Total synthesis of hyacinthacine A2: stereocontrolled 5-aza-cyclooctene photoisomerization and transannular hydroamination with planar-to-point chirality transfer

Photochemical Reactions as Key Steps in Natural Product Synthesis

(2011) Thorsten Bach et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Tetrazine-trans-cyclooctene ligation for the rapid construction of integrin αvβ3 targeted PET tracer based on a cyclic RGD peptide

(2011) Ramajeyam Selvaraj et al.   BIOORGANIC & MEDICINAL CHEMISTRY LETTERS

Planar-to-PlanarChirality Transfer in the Excited State. Enantiodifferentiating Photoisomerization of Cyclooctenes Sensitized by Planar-Chiral Paracyclophane

(2011) Ryo Maeda et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Design and Synthesis of Highly Reactive Dienophiles for the Tetrazine–trans-Cyclooctene Ligation

(2011) Michael T. Taylor et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric Synthesis of Polyhydroxylated Pyrrolizidines via Transannular Iodoamination with ConcomitantN-Debenzylation

(2011) E. Anne Brock et al.   ORGANIC LETTERS

Tetrazine–trans-cyclooctene ligation for the rapid construction of 18F labeled probes

(2010) Zibo Li et al.   CHEMICAL COMMUNICATIONS

Strained organosilacyclic compounds: synthesis of anti-Bredt olefins and trans-dioxasilacyclooctenes

(2010) Michel Prévost et al.   DALTON TRANSACTIONS

Recent Developments in the Synthesis of Pyrrolidine-Containing Iminosugars

(2010) Bridget L. Stocker et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Enantioselective Synthesis of Planar Chiral Organonitrogen Cycles

(2010) Katsuhiko Tomooka et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Silylene-Mediated Polarity Reversal of Dienoates: Additions of Dienoates to Aldehydes at the δ-Position To Formtrans-Dioxasilacyclononenes

(2010) Christian C. Ventocilla et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A flexible approach for the asymmetric syntheses of hyacinthacines A2, A3 and structural confirmation of hyacinthacine A3

(2010) Wen-Jun Liu et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Total Synthesis of Rhazinilam: Axial to Point Chirality Transfer in an Enantiospecific Pd-Catalyzed Transannular Cyclization

(2010) Zhenhua Gu et al.   ORGANIC LETTERS

Ring Strain Energy in the Cyclooctyl System. The Effect of Strain Energy on [3 + 2] Cycloaddition Reactions with Azides

(2009) Robert D. Bach   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Insertions of Silylenes into Vinyl Epoxides: Diastereoselective Synthesis of Functionalized, Optically Activetrans-Dioxasilacyclooctenes

(2009) Michel Prévost et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Stereoselective syntheses of the glycosidase inhibitors hyacinthacine A2, hyacinthacine A3 and 5-epi-hyacinthacine A3

(2009) Celia Ribes et al.   TETRAHEDRON

Synthesis of d-arabinose-derived polyhydroxylated pyrrolidine, indolizidine and pyrrolizidine alkaloids. Total synthesis of hyacinthacine A2

(2009) Ignacio Delso et al.   TETRAHEDRON

Hydroamination: Direct Addition of Amines to Alkenes and Alkynes

(2008) Thomas E. Müller et al.   CHEMICAL REVIEWS

Total Synthesis of (+)-Alexine by Utilizing a Highly Stereoselective [3+2] Annulation Reaction of anN-Tosyl-α-Amino Aldehyde and a 1,3-Bis(silyl)propene

(2008) Martina Dressel et al.   CHEMISTRY-A EUROPEAN JOURNAL

Building Bicyclic Polyhydroxylated Alkaloids: An Overview from 1995 to the Present

(2008) M. Lopez et al.   CURRENT ORGANIC CHEMISTRY

A Photochemical Synthesis of Functionalizedtrans-Cyclooctenes Driven by Metal Complexation

(2008) Maksim Royzen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mechanistic Studies of a Palladium-Catalyzed Intramolecular Hydroamination of Unactivated Alkenes:  Protonolysis of a Stable Palladium Alkyl Complex Is the Turnover-Limiting Step

(2008) Brian M. Cochran et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Tetrazine Ligation: Fast Bioconjugation Based on Inverse-Electron-Demand Diels−Alder Reactivity

(2008) Melissa L. Blackman et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

New asymmetric strategy for the total synthesis of naturally occurring (+)-alexine and (−)-7-epi-alexine

(2008) Masaki Takahashi et al.   TETRAHEDRON

Asymmetric synthesis of (−)- and (+)-kainic acid using a planar chiral amide as a chiral building block

(2008) Katsuhiko Tomooka et al.   TETRAHEDRON LETTERS

Intermolecular Hydroaminations via Strained (E)-Cycloalkenes

(2007) Joseph Moran et al.   JOURNAL OF ORGANIC CHEMISTRY