Formal hydrogenation of arynes with silyl Cβ–H bonds as an active hydride source

Mechanistic Switch in Dual Gold Catalysis of Diynes: C(sp3)-H Activation through Bifurcation-Vinylidene versus Carbene Pathways

(2013) Max M. Hansmann et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Alkane C–H Insertion by Aryne Intermediates with a Silver Catalyst

(2013) Sang Young Yun et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Alkane desaturation by concerted double hydrogen atom transfer to benzyne

(2013) Dawen Niu et al.   NATURE

Synthesis of complex benzenoids via the intermediate generation of o-benzynes through the hexadehydro-Diels-Alder reaction

(2013) Beeraiah Baire et al.   Nature Protocols

Alder-Ene Reactions of Arynes

(2013) Rajdip Karmakar et al.   ORGANIC LETTERS

Fused Heteroaromatic Dihydrosiloles: Synthesis and Double-Fold Modification

(2013) Alexey Kuznetsov et al.   ORGANIC LETTERS

Silver-mediated fluorination, trifluoromethylation, and trifluoromethylthiolation of arynes

(2013) Kung-Pern Wang et al.   Chemical Science

Tactics for probing aryne reactivity: mechanistic studies of silicon–oxygen bond cleavage during the trapping of (HDDA-generated) benzynes by silyl ethers

(2013) Thomas R. Hoye et al.   Chemical Science

Gold Catalysis 2.0

(2013) Ingo Braun et al.   ACS Catalysis

On the Interpretation of Deuterium Kinetic Isotope Effects in CH Bond Functionalizations by Transition-Metal Complexes

(2012) Eric M. Simmons et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Simple Gold-Catalyzed Synthesis of Benzofulvenes-gem-Diaurated Species as “Instant Dual-Activation” Precatalysts

(2012) A. Stephen K. Hashmi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Comprehensive History of Arynes in Natural Product Total Synthesis

(2012) Pamela M. Tadross et al.   CHEMICAL REVIEWS

C–H Bond Functionalization via Hydride Transfer: Formation of α-Arylated Piperidines and 1,2,3,4-Tetrahydroisoquinolines via Stereoselective Intramolecular Amination of Benzylic C–H Bonds

(2012) Paul A. Vadola et al.   JOURNAL OF ORGANIC CHEMISTRY

Steric Effects Compete with Aryne Distortion To Control Regioselectivities of Nucleophilic Additions to 3-Silylarynes

(2012) Sarah M. Bronner et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

The hexadehydro-Diels–Alder reaction

(2012) Thomas R. Hoye et al.   NATURE

Aryne Insertion Reactions into Carbon-Carbon σ-Bonds

(2012) Hiroto Yoshida et al.   SYNLETT

Concerted vs Stepwise Mechanisms in Dehydro-Diels–Alder Reactions

(2011) Aida Ajaz et al.   JOURNAL OF ORGANIC CHEMISTRY

Base-Mediated Intermolecular sp2C−H Bond Arylation via Benzyne Intermediates

(2011) Thanh Truong et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Experimental and Computational Evidence for Gold Vinylidenes: Generation from Terminal Alkynes via a Bifurcation Pathway and Facile C–H Insertions

(2011) Longwu Ye et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ynamides: A Modern Functional Group for the New Millennium

(2010) Kyle A. DeKorver et al.   CHEMICAL REVIEWS

C−H Bond Activation of Benzene by Unsaturated η2-Cyclopropene and η2-Benzyne Complexes of Niobium

(2010) Cédric Boulho et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Indolyne and Aryne Distortions and Nucleophilic Regioselectivites

(2010) Paul H.-Y. Cheong et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Hydroalkylation of Alkynyl Ethers via a Gold(I)-Catalyzed 1,5-Hydride Shift/Cyclization Sequence

(2010) Igor Dias Jurberg et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Gold(I)-Catalyzed Rearrangement of Propargyl Benzyl Ethers: A Practical Method for the Generation and in Situ Transformation of Substituted Allenes

(2010) Benoit Bolte et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

RECENT APPLICATIONS OF ARYNE CHEMISTRY TO ORGANIC SYNTHESIS. A REVIEW

(2009) Roberto Sanz   ORGANIC PREPARATIONS AND PROCEDURES INTERNATIONAL

A Metal-Templated 4 + 2 Cycloaddition Reaction of an Alkyne and a Diyne To Form a 1,2-Aryne

(2009) Jordan A. Tsui et al.   ORGANOMETALLICS

The gem-disubstituent effect—a computational study that exposes the relevance of existing theoretical models

(2009) Rafik Karaman   TETRAHEDRON LETTERS

Density Functionals with Broad Applicability in Chemistry

(2008) Yan Zhao et al.   ACCOUNTS OF CHEMICAL RESEARCH

Scope of the Thermal Cyclization of Nonconjugated Ene–Yne–Nitrile System: A Facile Synthesis of Cyanofluorenol Derivatives

(2008) Hidenori Kimura et al.   CHEMISTRY LETTERS

Orthogonal Synthesis of Indolines and Isoquinolines via Aryne Annulation

(2008) Christopher D. Gilmore et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY