Article
Chemistry, Physical
Liyang Fang, Fan Liu, David Diercks, Praveen Kumar, Feng Zhao, Dong Ding, Chuancheng Duan
Summary: Solid oxide electrochemical cells (SOECs) are a highly promising clean energy technology that can efficiently convert chemical energy to electricity and produce chemicals from abundant resources. However, the current SOECs suffer from poor performance. In this study, a hybrid oxygen electrode material was designed, which significantly improved the electrocatalytic activities of the oxygen reduction and evolution reactions. The newly developed SOECs achieved exceptional performance for power generation and steam electrolysis, with high stability.
JOURNAL OF MATERIALS CHEMISTRY A
(2023)
Article
Chemistry, Physical
Liyang Fang, Fan Liu, David Diercks, Praveen Kumar, Feng Zhao, Dong Ding, Chuancheng Duan
Summary: Solid oxide electrochemical cells (SOECs) are a promising clean energy technology that can efficiently convert energy stored in fuels. The current SOECs suffer from poor performance, but this study successfully designed a new oxygen electrode material with enhanced electrocatalytic activity, achieving exceptional power generation performance and stability.
JOURNAL OF MATERIALS CHEMISTRY A
(2023)
Article
Chemistry, Physical
Xin Zhou, Chenghao Yang, Caichen Yang, Jin Li, Bo Chi
Summary: In order to improve the electrochemical performance of solid oxide fuel cells (SOFCs), researchers designed an unsintered composite LaCo0.6Ni0.4O3-delta-Er0.4Bi1.6O3 (LCN-ESB) cathode and fabricated a porous cathode layer and cathode/electrolyte interface with good contact. This work provides more possibilities for the practical application of YSZ-based SOFCs, with the LCN-ESB cathode exhibiting competitive oxygen reduction reaction (ORR) activity among intermediate-temperature (IT) SOFC cathodes.
JOURNAL OF MATERIALS CHEMISTRY A
(2023)
Article
Nanoscience & Nanotechnology
Xi Zhang, Gowoon Kim, Qian Yang, Jiake Wei, Bin Feng, Yuichi Ikuhara, Hiromichi Ohta
Summary: Controlling the oxygen content allows manipulation of the electrical conductivity of transition metal oxides. YBa2Cu3O7-δ can be modulated from a superconductor to an insulator by adjusting δ using a solid-state electrochemical redox treatment. Negative voltage increases Tc while positive voltage suppresses the superconducting transition and modulates the electrical conductivity, indicating the possibility of superconducting oxide-based device applications.
ACS APPLIED MATERIALS & INTERFACES
(2021)
Article
Chemistry, Multidisciplinary
Jun Hyuk Kim, Dongyeon Kim, Sejong Ahn, Kyeong Joon Kim, SungHyun Jeon, Dae-Kwang Lim, Jun Kyu Kim, Uisik Kim, Ha-Ni Im, Bonjae Koo, Kang Taek Lee, WooChul Jung
Summary: Solid oxide electrochemical cells (SOCs) are promising energy storage and conversion devices, and the discovery of Ta-doped BaCoO3-δ catalysts with record-breaking electrode performance in both fuel cell and electrolysis operations greatly enhances their efficiency and stability. The introduction of pentavalent Ta ions improves the phase stability, electronic and ionic conductivity, and catalytic activity of the parent oxide. The high-performance SOCs with these versatile electrodes not only contribute to the advancement of energy conversion technology, but also have significant cost reduction potential for related electrochemical devices.
ENERGY & ENVIRONMENTAL SCIENCE
(2023)
Article
Chemistry, Physical
Rae-Hyun Lee, Seong-Jun Jo, Jong-Kyu Lee, Jung-Rag Yoon, Hyun-Kyung Kim, Seung-Hwan Lee
Summary: Solid-state electrolytes show promise as a replacement for liquid electrolytes in lithium ion batteries, despite their lower ionic conductivity. Among these, garnet-type LiLaZrO is a favorable material for all-solid-state lithium batteries due to its superior lithium ion kinetics, non-flammability, and excellent electrochemical/thermal stability. By adjusting the sintering time, the grain size can be controlled, affecting the electrochemical and mechanical properties. In this study, Li6.1Ga0.3La3Zr2O12 (LGLZO) sintered at 1250 degrees C for 10 hours exhibited higher relative density, hardness, ionic conductivity, and critical current density compared to LGLZO sintered for 20 hours. Thus, regulating sintering time is a simple and effective approach for achieving high performance all-solid-state lithium ion batteries.
