Article
Crystallography
Ting Zheng, Haibo Li, Taijin Lu, Xiaoming Chen, Bowen Li, Yingying Liu
Summary: Copal resins can be modified to simulate the appearance and spectral characteristics of ambers through different temperature and pressure treatment methods. However, treated copal resins can still be distinguished from natural ambers through spectroscopic methods.
Article
Multidisciplinary Sciences
Penglun Zheng, Rui Wang, Donghui Wang, Xiaoliang Peng, Yang Zhao, Quanyi Liu
Summary: The hyperbranched phosphorus-containing copper phthalocyanine compound (DOPO-CuPc) was synthesized and used as a flame-retardant additive for epoxy thermosets, significantly improving the flame retardant properties. The mechanism involved the release of phosphorus-containing radicals and gases in both the gas and condensed phases, contributing to the formation and stability of a protective char layer during combustion.
SCIENTIFIC REPORTS
(2021)
Article
Chemistry, Multidisciplinary
Jean-Marc Nuzillard
Summary: The quick identification of known organic low molecular weight compounds, also known as structural dereplication, is a highly important task in the chemical profiling of natural resource extracts. This article presents the results of structure searches carried out starting from 58 carbon-13 NMR data sets recorded on compounds selected in the metabolomics section of the biological magnetic resonance bank (BMRB). Two compound retrieval methods were employed, and both methods proved to be efficient and can be used together in a complementary way.
MAGNETIC RESONANCE IN CHEMISTRY
(2023)
Article
Plant Sciences
Qi Wang, Yingxue Zhu, Lianzhou Xu, Baiyang Chen, Chunzhu Liu, Xianfa Ma, Qingfeng Meng, Bing Liu, Zongwei Huang, Yusheng Jiao, Ye Yuan
Summary: Biochar addition has a positive effect on soil organic carbon (SOC) content and soil quality improvement. However, the mechanisms and structural changes of soil humic substances under different types of biochar addition are poorly understood. This study compared the effects of rice husk, corn stalk, and tobacco stalk biochar on humus composition and humic acid (HA) structure in Northeast China. Results showed that corn stalk biochar significantly increased the fulvic acid (FA) content and simplified the HA structure, while tobacco stalk biochar was superior in soil carbon sequestration.
JOURNAL OF SOIL SCIENCE AND PLANT NUTRITION
(2023)
Article
Chemistry, Analytical
Cristina Riccucci, Gabriel Maria Ingo, Marianna Pascucci, Maria Paola Staccioli, Maria Isabella Pierige, Monica Albini
Summary: In this study, micro-structural and micro-chemical investigation of archaeological bronze artefacts from ancient necropolises in central Italy provided new insights into the metallurgical manufacture of defensive weapons, including cuirass discs. The research revealed the high technological level of the Samnite metallurgists and their ability to manipulate fragile high tin bronze alloys successfully.
MICROCHEMICAL JOURNAL
(2022)
Article
Food Science & Technology
Tong Chen, Yufei Shen, Di Wu, Rong Wu, Jie Sheng, Xiao Feng, Xiaozhi Tang
Summary: The study investigated the effects of laccase crosslinking on the structure and properties of chitosan-based biodegradable films, showing significant improvements in particle size, tensile strength, and antioxidant activity. Addition of tea polyphenols and laccase catalysis had synergistic effects on the properties of the films, making them more suitable for application.
Article
Biochemistry & Molecular Biology
Wolfgang Robien
Summary: This study systematically investigates the quality of experimental C-13-NMR spectra published in the journal Molecules from 1996 to 2015 using CSEARCH technology. The results show that using the CSEARCH-Robot-Referee during peer review can prevent trivial assignment errors and wrong structure proposals. Comparison of key numbers with other journals in natural product chemistry indicates a similar level of quality among publishers.
