Journal
SURFACE & COATINGS TECHNOLOGY
Volume 259, Issue -, Pages 83-86Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.surfcoat.2014.05.061
Keywords
PMMA coating; Dispersion stability; Fluorescence stability; Oxidation; Degradation
Funding
- Human Resource Development Group program [20124030200130]
- Technology Innovation Program - Ministry of Trade, Industry and Energy (MTIE, Korea) [10043195]
- National Research Foundation of Korea (NRF) - Korea government (MSIP) [2008-0061891]
- Korea Evaluation Institute of Industrial Technology (KEIT) [10043195] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
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Surface overcoated CdSe/ZnSe core/shell structured quantum dots (QDs) with enhanced stability, narrow size distribution and strong photoluminescence have been successfully synthesized by using a simple poly(methylmethacrylate) (PMMA) coating on nanoparticles. When applied to the surface of QDs, the polymer coating provided ultra-dispersion stability and a high fluorescence quantum yield of above 80% that prevented chemical degradation, such as aggregation and Ostwald ripening. The degree of degradation was measured with respect to storage time (1, 7, 15, and 30 days) in order to provide a comparison between PMMA uncoated and coated QDs, and the oxidation of QDs was confirmed with Fourier transform infrared spectroscopy. (C) 2014 Elsevier B.V. All rights reserved.
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