt/TiO2 for hydrogen production.
INORGANIC CHEMISTRY FRONTIERS
(2021)
Review
Chemistry, Organic
Rong Zhou, Lishuang Ma, Xiaona Yang, Jilei Cao
Summary: Deuterated organic compounds are widely used in various fields such as medicinal chemistry, mechanistic studies, and quantitative analyses. Photocatalytic deuteration has emerged as a reliable platform for generating deuterated organic molecules, particularly pharmaceutical compounds, with advantages such as mild conditions and good site selectivity. This review summarizes recent advances in visible-light photocatalytic deuteration reactions based on the type of bond deuterated.
ORGANIC CHEMISTRY FRONTIERS
(2021)
Article
Chemistry, Inorganic & Nuclear
Kanokwan Phumivanichakit, Sumetha Suwanboon, Pongsaton Amornpitoksuk
Summary: AgIO3 is a wide bandgap photocatalyst that can only be activated by UV irradiation. Under visible light irradiation, AgIO3 exhibits photocatalytic activity through a dye sensitization mechanism, degrading dyes RO and EY. During the degradation process of RO or EY, metallic Ag is generated on the surface of AgIO3, and this Ag/AgIO3 product can degrade other dyes such as MB and CV under visible light irradiation.
INORGANIC CHEMISTRY COMMUNICATIONS
(2023)
Article
Materials Science, Textiles
Hui Zhang, Dou Wang, Cuihong Sheng, Deping Ben, Hailiang Wu, Ningtao Mao
Summary: The study investigated the photocatalytic activities of a composite photocatalyst made from PET filaments loaded with Ag-TiO2 nanoparticles under visible light irradiation. It was found that photoinduced holes were the major reactive radical species in the photodegradation process. The incorporation of Ag nanoparticles into TiO2 nanoparticles and the infiltration of Ag/Ti nanoparticles into PET polymers contributed to the enhanced photocatalytic activity.
FIBERS AND POLYMERS
(2021)
Article
Chemistry, Multidisciplinary
Ki-Nam Byun, Eisuke Yamamoto, Makoto Kobayash, Minoru Osada
Summary: We demonstrated a rational approach for designing high-performance polymer-based energy storage capacitors by depositing two-dimensional paraelectric Ca2Nb3O10 nanosheets on a ferroelectric poly(vinylidene fluoride) (PVDF) film to form paraelectric/ferroelectric hetero-assemblies. Such an artificial structuring enabled tailoring of the breakdown strength and dielectric response, realizing an enhanced energy density (similar to 10 J cm(-3)) compared to pristine PVDF film (similar to 1 J cm(-3)).
Article
Nanoscience & Nanotechnology
Takeshi Aihara, Wataru Aoki, Shin Kiyohara, Yu Kumagai, Keigo Kamata, Michikazu Hara
Summary: In this study, perovskite oxide nanoparticles were successfully synthesized using dicarboxylic acids as reagents. The resulting SrTiO3 nanoparticles showed high catalytic activity for the cyanosilylation of carbonyl compounds, even without a heat pretreatment.
ACS APPLIED MATERIALS & INTERFACES
(2023)
Article
Nanoscience & Nanotechnology
Yue Shi, Eisuke Yamamoto, Makoto Kobayashi, Minoru Osada
Summary: This article demonstrates an automated manufacturing method for high-quality 2D thin films using a modified drop-casting approach. By controlling the substrate temperature and liquid removal, nanosheets can come together to form a single-layer film in a short time. This method enables the production of different functional 2D thin films while reducing time and sample consumption.
ACS APPLIED MATERIALS & INTERFACES
(2023)
Article
Chemistry, Multidisciplinary
Hirofumi Tsunematsu, Yue Shi, Eisuke Yamamoto, Makoto Kobayashi, Tomohiro Yoshida, Minoru Osada
Summary: This study demonstrates a significant near-infrared (NIR) shielding effect while maintaining visible transparency by synthesizing a two-dimensional polytungstate material. The engineered plasmonic material achieved a high NIR reflectance (>53%) and a high visible transparency (>71%), making it a promising solution for thermal shielding and future thermal management technology.