Article
Environmental Sciences
Sriharan Raguraj, Susilawati Kasim, Noraini Md Jaafar, Muhamad Hazim Nazli, Rathnasekara Kuruppu Arachchige Amali
Summary: There is a growing demand for humic substances, but coal-related resources, from which humic substances are extracted, are in short supply. Consequently, there is an interest in producing humic-like substances from lignocellulosic waste materials. In this study, tea waste was used to extract humic fractions, including purified humic-like acid and unpurified humic and fulvic acids. Comparative analyses were performed between these tea waste derived humic-like substances (TWDHLS) and commercially available humic acid (CHA) extracted from lignite. The results showed slight differences in elemental composition and FTIR properties, while NMR results indicated similar carbon distribution. TWDHLS exhibited a more recalcitrant nature due to the presence of stable compounds. The biological activity of TWDHLS was found to be comparable to that of CHA. These findings suggest that TWDHLS could be a potential plant biostimulant and a better substitute for humic substances.
ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH
(2022)
Article
Construction & Building Technology
Ren Wei, Yuya Sakai, Naoki Ogiwara, Sayaka Uchida
Summary: This study investigates the microstructural changes between concrete and kraft lignin (KL) in botanical concrete (BC), and the effects of temperature and air on BC performance. The results show that condensation reactions between concrete and KL fragments are the most influential factor in improving BC strength.
CONSTRUCTION AND BUILDING MATERIALS
(2023)
Article
Polymer Science
Katarzyna Sawicz-Kryniger, Pawel Niezgoda, Pawel Stalmach, Katarzyna Starzak, Alicja Wysocka, Tomasz Swiergosz, Roman Popielarz
Summary: The study investigated the addition polymerization of epoxy resins using Fluorescence Probe Technique (FPT), Fourier-Transform InfraRed spectroscopy (FTIR) and Differential Scanning Calorimetry (DSC) methods. Results showed that FPT provided reliable real-time monitoring of reaction kinetics and correlated well with FTIR and DSC measurements. The activation energies determined by FPT were consistent with those obtained by DSC and reported in literature, making FPT a promising alternative for kinetic studies of chemical reactions.
EUROPEAN POLYMER JOURNAL
(2022)
Article
Plant Sciences
Nathan Bryant, Wellington Muchero, Rachel A. Weber, Jaime Barros, Jin-Gui Chen, Timothy J. Tschaplinski, Yunqiao Pu, Arthur J. Ragauskas
Summary: The study found that the lignin content in the cell wall of Populus was significantly increased in the region infected by Septoria, and the composition of lignin in the infected region was also different. These results provide important insights into the wood characteristic changes of Populus during Septoria infection.
FRONTIERS IN PLANT SCIENCE
(2023)
Article
Chemistry, Multidisciplinary
Ziyi Li, Jun Li, Huazhen Rong, Jiayu Zuo, Xiong Yang, Yi Xing, Yingshu Liu, Guangshan Zhu, Xiaoqin Zou
Summary: This study reports a method of facilitating SO2/NO2 separation through NO2 dimerization. The NO2 dimerization is triggered by temperature and pressure, resulting in N2O4 with a larger molecular size, which inhibits N2O4 diffusion into the zeolite pore and achieves high separation selectivity. High performance SO2/NO2 separation was achieved on an SSZ-13 zeolite membrane.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
(2022)
Article
Chemistry, Physical
Lin Qian, Chao Tao, Chao Ma, Jinkai Xue, Feiqiang Guo, Xiaopeng Jia, Weijie Yan
Summary: The molecular structure of Zhundong coal (ZD) was characterized by physical detection techniques, and the complex structure was confirmed through various analyses, providing a reference for understanding the structural characteristics of ZD coal and helping to understand its reactivity.
JOURNAL OF MOLECULAR STRUCTURE
(2022)
Article
Chemistry, Physical
Maria Gunnarsson, Enamul Haque Mojumdar, Daniel Topgaard, Emma Sparr
Summary: The study investigates the impact of NMF on skin molecular dynamics and the reversal of its effects by adding specific NMF components. It was found that removing NMF reduces molecular mobility in the skin, but replacing it with single NMF components restores molecular dynamics.
JOURNAL OF COLLOID AND INTERFACE SCIENCE
(2021)
Article
Chemistry, Analytical
Xinyu Lu, Haoquan Guo, Han Que, Dandan Wang, Dingxiang Liang, Tao He, Hossain Mahmud Robin, Chaozhong Xu, Xingguang Zhang, Xiaoli Gu
Summary: Lignin extracted from bio-ethanol production residue was used to synthesize a novel lignin-based flame retardant agent, which showed enhanced thermal stability and flame retardancy in epoxy resin composites. The significant effects of the modified flame retardant agent were mainly observed in the early and final stages of decomposition compared to general lignocellulosic biomass materials.
JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS
(2021)
Article
Environmental Sciences
Vittoria Guglielmi, Martina Andreoli, Valeria Comite, Anna Baroni, Paola Fermo
Summary: The study aimed to identify the painter's materials used in wall decorations of destroyed buildings dating between the 1st century B.C. and the 1st century A.D. Analytical investigations were conducted using SEM-EDX, Raman, FTIR spectroscopies, and visible reflectance measurements, highlighting the use of non-destructive techniques in archaeological studies. The study revealed the use of well-known pigments like cinnabar, red ochre, hematite, and yellow ochre, as well as the possible use of bone white as a pigment in Roman wall decorations.
ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH
(2022)
Article
Environmental Sciences
Paola Fermo, Mario Colella, Marco Malagodi, Giacomo Fiocco, Michela Albano, Silvia Marchioron, Vittoria Guglielmi, Valeria Comite
Summary: The surface coating on a marble statue from the Renaissance period stored in Milan was studied and found to have a degradation layer composed of gypsum, likely due to exposure to outdoor environment and atmospheric pollution. Additionally, it was suggested that the chemical nature of the coating applied in the late 19th century could have contributed to the surface alteration.
ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH
(2022)
Article
Chemistry, Analytical
Margherita Longoni, Francesco Ferretti, Sofia Zucca, Letizia Caielli, Silvia Bruni
Summary: In this study, surface-enhanced Raman spectroscopy (SERS) was used for the identification of dyes in chromogenic films. The results showed that SERS spectroscopy is an efficient technique for this purpose, and the excellent SERS properties of anisotropic nanomaterials were confirmed.
Article
Biochemistry & Molecular Biology
Margherita Longoni, Carlotta Beccaria, Letizia Bonizzoni, Silvia Bruni
Summary: In this study, a thorough investigation was conducted on one of Fontana's artworks using non-invasive and micro-invasive methods, revealing the composition of the metallic paint layer and underlying dark layer.
Article
Chemistry, Analytical
Margherita Longoni, Ester Sara Cacciola, Silvia Bruni
Summary: This study analyzed a significant number of model painting samples using a prototype portable fluorimeter to investigate the possibility of identifying binders in ancient paintings through fluorescence emission. The study found that the technique allows for a preliminary identification of pure binders.
Article
Chemistry, Physical
Margherita Longoni, Serena Francone, Maddalena Boscacci, Diego Sali, Isabella Cavaliere, Vittoria Guglielmi, Silvia Bruni
Summary: Since their introduction in the early 20th century, fluorescent pigments have been widely used in various fields. The Italian Black Light Art movement utilizes different types of radiation (UV or visible light) to convey different aesthetic messages. Through non-invasive in-situ investigation techniques, the researchers successfully identified the materials used by the artists in Black Light Art paintings exhibited in Milan.
Article
Green & Sustainable Science & Technology
Chiara Andrea Lombardi, Valeria Comite, Paola Fermo, Andrea Bergomi, Luca Trombino, Vittoria Guglielmi
Summary: This study focuses on the analysis of the color palette used in the decoration of an Egyptian sarcophagus cover. Raman spectrometer and laboratory techniques such as microscopy, infrared spectroscopy, and luminescence imaging were employed. The results revealed the presence of specific pigments such as calcite, red ochre, black carbon, and Egyptian blue. The findings provide insights into the authenticity and composition of the sarcophagus.
