4.6 Article

Amination and dehydration of 1,3-propanediol by hydrogen transfer: reactions of a bio-renewable platform chemical

Journal

CATALYSIS SCIENCE & TECHNOLOGY
Volume 2, Issue 2, Pages 288-290

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c1cy00339a

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Funding

  1. EPSRC [EP/E010636/1]
  2. Queen's University Belfast
  3. Engineering and Physical Sciences Research Council [EP/E010636/1] Funding Source: researchfish

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1,3-propanediol was subjected to a range of amination conditions. The N-heterocyclic carbene piano stool complex [Cp*IrCl2(bmim)] was found to be a good catalyst for amination and dehydration in toluene or ionic liquid; product compositions could be tuned by altering the ratio of diol to amine.

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