Article
Chemistry, Multidisciplinary
Makoto Kobayash, Tsubasa Tasaka, Eisuke Yamamoto, Minoru Osada
Summary: Two types of single-crystalline oxyfluoride nanosheets were synthesized through exfoliation of layered bismuth oxyfluorides intercalated with nitrates. The solution-based exfoliation process resulted in multilayered cationic oxyfluoride nanosheets with thicknesses of several nanometers. A second harmonic generation measurement confirmed that one of the nanosheets exhibited a noncentrosymmetric structure. This is the first instance of a cationic nanosheet with nonlinear optical properties.
Article
Chemistry, Multidisciplinary
Hikaru Sugimoto, Makoto Kobayashi, Eisuke Yamamoto, Minoru Osada
Summary: We demonstrated a method for synthesizing amorphous oxide nano-sheets from crystalline nano-sheets prepared by the exfoliation of layered compounds. By calcining single-crystalline oxide nano-sheets with C3N4 powder in nitrogen and annealing them in air, amorphous oxide nano-sheets were produced. The treatment did not change the cation composition and valence, shape, lateral size, surface roughness, and thickness. This approach allows for the production of amorphous oxide nano-sheets with distinct morphologies and compositions and large lateral sizes.
Article
Chemistry, Multidisciplinary
Masashi Hattori, Natsuo Okuyama, Hiyori Kurosawa, Michikazu Hara
Summary: The Haber-Bosch process is required to produce ammonia without using fossil fuels in order to reduce global CO2 emissions. It is crucial to develop heterogeneous catalysts that can synthesize ammonia at temperatures below 100-150 degrees C to minimize energy consumption. In this study, metallic iron particles combined with an electron-donating material were used as a catalyst for ammonia synthesis, showing a high turnover frequency compared to other transition metals. This is attributed to the intrinsic desorption of hydrogen atoms from iron at low temperatures.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
(2023)
Article
Chemistry, Multidisciplinary
Hyung-Jun Kim, Shu Morita, Ki-Nam Byun, Yue Shi, Takaaki Taniguchi, Eisuke Yamamoto, Makoto Kobayashi, Yasuo Ebina, Takayoshi Sasaki, Minoru Osada
Summary: Two-dimensional high-K dielectric perovskite materials can be designed into ultrahigh energy storage capacitors, with ultrahigh energy densities, high efficiency, excellent reliability, and temperature stability, even comparable to lithium-ion batteries. Enhancing the energy density may make dielectric capacitors more competitive.
Article
Chemistry, Multidisciplinary
Eisuke Yamamoto, Kosuke Fujihara, Yuma Takezaki, Kentaro Ito, Yue Shi, Makoto Kobayashi, Minoru Osada
Summary: Recent progress in 2D materials has led to the exploration of molecularly thin amorphous materials with unique properties and structures. However, the synthesis of molecularly thin amorphous silica remains a challenge, and the existence of free-standing silica nanosheets is still uncertain. In this study, a new chemical protocol is introduced, where solid-state surfactant lamellae with ordered alkyl-chain arrangements act as templates to guide the formation of free-standing amorphous silica nanosheets. Sonication of the lamellar hybrids results in the exfoliation of monolayer amorphous silica nanosheets with a thickness of 0.9 nm. These nanosheets also exhibit high colloidal stability, enabling atomic layer engineering of silica nanocoatings and dielectric nanofilms. This approach offers new insights into the properties and applications of silica.
Article
Chemistry, Physical
Akihiko Kudo, Yoshihisa Sakata, Junko N. Kondo, Michikazu Hara, Jun Kubota, Shigeru Ikeda, Tsuyoshi Takata, Ryu Abe, Atsushi Takagaki, Takashi Hisatomi
Summary: Professor Kazunari Domen has focused on the research of catalysis, including the development of various photocatalysts, such as layered oxide and oxynitride photocatalysts, as well as oxysulfide photocatalysts with visible-light response. He has also explored water splitting using mechanocatalysis with metal oxides suspended in distilled water. In addition, Professor Domen has advanced the understanding of catalytic mechanisms through spectroscopic techniques such as transmission infrared spectroscopy and interfacial sum-frequency spectroscopy. Furthermore, he has investigated the use of carbon-based and layered solid acid materials as efficient catalysts.