ACS APPLIED ENERGY MATERIALS
(2023)
Article
Chemistry, Multidisciplinary
Hirotada Gamo, Kazuhiro Hikima, Atsunori Matsuda
Summary: This study reports a cathode design for all-solid-state lithium-sulfur batteries (ASLSBs) that enhances the redox reaction kinetics of the cathode, suppresses interfacial degradation, and improves the practical performance of the batteries. The design uses Li2S and transition-metal sulfides in the composite cathode and shows promising results in terms of discharge capacity and long-term stability.
Article
Materials Science, Multidisciplinary
In -Ho Kim, Dae-Kwang Lim, Yeon Namgung, Hohan Bae, Jun-Young Park, Sun-Ju Song
Summary: In this study, the electrochemical and transport properties of a perovskite-type proton conductor BZCYYb5311 were evaluated. The material showed high proton conductivity and exceptional chemical stability. It exhibited a proton conductivity of 98% compared to ionic conductivity at 600°C. The maximum power density in fuel cell mode and current density in electrolysis mode were calculated, indicating the potential of BZCYYb5311 as a fuel cell material.
Article
Chemistry, Inorganic & Nuclear
Anbazhagan Murugan, Vadivel Siva, Abdul Samad Shameem, Sultan Asath Bahadur
Summary: Transition metal chalcogenides are being extensively investigated as electrode materials for energy storage systems due to their high conductivity and synergistic effect during electrochemical reactions. Nanocrystalline Cu2CoSnS4 (CCTS) thin films were successfully deposited on conductive and nonconductive substrates using the cost-effective SILAR method. The properties of the deposited CCTS thin film were examined using various characterization techniques, confirming its high purity and kesterite structure. Electrochemical studies showed that CCTS thin film electrode is a promising candidate for high performance supercapacitors.
INORGANIC CHEMISTRY COMMUNICATIONS
(2023)
Article
Electrochemistry
Aman Bhardwaj, Hohan Bae, Lakshya Mathur, Sanjay Mathur, Sun-Ju Song
Summary: In order to achieve a sustainable energy future, maximizing energy consumption from renewable sources and drastically reducing greenhouse gas emissions are essential. This study demonstrates an efficient electrochemical sensor for selective nitric oxide (NO) detection, with high sensitivity, fast response time, and detection abilities as low as 200 ppb. Rare-Earth cations play a role in influencing the sensing mechanism, contributing to improved sensing behavior. Careful consideration of the mixed-potential model and durability assessment supports the applicability of the sensor for on-board NOX monitoring systems.
JOURNAL OF THE ELECTROCHEMICAL SOCIETY
(2022)
Article
Materials Science, Ceramics
Hongtao Wang, Shouyue Wang, Yanting Huang, Haodong Yang, Zhen Zhang
Summary: This study investigates the influence of sintering additive and calcining temperature on the structures, morphologies, and conductivities of Ho3+ and Sm3+ co-doped CeO2 and NiO doped CeO2 samples. The addition of NiO and higher sintering temperature significantly increases the conductivities of the ceramic sheets. A fuel cell with NiO-HSDC and 1450-HSDC-2NiO as the membrane exhibits good performance at high temperatures, showing high current densities and power densities. The stability of the fuel cell is relatively good within the testing range.
CERAMICS INTERNATIONAL
(2023)
Article
Electrochemistry
Mei Wang, Kamil Maciej Nowicki, John Thomas Sirr Irvine
Summary: A tubular solid oxide electrochemical oxygen pump was developed, featuring YSZ electrolyte and LSCF/CGO symmetrical air electrodes. The pump exhibited excellent stability, low power consumption, and high oxygen production, making it a promising solution for various applications.
JOURNAL OF THE ELECTROCHEMICAL SOCIETY
(2022)
Article
Chemistry, Multidisciplinary
Sholpan G. Giniyatova, Artem L. Kozlovskiy, Rafael I. Shakirzyanov, Natalia O. Volodina, Dmitriy I. Shlimas, Daryn B. Borgekov
Summary: This study investigated the structural, electrical, and mechanical properties and phase composition of high-content cubic zirconium oxide ceramics stabilized with Ca. The synthesized ceramics demonstrated suitable mechanical and electrical properties and phase composition for use as a matrix for dispersed nuclear fuels.
APPLIED SCIENCES-BASEL
(2023)
Article
Energy & Fuels
Seo Ju Kim, Mingi Choi, Taeeun Mun, Deok Yoon Woo, Wonyoung Lee
Summary: This study reports the feasibility and opportunity of nanostructured and defect-engineered electrodes for solid oxide fuel cells operating at intermediate temperatures (500-700 degrees C). The nanostructured electrode with the lowest sintering temperature of 800 degrees C exhibits significantly higher specific surface area and oxygen vacancy concentration compared to the electrode sintered at 1200 degrees C. The cell with a sintering temperature of 800 degrees C demonstrates outstanding performance and stability under different temperatures and current densities.
