4.6 Article

Structural, transport, magnetic and magnetoelectric properties of CaMn1-xFexO3-δ (0.0 ≤ x ≤ 0.4)

Journal

RSC ADVANCES
Volume 5, Issue 50, Pages 39938-39945

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c5ra03565a

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Funding

  1. Department of Science and Technology, India

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The structural, magnetic, transport and magnetoelectric properties of parent and Fe doped CaMn1-xFexO3-delta (0.0 <= x <= 0.4) manganites are investigated using synchrotron X-ray, Raman, SQUID and nova control impedance analyzer. The Fe doped composition x = 0.3 shows a strong Maxwell-Wagner effect, and quite high positive magnetocapacitance (MC) of similar to 8.45% at room temperature and at low magnetic field 7.8 kG has been observed. Rietveld refinement of synchrotron X-ray diffraction patterns suggests (i) a structural transformation from orthorhombic to cubic crystal system and (ii) an increase in lattice parameters with the substitution of Fe at the Mn site. Sintering at 1300 degrees C stabilizes the doping of higher ionic radii Fe+3 (0.645 angstrom)/Fe+4 (0.585 angstrom) atoms at the Mn+4 (0.53 angstrom) site in CaMn1-xFexO3-delta. The Magnetization data show a transformation of the G type of antiferromagnetic arrangement of Mn+4 electrons spins in CaMnO3 into a paramagnetic spin type arrangement with Fe substitution. The AC conductivity of the Fe doped compositions decreases more than two orders of magnitude in comparison to CaMnO3-delta.

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