4.7 Article

A proto-type sensor for volatile organic compounds based on magnesium porphyrin molecular films

Journal

SENSORS AND ACTUATORS B-CHEMICAL
Volume 202, Issue -, Pages 854-860

Publisher

ELSEVIER SCIENCE SA
DOI: 10.1016/j.snb.2014.05.082

Keywords

Optical gas sensor; Portable device; Metallo-porphyrin; Alcohol detection

Funding

  1. CONACYT (Mexico) [211999]

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An inexpensive portable sensor which can detect volatile organic compounds (VOCs) has been developed. The system consists of a commercial blue LED which emits light that is detected by a phototransistor. The phototransistor is coated with a few thin layers of a gas sensing porphyrin. Porphyrins have a highly conjugated molecular structure that displays strong absorption in the visible region of the spectrum. The porphyrin layer undergoes a subtle shift in its absorbance characteristics upon exposure to specific volatile organic compounds. This varies the light intensity received by the phototransistor and results in a change in the voltage across the phototransistor when the analyte is detected. This sensor design can be applied to any available porphyrin-analyte pairing to develop a wide range of VOC detectors. Presented here is an alcohol sensor based upon the interaction of various alcohols with a magnesium porphyrin. (C) 2014 Elsevier B.V. All rights reserved.

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