4.8 Article

A new insight into membrane fouling mechanism in submerged membrane bioreactor: Osmotic pressure during cake layer filtration

Journal

WATER RESEARCH
Volume 47, Issue 8, Pages 2777-2786

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.watres.2013.02.041

Keywords

Membrane bioreactor; Membrane fouling; Extracellular polymeric substances; Osmotic pressure

Funding

  1. National Natural Science Foundation of China [51108424, 21107099, 21003109, 21275130]
  2. Qianjiang Talent Project of Zhejiang Province [2012R10061]
  3. Department of Education of Zhejiang Province [Y201121142]
  4. National Undergraduate Training Programs for Innovation and Entrepreneurship

Ask authors/readers for more resources

Big gap between experimental filtration resistance of cake layer formed on membrane surface and the hydraulic resistance calculated through the Carman-Kozeny equation, suggested the existence of a new membrane fouling mechanism: osmotic pressure during cake layer filtration in SMBR system. An osmotic pressure model based on chemical potential difference was then proposed. Simulation of the model showed that osmotic pressure accounted for the major fraction of total operation pressure, and pH, applied pressure and ionic strength were the key determining factors for osmosis effect. It was found that, variations of osmotic pressure with pH, applied pressure and added ionic strength were well coincident with perditions of model's simulation, providing the first direct evidences of the real occurrence of osmosis mechanism and the feasibility of the proposed model. These findings illustrate the essential role of osmotic pressure in filtration resistance, and improve fundamental understanding on membrane fouling in SMBR systems. (C) 2013 Elsevier Ltd. All rights reserved.

Authors

I am an author on this paper
Click your name to claim this paper and add it to your profile.

Reviews

Primary Rating

4.8
Not enough ratings

Secondary Ratings

Novelty
-
Significance
-
Scientific rigor
-
Rate this paper

Recommended

Article Chemistry, Multidisciplinary

A biobased flame retardant towards improvement of flame retardancy and mechanical property of ethylene vinyl acetate

Siyi Xu, Yue Han, Cheng Zhou, Jianxi Li, Liguo Shen, Hongjun Lin

Summary: A new biobased flame retardant (MHPA) was synthesized by neutralizing magnesium hydroxide (MH) with phytic acid (PA). Adding MHPA to ethylene vinyl acetate (EVA) significantly improved the fire retardancy, smoke suppression, and mechanical properties of the composites. The combination of MHPA and MH exhibited excellent carbonization and expansion effects, contributing to the improved flame retardancy.

CHINESE CHEMICAL LETTERS (2023)

Article Chemistry, Physical

Fe-N-C catalyst coated on carbon felt for efficient degradation of antibiotics via electro-Fenton process

Mengying Qian, Fangyu Zhuo, Yu Li, Penghui Yi, Yubei Gao, Weilu Zhou, Yanlong Sun, Jianrong Chen

Summary: In this study, a novel electro-Fenton system using Fe-N-C catalyst supported on carbon felt as the cathodic catalyst and air as the oxygen source was developed. The CF/Fe-N-C catalyst exhibited high efficiency in the degradation and mineralization of antibiotics in aqueous solution. It also demonstrated outstanding reusability and stability, and could be used for the in-situ fabrication of reticular nanostructure.

APPLIED SURFACE SCIENCE (2023)

Article Engineering, Environmental

High propensity of membrane fouling and the underlying mechanisms in a membrane bioreactor during occurrence of sludge bulking

Mengfei Wu, Meijia Zhang, Liguo Shen, Xinhua Wang, Deng Ying, Hongjun Lin, Renjie Li, Yanchao Xu, Huachang Hong

Summary: This study compared the fouling behaviors of a membrane bioreactor (MBR) operated at normal and sludge bulking stages, and explored the different mechanisms behind these behaviors. The results showed that the MBR could be stably operated for about 60 days without membrane cleaning in the normal stage, while daily membrane cleaning was required in the sludge bulking stage. Further characterizations revealed that the bulking sludge had lower dewaterability, smaller particle size, higher fractal dimension, higher viscosity, abundant filamentous bacteria, and different types of extracellular polymer substances (EPS). It was suggested that microbial community transition was responsible for the occurrence of sludge bulking, which in turn affected membrane fouling. Based on these findings, it was proposed that providing extra force to offset a chemical potential gap caused by foulant layer structure transition during sludge bulking is necessary to sustain filtration and prevent extremely high specific filtration resistance (SFR).

WATER RESEARCH (2023)

Article Engineering, Environmental

Graphene oxide assisted assembly of superhydrophilic MOF-based membrane with 2D/3D hybrid nanochannels for enhanced water purification

Lingya Fei, Cheng Chen, Liguo Shen, Yuyao Zhang, Boya Wang, Jiujing Xu, Bisheng Li, Saleem Raza, Hongjun Lin

Summary: A facile approach using graphene oxide (GO) as a 2D nano-surfactant to assist the dispersion and assembly of superhydrophilic amino acid-based Zr-MOF microcrystals into a bulge-structured membrane is reported. The resulting GO/MIP-202(Zr) membrane with 2D/3D hybrid nanochannels and enhanced hydrophilicity showed superior water permeance and antifouling performance, making it promising for water treatment applications.

CHEMICAL ENGINEERING JOURNAL (2023)

Review Chemistry, Inorganic & Nuclear

What happens when graphdiyne encounters doping for electrochemical energy conversion and storage

Shuning Yu, Junjie Chen, Cheng Chen, Mingzhu Zhou, Liguo Shen, Bisheng Li, Hongjun Lin

Summary: Graphdiyne (GDY) is a rising-star two-dimensional carbon allotrope that has been widely used in the field of electro-chemistry due to its unique properties. However, the pure GDY does not achieve optimum performance. The doping of heteroatoms into GDY can regulate its electronic structure and improve its performance. In this review, the preparation methods and various doping elements of heteroatom-doped GDY are introduced, and the electrochemical applications in energy conversion and storage are summarized. The challenges and opportunities of heteroatom-doped GDY are also discussed.

COORDINATION CHEMISTRY REVIEWS (2023)

Article Environmental Sciences

Novel thermodynamic mechanisms of co-conditioning with polymeric aluminum chloride and polyacrylamide for improved sludge dewatering: A paradigm shift in the field

Yansha Zeng, Zhe Wang, Zhenxiang Pan, Liguo Shen, Jiaheng Teng, Hongjun Lin, Jianzhen Zhang

Summary: This study investigated the combined effects of polymeric aluminum chloride (PAC) and polyacrylamide (PAM) on sludge dewatering, aiming to uncover the underlying mechanisms. The co-conditioning of 15 mg g-1 PAC and 1 mg g-1 PAM achieved optimal dewatering performance, significantly reducing the specific filtration resistance (SFR) of the co-conditioned sludge. The findings provide insights into the improved dewatering performance and the thermodynamic mechanisms of sludge dewatering with different chemical conditioning.

ENVIRONMENTAL RESEARCH (2023)

Article Chemistry, Physical

Preparation of NaNbO3 microcube with abundant oxygen vacancies and its high photocatalytic N2 fixation activity in the help of Pt nanoparticles

Jiayu Zhang, Lin Yue, Zhihao Zeng, Chunran Zhao, Linjiang Fang, Xin Hu, Hongjun Lin, Leihong Zhao, Yiming He

Summary: The photocatalytic N2 immobilization performance of NaNbO3 is enhanced via oxygen vacancy introduction and Pt loading. The Pt-loaded NaNbO3 with rich oxygen defects (Pt/O-NaNbO3) is synthesized by combining ion-exchange and photodeposition methods. The introduction of oxygen defects greatly affects the energy band structure, resulting in higher photoactivity and NH3 production rate compared to O-NaNbO3 and NaNbO3. The loaded Pt nanoparticles further increase surface charge separation, contributing to the increased photocatalytic activity.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2023)

Article Environmental Sciences

One-step preparation of MoOX/ZnS/ZnO composite and its excellent performance in piezocatalytic degradation of Rhodamine B under ultrasonic vibration

Song Zheng, Xiaojing Li, Jiayu Zhang, Junfeng Wang, Chunran Zhao, Xin Hu, Ying Wu, Yiming He

Summary: This paper synthesized a new type of ternary piezoelectric catalyst MoOX/ZnS/ZnO (MZZ) and studied its catalytic degradation performance of Rhodamine B solution. The results showed that the MZZ catalyst exhibited excellent piezoelectric catalytic activity due to its core-shell structure and heterojunction structure.