Article
Biochemistry & Molecular Biology
Silvia Bruni, Margherita Longoni, Camilla Minzoni, Martina Basili, Ilaria Zocca, Stefano Pieraccini, Maurizio Sironi
Summary: Microanalysis techniques based on resonance Raman and reflection visible spectroscopy were used to characterize the pigments responsible for blue or violet coloration in flowers such as Lobelia erinus, Campanula portenschlagiana, Cineraria, Viola tricolor, Anemone coronaria, Agapanthus, Platycodon, Salvia farinacea, Plumbago capensis, Ceratostigma plumbaginoides, Commelina communis, and Salvia patens. The spectroscopic methods were applied both in vivo on the flower petals and in vitro on extracts obtained through solid-phase extraction. Different patterns in the Raman spectra were correlated with substitution schemes of anthocyanins' benzopyrilium nucleus and copigmentation forms responsible for blue color stabilization. The results were confirmed through comparison with analysis by liquid chromatography-electrospray ionization-mass spectrometry.
Article
Biochemistry & Molecular Biology
Andrea Bergomi, Valeria Comite, Vittoria Guglielmi, Mattia Borelli, Chiara Andrea Lombardi, Roberto Bonomi, Concetta Pironti, Maria Ricciardi, Antonio Proto, Carlo Mariani, Paola Fermo
Summary: In this study, the microclimatic conditions and air quality inside the Santuario della Beata Vergine dei Miracoli in Saronno (VA) were monitored. The results showed that despite lower indoor pollutant concentrations compared to the outdoor values, the microclimatic conditions often did not meet the regulations and standards in Italy.
Article
Environmental Sciences
Mattia Borelli, Andrea Bergomi, Valeria Comite, Vittoria Guglielmi, Chiara Andrea Lombardi, Stefania Gilardoni, Biagio Di Mauro, Marina Lasagni, Paola Fermo
Summary: The aim of this study was to develop a new method to quantify carbonaceous fractions that contribute significantly to darkening of snow and ice samples. Snow samples were collected at two Italian locations and analyzed using different techniques. The results showed a correlation between the nature of the sample and the experimental results, validating the proposed method.
Article
Chemistry, Multidisciplinary
Vittoria Guglielmi, Chiara Andrea Lombardi, Giacomo Fiocco, Valeria Comite, Andrea Bergomi, Mattia Borelli, Monica Azzarone, Marco Malagodi, Mario Colella, Paola Fermo
Summary: This research aimed to characterize the pigments used in a 15th-century polychrome earthenware bas-relief artwork. Various analysis methods such as optical microscopy, scanning electron microscopy, and Fourier-transform infrared microspectroscopy were used to identify the materials underneath the coating and discover different natural and synthetic pigments. In addition, portable Raman spectrometer measurements revealed the use of specific pigments and previous restoration traces, while the background was made with true gold, highlighting the significance and value of the artwork.
APPLIED SCIENCES-BASEL
(2023)
Article
Chemistry, Multidisciplinary
Vittoria Guglielmi, Valeria Comite, Chiara Andrea Lombardi, Andrea Bergomi, Elisabetta Boanini, Roberto Bonomi, Elisa Monfasani, Letizia Sassi, Mattia Borelli, Paola Fermo
Summary: The cleaning of historical tapestries is usually done using standard methods. A new hydro-aspiration method was developed to improve efficiency and compared to traditional cleaning methods. The new method was found to be more effective in removing dirt and preserving the structure of the tapestry's metallic threads, while being less invasive to the fragile surface patina.
APPLIED SCIENCES-BASEL
(2023)
Article
Humanities, Multidisciplinary
Margherita Longoni, Noemi Hopes, Federico Rossi, Miriam Rita Tessera, Marco Petoletti, Silvia Bruni
Summary: In this study, a method combining spectrofluorimetry and multivariate analysis was proposed for non-invasive investigation of natural dyes used in illuminations. The experimental conditions were optimized and applied to both mock-up samples and illuminated manuscripts. Satisfactory results were obtained for grouping samples with the same dye, demonstrating the effectiveness of the analytical protocol.
Article
Geochemistry & Geophysics
Silvia Bruni, Margherita Longoni, Francesca De Filippi, Noemi Calore, Giovanna Bagnasco Gianni
Summary: The mineralogical composition of archaeological pottery provides important information about the origin and manufacturing technology of ceramic artifacts. Techniques such as X-ray diffraction, Fourier-transform infrared spectroscopy, and petrographic analysis are commonly used to determine the mineralogical phases. This study investigates the non-invasive analysis of the mineralogical composition of archaeological pottery using reflection FTIR spectroscopy.