Article
Chemistry, Physical
Aoi Matsuda, Kazuhiko Obara, Atsushi Ishikawa, Meng-Hsuan Tsai, Chia-Hsin Wang, Yu-Chuan Lin, Michikazu Hara, Keigo Kamata
Summary: The direct oxidation of methane to formaldehyde using molecular oxygen as the sole oxidant was studied over different bismuth-based catalysts. Among the catalysts tested, monoclinic BiPO4 nanoparticles synthesized in a mixed solvent of diethylene glycol (DEG) and water showed the highest catalytic activity and selectivity for formaldehyde formation.
CATALYSIS SCIENCE & TECHNOLOGY
(2023)
Article
Chemistry, Multidisciplinary
Masashi Hattori, Natsuo Okuyama, Hiyori Kurosawa, Michikazu Hara
Summary: The Haber-Bosch process is used to produce ammonia for over 5 billion people, but now it is required to be produced without the use of fossil fuels to reduce global CO2 emissions by 3% or more. It is crucial to develop heterogeneous catalysts for ammonia synthesis below 100-150 degrees C to minimize energy consumption. This paper reports metallic iron particles combined with an electron-donating material as a catalyst for ammonia synthesis, which can catalyze ammonia synthesis even at 100 degrees C. The iron catalyst exhibits a high turnover frequency and can desorb adsorbed hydrogen atoms as hydrogen molecules at low temperatures.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
(2023)
Article
Materials Science, Ceramics
Ki-Nam Byun, Yue Shi, Eisuke Yamamoto, Makoto Kobayashi, Minoru Osada
Summary: We introduce a novel approach to design flexible energy storage capacitors using two-dimensional inorganic nanosheets. Ca2Nb3O10 nanosheet and PVDF are chosen as model materials. A (Ca2Nb3O10/PVDF) nanocomposite film is fabricated on an ITO-coated PET substrate using the Langmuir-Blodgett deposition technique. This new composite design demonstrates improved energy density (37 J cm13) and efficiency (378%) even in ultra-thin form (320 nm) on the ITO-coated PET substrate, while maintaining stable performance after 104 bending cycles. These findings illustrate the technological significance of our nanosheet approach in exploring new flexible dielectric capacitors.
JOURNAL OF THE CERAMIC SOCIETY OF JAPAN
(2023)
Article
Chemistry, Physical
Kaoru Yamazaki, Shunsuke Goto, Shunya Yoshino, Anna Gubarevich, Katsumi Yoshida, Hideki Kato, Masanori Yamamoto
Summary: Nanoporous graphene materials exhibit remarkable electrochemical stability and possess the seamless graphene structures developed over the 3D space.
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
(2023)
Article
Chemistry, Physical
Daniele Padovan, Koichiro Endo, Takeshi Matsumoto, Toshiyuki Yokoi, Atsushi Fukuoka, Hideki Kato, Kiyotaka Nakajima
Summary: The acid-base properties of amphoteric crystalline YNbO4 are adjusted by impregnating phosphate groups, resulting in materials with increased activity and selectivity in glucose dehydration. The introduction of phosphate groups leads to the optimal catalyst, 5P-YNbO4, which exhibits 50% selectivity at 75% conversion. The catalyst can be deactivated due to carbon deposits, but its activity can be completely recovered through washing and calcination.
Article
Chemistry, Physical
Zi-Ye Liu, Qian-Yu Wang, Ji-Ming Hu
Summary: In this study, a layered carbon dot composite catalyst (NiFe LDH@CDs) was prepared using a one-step coprecipitation method, without the need for heating or hydrothermal treatment. The CD-functionalized catalyst facilitated rapid charge transfer and accelerated the oxygen evolution reaction. Additionally, the heterojunction structure formed between NiFe LDH and CDs efficiently suppressed photoelectron-hole recombination.
CATALYSIS SCIENCE & TECHNOLOGY
(2024)
Article
Chemistry, Physical
Rohit Kumar, Ankit Kumar Srivastava, Palaniyappan Nagarasu, Vedichi Madhu, Ekambaram Balaraman
Summary: We designed and synthesized a NN-CoII bidentate complex and used it for the amination of alcohols under mild and solventless conditions. The complex exhibited good reactivity towards both primary and sterically hindered secondary alcohols, providing high yields of amines. The pyrazole moiety in the ligand played a crucial role in the reaction. Furthermore, we demonstrated the reusability of the complex as a homogeneous cobalt catalyst.