JOURNAL OF ENVIRONMENTAL SCIENCES (2023)

Article Engineering, Chemical

Greatly boosted photocatalytic N2-to-NH3 conversion by bismuth doping in CdMoO4: Band structure engineering and N2 adsorption modification

Junfeng Wang, Lifang Guan, Shude Yuan, Jiayu Zhang, Chunran Zhao, Xin Hu, Botao Teng, Ying Wu, Yiming He

Summary: This work enhances the photocatalytic N2 immobilization performance of CdMoO4 through Bi doping, which reduces the particle size and narrows the band gap. The Bi-doped CdMoO4 exhibits a stronger ability in generating and separating charge carriers than CdMoO4. N2 has stronger adsorption at the unsaturated Mo sites of Bi-doped CdMoO4 due to the interactions between the 2 pi* orbital of N2 with the d orbital of Mo, leading to excellent photocatalytic N2-to-NH3 performance.

SEPARATION AND PURIFICATION TECHNOLOGY (2023)

Article Engineering, Environmental

A novel flower-like nickel-metal-organic framework (Ni-MOF) membrane for efficient multi-component pollutants removal by gravity

Lei Han, Jing Ma, Hongjun Lin, Cheng Chen, Jiaheng Teng, Bisheng Li, Dieling Zhao, Yanchao Xu, Wei Yu, Liguo Shen

Summary: The recycling of wastewater with multiple pollutants is an urgent issue, and gravity-driven membrane separation with metal-organic frameworks (MOFs) as membrane modifications has shown great potential. In this study, a novel Ni-MOF membrane was prepared by synthesizing flower-like nickel-based MOF particles and assembling them on a nylon membrane. The Ni-MOF membrane exhibited superhydrophilic and underwater superoleophobic properties, and demonstrated significantly improved rejection rates for various dye solutions, oil-water emulsion, and microplastic wastewater, while maintaining long-term stability. These findings highlight the broad application prospects of Ni-MOF membranes in wastewater treatment.

CHEMICAL ENGINEERING JOURNAL (2023)

Article Engineering, Environmental

Titanium oxide nanotubes intercalated two-dimensional MXene composite membrane with exceptional antifouling and self-cleaning properties for oil/water separation

Qianqian Zeng, Die Ling Zhao, Liguo Shen, Hongjun Lin, Ning Kong, Lei Han, Cheng Chen, Jiaheng Teng, Chuyang Tang, Tai-Shung Chung

Summary: This study inserted titanium oxide nanotubes into the interlayer space of 2D MXene-based membranes to prepare PMT membranes with excellent performance. The PMT membrane has outstanding hydrophilicity, high retention rates, and ultra-high permeability. It also exhibits excellent antifouling and self-cleaning properties. The incorporation of TiONT increased the interaction energy between the membrane and pollutants, thereby improving its antifouling performance. This novel 2D membrane shows great promise for large-scale continuous separations of oil/water emulsions.

CHEMICAL ENGINEERING JOURNAL (2023)

Article Engineering, Chemical

Transversal nanochannel-enabled MXene laminated membranes for superior oil-water separation: A fluid mosaic cytomembrane inspired approach

Ning Kong, Liguo Shen, Qianqian Zeng, Cheng Chen, Jiaheng Teng, Yanchao Xu, Leihong Zhao, Hongjun Lin

Summary: A novel approach involving the synthesis of ultra-thin MXene and ferroferric oxide doped molybdenum disulfide (FM) was developed to improve the performance of MXene membranes for oil separation. The resulting membranes showed enhanced interface hydrophilicity, increased surface roughness, and improved permeability, leading to high water flux and efficient oil separation.

JOURNAL OF MEMBRANE SCIENCE (2023)

Article Chemistry, Multidisciplinary

In Situ Fabrication of an S-Scheme NaNbO3/Bi2O2CO3 Heterojunction for Enhanced Performance in Photocatalytic Nitrogen Fixation

Lin Yue, Jiayu Zhang, Zhihao Zeng, Chunran Zhao, Xin Hu, Leihong Zhao, Bing Zhao, Yiming He

Summary: In this study, NaNbO3 microcubes were used to construct a series of NaNbO3/Bi2O2CO3 heterojunctions with different NaNbO3 content. The photoactivity of these heterojunctions for N-2 fixation was examined, and the results showed that 7.5% NaNbO3/Bi2O2CO3 had the highest photoactivity. A comprehensive investigation on the physical and chemical properties of the NaNbO3/Bi2O2CO3 photocatalyst was conducted, and it was found that the addition of NaNbO3 did not affect the photoabsorption performance and specific surface area of Bi2O2CO3. However, the tight contact and appropriate band positions between NaNbO3 and Bi2O2CO3 resulted in the formation of a heterojunction structure, allowing efficient separation of photogenerated electrons and holes and achieving exceptional performance in the photocatalytic nitrogen fixation reaction.

