Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 133, Issue 27, Pages 10379-10381Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja203781f
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Funding
- Japan Society for the Promotion of Science [21245011, 21350119, 23350018]
- Mitsubishi Chemical Corporation Fund
- Waseda University [2009A-605]
- Grants-in-Aid for Scientific Research [21350119, 23350018, 21245011, 23655096] Funding Source: KAKEN
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Photochemical planar-to-planar chirality transfer was effected by using (R)-[10] paracyclophane-12-carboxylates as a planar-chiral sensitizer and (Z)-cyclooctene and (Z,Z)-1,5-cyclooctadiene as prochiral substrates to give a planar-chiral (E)and (E,Z)-isomer in up to 44% and 87% enantiomeric excess, respectively, the latter of which being the highest ever reported for a sensitized photochirogenic reaction.
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