CATALYSIS SCIENCE & TECHNOLOGY
(2024)
Article
Chemistry, Physical
Shivanand Chettri, Liang-Ting Wu, Sagarmani Rasaily, Debesh Sharma, Bikram Gurung, Rajani Dewan, Sudarsan Tamang, Jyh-Chiang Jiang, Anand Pariyar
Summary: Replicating the enzymatic surface microenvironment in vitro is challenging, but constructing an analogous model could facilitate our understanding of surface effects and aid in developing an efficient bioinspired catalytic system. In this study, five unique Cu2O morphologies were generated, and the surface morphology variations were found to be a consequence of differences in the exposure of low-index facets. The reactivity of Cu2O was found to be influenced by the proportion of {110} planes, with r-Cu2O exhibiting the highest reactivity.
CATALYSIS SCIENCE & TECHNOLOGY
(2024)
Article
Chemistry, Physical
Yong Tang, Jianhao Qiu, Dingliang Dai, Guanglu Xia, Lu Zhang, Jianfeng Yao
Summary: Defect engineering has been shown to improve the photocatalytic performance. This study investigated the use of defect-rich UiO-66-NH2 wrapped by ZnIn2S4 as a catalyst for photocatalytic H2O2 production. The defects in UiO-66-NH2 enhanced O-2 adsorption and charge separation, leading to higher H2O2 yield. The insights from this work can advance the research in defect engineering of MOFs and photocatalytic H2O2 synthesis.
CATALYSIS SCIENCE & TECHNOLOGY
(2024)
Article
Chemistry, Physical
Ruiyang Qu, Shuxin Mao, Jana Weiss, Vita A. Kondratenko, Evgenii V. Kondratenko, Stephan Bartling, Haifeng Qi, Annette-Enrica Surkus, Kathrin Junge, Matthias Beller
Summary: The hydrogenation of amides, a challenging reaction usually performed at high temperatures, has been achieved under milder conditions using a new Pt-MoOx/TiO2 catalyst. This catalyst system enables the selective hydrogenation of various amides and imides.
CATALYSIS SCIENCE & TECHNOLOGY
(2024)
Article
Chemistry, Physical
Xiaoran Niu, Ao Wang, Lei Tong, Lei Wang, Yuan Kong, Chenliang Su, Hai-Wei Liang
Summary: This study introduces a novel intermetallic PdCu3 catalyst supported on defective nanodiamond-graphene (ND@G), which exhibits high selectivity (95%) and remarkable activity (turnover frequency: 2940 h(-1)), six times higher than that of the commercial Lindlar catalyst.
CATALYSIS SCIENCE & TECHNOLOGY
(2024)
Review
Chemistry, Physical
Zhiyuan Zheng, Yiming Yue, Hongying Zhuo, Qinggang Liu, Yanqiang Huang
Summary: This review presents the recent research advances on single-atom catalysis for deep reduction of CO2. Detailed introductions and summaries were classified into three categories based on proton-coupled multi-electron transfer approaches: strengthening metal-support interaction, rational design and regulation of coordination environment, and development of SACs with multi-atom active sites. The challenges and future research directions in the field of SACs for CO2 reduction are also proposed.
CATALYSIS SCIENCE & TECHNOLOGY
(2024)
Article
Chemistry, Physical
Shiv Kumar, Paramita Datta, Anup Bhunia, Swadhin K. Mandal
Summary: This article reports a transition-metal-free process for in situ denitrogenation of tosylhydrazones, resulting in the production of various sulfones. The authors used a phenalenyl-based odd alternant hydrocarbon as a photoredox catalyst, which acted as a potent oxidant to facilitate the denitrogenation reaction. The method showed wide functional-group tolerance and high yields, making it suitable for late-stage modification of natural products.
CATALYSIS SCIENCE & TECHNOLOGY
(2024)
Article
Chemistry, Physical
L. A. Luque-Alvarez, J. Gonzalez-Arias, F. Romero-Sarria, T. R. Reina, L. F. Bobadilla, J. A. Odriozola
Summary: Currently, the production of acetic acid through the carbonylation reaction of methanol has limitations, leading to the exploration of alternative methods using heterogeneous catalysts. This study investigates the methanol carbonylation reaction over a Cu-H-MOR catalyst and proposes a reaction mechanism based on the catalytic behavior and performance of the catalyst. The results provide insights into the reaction mechanism and the involvement of acid and redox centers.
CATALYSIS SCIENCE & TECHNOLOGY
(2024)