LANGMUIR (2023)

Article Materials Science, Multidisciplinary

Fabrication of novel BiPO4/Bi4O5Br2 heterojunctions for improving photoactivity in N2 fixation and dye degradation

Chunran Zhao, Xiaojing Li, Lin Yue, Xujie Ren, Shude Yuan, Zhihao Zeng, Yiming He

Summary: BiPO4/Bi4O5Br2 composites were synthesized and applied for photocatalytic N2 fixation and dye degradation for the first time. The synthesized BiPO4/Bi4O5Br2 exhibited exceptional photocatalytic performance under simulated solar light. Various techniques were employed to characterize the prepared photocatalysts, revealing the enhancement of charge separation as the primary factor affecting the photocatalytic performance.

MATERIALS RESEARCH BULLETIN (2023)

Article Engineering, Chemical

S-scheme Bi2O3/CdMoO4 hybrid with highly efficient charge separation for photocatalytic N2 fixation and tetracycline Degradation: Fabrication, catalytic Optimization, physicochemical studies

Shude Yuan, Junfeng Wang, Chunran Zhao, Lin Yue, Xujie Ren, Zhihao Zeng, Xin Hu, Ying Wu, Yiming He

Summary: This study designed and synthesized a novel composite photocatalyst of Bi2O3/CdMoO4 using a deposition-oxidation method. It investigated the morphology, specific surface area, structure, optical properties, and photoelectric chemical properties of the Bi2O3/CdMoO4 composite. The results showed that the dispersion of Bi2O3 nanoparticles on the surface of CdMoO4 polymers increased light absorption and facilitated the photocatalytic reaction. The presence of a tight contact between CdMoO4 and Bi2O3 resulted in the formation of a heterojunction structure, promoting the separation efficiency of electron-hole pairs through an S-scheme mechanism.

SEPARATION AND PURIFICATION TECHNOLOGY (2023)

Article Engineering, Environmental

Parabens and their metabolite in a marine benthic-dominated food web from the Beibu gulf, South China Sea: Occurrence, trophic transfer and health risk assessment

Rong-Gui Zhu, Chang-Gui Pan, Feng-Jiao Peng, Chao-Yang Zhou, Jun-Jie Hu, Kefu Yu

Summary: This comprehensive survey investigated the occurrence, bioaccumulation, and trophic magnification of parabens and their metabolite 4-HB in a marine food web. Results showed that parabens were the predominant pollutants in marine organisms, with significant bioaccumulation from sediments. The estimated trophic magnification factor indicated biomagnification for MeP and trophic dilution for 4-HB. Overall, the risks for humans consuming marine organisms were found to be low.

WATER RESEARCH (2024)

Article Engineering, Environmental

Partitioning and inactivation of enveloped and nonenveloped viruses in activated sludge, anaerobic and microalgae-based wastewater treatment systems

Andres F. Torres-Franco, Deborah Leroy-Freitas, Cristina Martinez-Fraile, Elisa Rodriguez, Pedro A. Garcia-Encina, Raul Munoz

Summary: Anaerobic and microalgae-based technologies have emerged as sustainable alternatives for municipal wastewater treatment. However, the presence of viruses in the treated wastewater is a major concern for reuse applications. This study assessed the ability of these technologies to reduce viruses during secondary wastewater treatment. The results showed that all technologies were effective in reducing the concentration of viruses, with microalgae-based treatment exhibiting the highest potential for reducing the disinfection requirements of treated wastewater.

WATER RESEARCH (2024)

Article Engineering, Environmental

Reconsidering mercury sources and exposure pathways to bivalves: Insights from mercury stable isotopes

Young Gwang Kim, Sae Yun Kwon, Spencer J. Washburn, Scott C. Brooks, Ji Won Yoon, Lucien Besnard

Summary: The study uses Hg isotope ratios to identify the sources and exposure pathways of mercury in bivalves, finding that dissolved Hg phases in the water column are the primary source and exposure pathway to bivalves. This provides new insights into using bivalves as bioindicators for sediment quality monitoring.