Article
Humanities, Multidisciplinary
Margherita Longoni, Norma Cicala, Vittoria Guglielmi, Gianluca Poldi, Silvia Bruni
Summary: This study investigated the materials used by the artist Silvio Pasotti in two paintings made on aluminium support. Various molecular analysis techniques were employed to identify the pigments and binders used, and imaging techniques were used to gain a better understanding of the painting practice.
Article
Spectroscopy
Zh. E. Ozbekova, A. A. Abdyldaev, A. A. Kulmyrzaev
Summary: This study compared two drying methods for cow and yak muscles, finding that freeze drying caused less discoloration. Additionally, analysis of fluorescence spectra allowed for accurate prediction of chemical composition and color characteristics of the muscles.
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
(2024)
Article
Spectroscopy
Leo Mandic, Ivan Ljubic, Iva Dzeba
Summary: In this study, a combined experimental and computational approach was used to investigate the photoexcitation and photodegradation mechanisms of Doxazosin (DOX). The results provide valuable insights into the primary events following the photoexcitation of DOX and its potential applications.
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
(2024)
Article
Spectroscopy
Xiufeng Wang, Yao Jin, Wenhui Ai, Siqi Wang, Zhiqing Zhang, Ting Zhou, Fang Wang, Guodong Zhang
Summary: This study successfully synthesized near infrared fluorescence Ag2S quantum dots (QDs) and developed a dual-mode sensor for sulfide anion using the excellent oxidase-like characteristics of manganese dioxide (MnO2) nanosheets. The sensor showed a wider detection range, higher sensitivity, and shorter reaction time, making it suitable for highly selective detection of sulfide in different concentration ranges.
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
(2024)
Article
Spectroscopy
Yafei Li, Yanming Ma, Chuantao Zheng, Di Yu, Lien Hu, Shuo Yang, Fang Song, Yadan Li, Shuanghai Liu, Zhanrui Zhang, Yu Zhang, Yiding Wang, Frank K. Tittel
Summary: To effectively monitor gas explosion and coal spontaneous combustion in coal mine, an intrinsically safe and explosion-proof dual-gas sensor system was developed for methane (CH4) and carbon monoxide (CO) measurement. The system achieved different measurement ranges using laser scanning and gas cells, and improved stability and accuracy through gas pre-treatment and temperature compensation algorithm.
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
(2024)
Article
Spectroscopy
Pei-Rong Chen, Li-Kang Chu
Summary: In this study, the hydrates of glyoxal were investigated using infrared absorption spectrometry. The results showed that at low concentrations, glyoxal mainly exists as monomeric dihydrate. These findings provide suitable detection windows for further research on the roles of glyoxal and its hydrates in atmospheric and aerosol chemistry, as well as the relevant reaction kinetics.
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
(2024)
Article
Spectroscopy
Nichole O'Neill, Thamires A. Lima, Fabio Furlan Ferreira, Nicolas J. Alvarez, Reinhard Schweitzer-Stenner
Summary: This study determines the main fibril axis of GHG gel-forming fibrils using various techniques and compares the results with simulated data. The analysis suggests that the hydrophobic xz-surfaces of GHG fibrils could be a good target for the adsorption of hydrophobic drugs.
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
(2024)
Article
Spectroscopy
Mengyuan Liu, Hanchuang Zhu, Yikun Fang, Caiyun Liu, Xinke Li, Xiaohui Zhang, Lixue Ma, Kun Wang, Miaohui Yu, Wenlong Sheng, Baocun Zhu
Summary: ABHS is an efficient fluorescent probe that can accurately and sensitively detect Al3+ with strong resistance to interference. It also demonstrates excellent detection and imaging capabilities in complex real samples.
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
(2024)
Article
Spectroscopy
Ahmed S. El-Shafie, Evana Rahman, Yasser Gadelhak, Rehab Mahmoud, Marwa El-Azary
Summary: The recycling of waste mandarin peels into biochar (MRBC) has been used as a high performance and cost-effective adsorbent for treating polluted wastewater effluents. Batch adsorption studies were conducted to analyze the adsorption competency of MRBC on two dyes, methylene blue (MB) and basic fuchsin (BF), either in individual solutions or binary combinations. The results showed that MRBC was capable of effectively removing a high percentage of both dyes. However, the adsorption capacity decreased when the dyes were combined. The cost estimation of MRBC production and wastewater treatment indicated that both were relatively low.
