Journal
RSC ADVANCES
Volume 5, Issue 40, Pages 31664-31669Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4ra16675b
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Funding
- National Natural Science Foundation of China [51321062, 51273197, 21134002]
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A novel conjugated microporous polymer was solvothermally synthesized using an aluminum porphyrin as a main building block, which had a high Brunauer-Emmett-Teller specific surface area up to 839 m(2) g(-1) and a pore volume of 2.14 cm(3) g(-1). The polymer displayed excellent capacity to capture carbon dioxide (4.3 wt%) at 273 K and 1 bar, and good catalytic activity for cyclic carbonate synthesis with TOF up to 364 h(-1).
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