WATER RESEARCH (2024)

Article Engineering, Environmental

Cation exchange resins enhance anaerobic digestion of sewage sludge: Roles in sequential recovery of hydrogen and methane

Hui Geng, Ying Xu, Rui Liu, Dianhai Yang, Xiaohu Dai

Summary: This study investigates the effect of cation exchange resin (CER) on the sequential recovery of hydrogen and methane from anaerobic digestion (AD) and the corresponding mechanisms. The results show that CER can simultaneously enhance the production of hydrogen and methane by promoting the solubilisation, hydrolysis, and acidification of organic matter. Additionally, CER facilitates effective contact between bacteria and organic particulates and reduces the energy barrier for mass transfer during methane production. The study also reveals changes in the microbial community structure and metagenomics during the AD process.

WATER RESEARCH (2024)

Article Engineering, Environmental

Fertilizer recovery from source-separated urine by evaporation with a combined process of dehumidification and the addition of absorbent resin supplement

Xiaojing Lin, Zhan Jin, Shunfeng Jiang, Zhiquan Wang, Suqing Wu, Ke Bei, Min Zhao, Xiangyong Zheng

Summary: Dehumidification combined with addition of absorbent resin supplement (ARS) was used to achieve rapid evaporation of non-pretreated urine, resulting in high water evaporation efficiency and nutrient recovery.

WATER RESEARCH (2024)

Article Engineering, Environmental

Influences of hydrodynamics on microbial community assembly and organic carbon composition of resuspended sediments in shallow marginal seas

Yangli Che, Chaoran Lin, Shen Li, Jiao Liu, Longhai Zhu, Shilei Yu, Nan Wang, Haoshuai Li, Mutai Bao, Yang Zhou, Tonghao Si, Rui Bao

Summary: Hydrodynamic processes play a crucial role in the transmission of sediments, microbial assembly, and organic carbon redistribution in the ocean. Through experiments and analysis, we found that hydrodynamics shape the assembly of microbial communities and control the redistribution of different sourced organic carbon, thereby influencing microbial-mediated biogeochemical transformation.

WATER RESEARCH (2024)

Article Engineering, Environmental

A comprehensive evaluation of the temporal and spatial fouling characteristics of RO membranes in a full-scale seawater desalination plant

Chao Chen, Yu Yang, Nigel J. D. Graham, Zhenyu Li, Xingtao Yang, Zhining Wang, Nadia Farhat, Johannes S. Vrouwenvelder, Li -an Hou

Summary: The fouling of seawater reverse osmosis membranes is a persistent challenge in desalination. This study monitored the operational performance of a desalination plant for 7 years and the fouling development in different areas of membrane modules. The findings showed that operational performance declined over time and fouling mainly occurred at the feed side of the modules, with the highest microbial diversity. Keystone species like Chloroflexi and Planctomycetes played an important role in maintaining community structure and biofilm maturation. Polysaccharides, soluble microbial products, marine humic acid-like substances, and inorganic substances contributed to fouling. Overall, biofouling had a significant impact on membrane fouling after 7 years of operation.

WATER RESEARCH (2024)

Article Engineering, Environmental

Fluctuating redox conditions accelerate the electron storage and transfer in magnetite and production of dark hydroxyl radicals

Dan Li, Jieyi Sun, Yibo Fu, Wentao Hong, Heli Wang, Qian Yang, Junhong Wu, Sen Yang, Jianhui Xu, Yunfei Zhang, Yirong Deng, Yin Zhong, Ping'an Peng

Summary: Sulfidation-oxidation treatment of magnetite (Fe3O4) enhances the production of dark center dot OH, which can efficiently degrade dissolved organic matter (DOM) and accelerate carbon cycling.

WATER RESEARCH (2024)

Article Engineering, Environmental

Full-scale upgrade activated sludge to continuous-flow aerobic granular sludge: Implementing microaerobic-aerobic configuration with internal separators

Cheng Yu, Kaijun Wang, Kaiyuan Zhang, Ruiyang Liu, Pingping Zheng

Summary: This study implemented a microaerobic-aerobic configuration in a full-scale municipal wastewater treatment facility and investigated the effects on sludge characteristics, pollutant removal, microbial community, and granulation mechanisms. The results showed successful transition from flocculent-activated sludge to well-defined AGS after two months of operation. The primary pathways for pollutant removal were simultaneous nitrification, denitrification, and phosphorus removal. Moreover, the incorporation of internal separators induced shifts in the flow pattern, which promoted granulation.