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
(2024)
Article
Spectroscopy
Anindita Bhatta, Jahnabi Upadhyaya, Dipak Chamlagai, Lincoln Dkhar, Pynskhemborlang T. Phanrang, Mohan Rao Kollipara, Sivaprasad Mitra
Summary: Derivatives of thiazole-pyrazole fused benzo-coumarin compounds were synthesized and their photophysical properties were investigated. The synthesized coumarin compounds showed potential as therapeutic agents for Alzheimer's disease, inhibiting acetylcholinesterase activity. The presence of human serum albumin was found to affect the inhibition activity.
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
(2024)
Article
Spectroscopy
Yongwei Duan, Quancheng Liu, Yiju Zhu, Qi Zhang, Xiaohui Duan, Hu Deng, Liping Shang
Summary: In this study, the phase transition of CL-20 was observed using terahertz spectroscopy, and quantum chemical calculations were employed to analyze the vibrations. The results indicated changes in the vibrations of CL-20 before and after phase transition.
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
(2024)
Article
Spectroscopy
Yuefeng Gao, Sai Xu, Baojiu Chen
Summary: This study synthesized Cs2NaInCl6 nanocrystals co-doped with Sb3+ and Tb3+ ions as probes for copper ions detection in lubricating oil. The introduction of Sb3+ effectively reduced the band gap of the host material and enabled energy transfer pathway for Tb3+ emission. The doped Tb3+ ions resulted in the suppression of emission due to electron transfer. The Cs2NaInCl6: 2.5 %Sb3+, 40 %Tb3+ NCs exhibited superior sensitivity and selectivity for copper ions detection.
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
(2024)
Article
Spectroscopy
Yu Liu, Yue Zhang, Changyao Liu, Ce Wang, Baocai Xu, Li Zhao
Summary: A highly sensitive detection platform for heparin was developed using a cationic fluorescent dye (cresyl violet acetate) as a fluorescence probe. The platform demonstrated high selectivity towards heparin and achieved detection in both HEPES solution and serum.
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
(2024)
Article
Spectroscopy
Lopamudra Roy, Nivedita Pan, Susmita Mondal, Ria Ghosh, Md. Nur Hasan, Neha Bhattacharyya, Soumendra Singh, Kallol Bhattacharyya, Arpita Chattopadhyay, Samir Kumar Pal
Summary: The study focuses on the interaction between reactive oxygen species (ROS) and a spectroscopic probe called Rose Bengal (RB), encapsulated in nanoscopic sodium dodecyl sulphate (SDS) micelles and entrapped in microscopic nylon 66 solid matrix. The research demonstrates efficient interaction between ROS and RB-SDS, and investigates the mechanism of hydroxyl radicals generation. Based on these findings, a prototype device utilizing RB embedded in a nylon thin film for quantification of ROS in extracellular fluids and food materials was developed.
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
(2024)
Article
Spectroscopy
Xiaosong Sun, Qihao Cui, Wenyue Dong, Qian Duan, Teng Fei
Summary: Conjugated porous polymers (CPPs) are promising sensing materials and their application in aqueous media is limited. In this study, we synthesized CPPs with porous structure and prepared nanoparticles, enabling efficient photoluminescence sensing of nitroaromatic explosives in aqueous phase.
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
(2024)
Article
Spectroscopy
Maria Cristina Caggiani, Germana Barone, Paolo Mazzoleni
Summary: Raman spectroscopy is commonly used for studying glassy materials in cultural heritage, but it is more difficult to interpret the spectra and apply the technique with portable instruments. In contrast, diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS) can be used in archaeometric investigations as it is portable and non-invasive. However, there is limited application of this technique to historical glasses. This exploratory work demonstrates the potential of DRIFTS, in combination with portable X-ray Fluorescence (pXRF) and EDS microanalyses, for studying the composition and alteration of glass samples in cultural heritage.
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
(2024)