INTERNATIONAL JOURNAL OF ENERGY RESEARCH
(2023)
Article
Nanoscience & Nanotechnology
Kaihui Nie, Siyuan Wu, Junyang Wang, Xiaorui Sun, Zhao Yan, Jiliang Qiu, Qi Yang, Ruijuan Xiao, Xiqian Yu, Hong Li, Liquan Chen, Xuejie Huang
Summary: This study investigated the stability and reaction mechanisms of several commonly used organic solvents with garnets, revealing that solvent acidity determines the reaction strength, and solvents with hydroxyl groups may lead to violent reaction. Ether compounds and saturated aliphatic hydrocarbons exhibit high stability against garnets.
ACS APPLIED MATERIALS & INTERFACES
(2021)
Article
Materials Science, Multidisciplinary
Leandro da Conceicao, Sabine Lay, Florence Robaut, Gilles Renou, E. N. S. Muccillo, Elisabeth Djurado
FUNCTIONAL MATERIALS LETTERS
(2017)
Article
Materials Science, Multidisciplinary
S. Lanfredi, F. Storti, L. P. M. Simoes, E. Djurado, M. A. L. Nobre
Article
Chemistry, Physical
R. K. Sharma, E. Djurado
JOURNAL OF MATERIALS CHEMISTRY A
(2017)
Article
Chemistry, Physical
Florent Tonus, Mona Bahout, Vincent Dorcet, Rakesh K. Sharma, Elisabeth Djurado, Serge Paofai, Ronald I. Smith, Stephen J. Skinner
JOURNAL OF MATERIALS CHEMISTRY A
(2017)
Article
Chemistry, Physical
Rakesh K. Sharma, Seng-Kian Cheah, Monica Burriel, Laurent Dessemond, Jean-Marc Bassat, Elisabeth Djurado
JOURNAL OF MATERIALS CHEMISTRY A
(2017)
Editorial Material
Chemistry, Physical
Aude Bailly, Elisabeth Djurado, Robert Felici, Anouk Galtayries, Olivier Renault
APPLIED SURFACE SCIENCE
(2018)
Article
Chemistry, Physical
R. K. Sharma, E. Djurado
JOURNAL OF MATERIALS CHEMISTRY A
(2018)
Article
Chemistry, Physical
Rakesh K. Sharma, Veronica Mueller, Marian Chatenet, Elisabeth Djurado
Article
Electrochemistry
V Tezyk, C. Rossignol, N. Sergent, E. Djurado, J. Laurencin, E. Siebert
ELECTROCHIMICA ACTA
(2019)
Article
Chemistry, Physical
Rakesh K. Sharma, Nur I. Khamidy, Laetitia Rapenne, Frederic Chariot, Hamza Moussaoui, Jerome Laurencin, Elisabeth Djurado
JOURNAL OF POWER SOURCES
(2019)
Article
Chemistry, Physical
Nur Istiqomah Khamidy, Jerome Laurencin, Dario Ferreira Sanchez, Federico Monaco, Frederic Chariot, Elisabeth Djurado
JOURNAL OF POWER SOURCES
(2020)
Article
Electrochemistry
Federico Monaco, Elisa Effori, Maxime Hubert, Elisabeth Siebert, Gregory Geneste, Bertrand Morel, Elisabeth Djurado, Dario Montinaro, Jerome Laurencin
Summary: The electrochemical reactions of hydrogen oxidation and steam reduction on a porous cermet electrode made of Ni and 3YSZ were investigated, showing different response mechanisms under anodic and cathodic current. A continuous dynamic model was developed to interpret the experimental results based on charge transfer mechanisms. The electrode response is controlled by charge transfer at triple phase boundary lengths, oxygen vacancies migration in the 3YSZ network, and a purely chemical surface process depending on polarization.
ELECTROCHIMICA ACTA
(2021)
Article
Chemistry, Physical
Ozden Celikbilek, Cam-Anh Thieu, Fabio Agnese, Eleonora Cali, Christian Lenser, Norbert H. Menzler, Ji-Won Son, Stephen J. Skinner, Elisabeth Djurado
JOURNAL OF MATERIALS CHEMISTRY A
(2019)
Proceedings Paper
Electrochemistry
Ozden Celikbilek, Laurent Dessemond, Elisabeth Djurado
SOLID OXIDE FUEL CELLS 15 (SOFC-XV)
(2017)
Article
Electrochemistry
Ozden Celikbilek, Elisabeth Siebert, David Jauffres, Christophe L. Martin, Elisabeth Djurado
ELECTROCHIMICA ACTA
(2017)