WATER RESEARCH (2024)

Article Engineering, Environmental

Target analysis, occurrence and cytotoxicity of halogenated polyhydroxyphenols as emerging disinfection byproducts in drinking water

Zhe Zhang, Shaoyang Hu, Guangrong Sun, Wei Wang

Summary: Halogenated aromatic disinfection byproducts (DBPs), such as halogenated phenols, have garnered widespread attention due to their high toxicity and prevalence. This study reports on the analysis, occurrence, and cytotoxicity of a group of emerging halogenated aromatic DBPs, known as halogenated polyhydroxyphenols (HPPs), in drinking water.

WATER RESEARCH (2024)

Article Engineering, Environmental

A coupled model to improve river water quality prediction towards addressing non-stationarity and data limitation

Shengyue Chen, Jinliang Huang, Peng Wang, Xi Tang, Zhenyu Zhang

Summary: Accurate prediction of river water quality is crucial for sustainable water management. This study introduces wavelet analysis and transfer learning techniques to assist LSTM modeling, proposing a newly coupled modeling approach that improves short-term prediction of river water quality.

WATER RESEARCH (2024)

Article Engineering, Environmental

Deciphering anaerobic ethanol metabolic pathways shaped by operational modes

Bang Du, Xinmin Zhan, Piet N. L. Lens, Yifeng Zhang, Guangxue Wu

Summary: Efficient anaerobic digestion relies on the cooperation of different microorganisms with different metabolic pathways. This study investigated the effects of different operational modes and the addition of powdered activated carbon (PAC) on ethanol metabolic pathways. The results showed that the SBR mode and the presence of CO2 facilitated ethanol metabolism towards propionate production, while the CFR mode with extended solids retention time enriched Geobacter. Adjusting operational modes and PAC addition can modulate anaerobic ethanol metabolism and enrich Geobacter.

WATER RESEARCH (2024)

Article Engineering, Environmental

Unraveling the factors influencing CO2 emissions from hydroelectric reservoirs in karst and non-karst regions: A comparative analysis

Wanfa Wang, Si-Liang Li, Jun Zhong, Yuanbi Yi, Fujun Yue, Zenglei Han, Qixin Wu, Ding He, Cong-Qiang Liu

Summary: This study compares the carbon biogeochemical processes in karst and non-karst regions within large thermal stratified river-reservoir systems. The results demonstrate that karst reservoirs have a reduced potential for carbon emissions and highlight the importance of considering geologic settings to improve accuracy in regional and global CO2 emission estimates.

WATER RESEARCH (2024)

Article Engineering, Environmental

Rare resistome rather than core resistome exhibited higher diversity and risk along the Yangtze River

Chunxia Jiang, Zelong Zhao, Dong Zhu, Xiong Pan, Yuyi Yang

Summary: This study analyzed the occurrence and distribution of antibiotic resistance genes (ARGs) in different environmental media of the Yangtze River using metagenomics. Core resistome dominated by multidrug resistance genes was found in all samples, while rare resistome dominated by various resistance genes was more prevalent in plasmids. Specific bacteria were identified as hosts for both core and rare resistomes, with high clinical concern ARGs found in the rare resistome. Particle-associated environment provided the most ideal conditions for resistome hosts. This study provided insights into the genetic locations of ARGs and the community assembly mechanisms of ARG hosts in freshwater environments.

WATER RESEARCH (2024)

Article Engineering, Environmental

Uncovering interactions among ternary electron donors of organic carbon source, thiosulfate and Fe0 in mixotrophic advanced denitrification: Proof of concept from simulated to authentic secondary effluent

Yu Zhang, Yongtao He, Linchun Jia, Lei Xu, Zheng Wang, Yueling He, Ling Xiong, Xumeng Lin, Hong Chen, Gang Xue

Summary: By synergizing organic carbon source, thiosulfate, and zero-valent iron, efficient mixotrophic denitrification of oligotrophic secondary effluent can be achieved. Thiosulfate plays a vital role in promoting TN removal efficiency, while corrosion of Fe0 releases OH- to neutralize H+ from thiosulfate-driven denitrification, creating a suitable environment for denitrification. The coordination of thiosulfate and Fe0 maintains the dominance of Thiobacillus for denitrification.

WATER RESEARCH (2024)