Journal
SMALL
Volume 8, Issue 9, Pages 1423-1428Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/smll.201101967
Keywords
reversible single-molecule switching; STM; dipole molecules; bistable states; molecular electronics
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Funding
- Singapore ARF [R-143-000-440-112]
- NUS YIA [R143-000-452-101]
- G-COE at Chiba University (MEXT) [G-03]
- JSPS
- Grants-in-Aid for Scientific Research [10F00367, 20245039, 23360005] Funding Source: KAKEN
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Making electronic devices using a single molecule has been the ultimate goal of molecular electronics. For binary data storage in particular, the challenge has been the ability to switch a single molecule in between bistable states in a simple and repeatable manner. The reversible switching of single molecules of chloroaluminum phthalocyanine (ClAlPc) dipolar molecules within a close-packed monolayer is demonstrated. By pulsing an scanning tunneling microscopy tip, readwrite operations of single-molecular binary bits at similar to 40 Tb/cm2 (similar to 250 Tb/in2) are demonstrated.
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