4.6 Article

A dual-mode luminescent probe composed of co-assembled down-conversion CdTe and up-conversion NaYF4:Yb, Tm(Er) nanoparticles

Journal

RSC ADVANCES
Volume 5, Issue 59, Pages 48024-48030

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c5ra07964k

Keywords

-

Funding

  1. NSFC [51425303, 81301650, 21374042, 21174051, 21221063]
  2. 973 Program of China [2014CB643503]
  3. Natural Science Foundation of Jilin Province [20140101048JC]
  4. Special Project from MOST of China
  5. Fundamental Research Funds for the Central Universities

Ask authors/readers for more resources

Multiplex luminescent probes with good water-dispersibility are basic materials in current biological research as labels and sensors. In this work, we demonstrate a facile approach to fabricate water-dispersible dual-mode luminescent probes by co-assembling down-conversion CdTe nanoparticles (NPs) and up-conversion NaYF4:Yb, Tm(Er) NPs. 3-Mercaptopropionic acid (MPA)-capped CdTe NPs are water soluble, while oleic acid (OA)-capped NaYF4: Yb, Tm(Er) NPs are dispersed in chloroform. There also exists an excess of Cd-MPA complex in the CdTe aqueous solution. After mixing CdTe and NaYF4:Yb, Tm(Er), the MPA on CdTe NPs and Cd-MPA complexes is capable of partially replacing the OA on NaYF4:Yb, Tm(Er) NPs, thus transferring NaYF4:Yb, Tm(Er) NPs to water and forming CdTeNaYF4:Yb, Tm(Er) hybrid NPs. The hybrid NPs combine the down-conversion emission of CdTe and the up-conversion emission of NaYF4:Yb, Tm(Er), which can be excited both by 400 and 980 nm irradiation and exhibit dual-mode emission. Both Forster resonance energy transfer from NaYF4:Yb, Tm(Er) to CdTe and photon re-absorption are observed as the hybrid NPs are excited by 980 nm irradiation.

Authors

I am an author on this paper
Click your name to claim this paper and add it to your profile.

Reviews

Primary Rating

4.6
Not enough ratings

Secondary Ratings

Novelty
-
Significance
-
Scientific rigor
-
Rate this paper

Recommended

Article Chemistry, Multidisciplinary

Contribution of Metal Defects in the Assembly Induced Emission of Cu Nanoclusters

Zhennan Wu, Huiwen Liu, Tingting Li, Jiale Liu, Jun Yin, Omar F. Mohammed, Osman M. Bakr, Yi Liu, Bai Yang, Hao Zhang

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2017)

Article Chemistry, Multidisciplinary

Analogous self-assembly and crystallization: a chloride-directed orientated self-assembly of Cu nanoclusters and subsequent growth of Cu2-xS nanocrystals

Jiale Liu, Ye Tian, Zhennan Wu, Lin Ai, Yi Liu, Jianli Cui, Weili Yu, Hao Zhang, Bai Yang

NANOSCALE (2017)

Article Chemistry, Physical

Water-Induced Dimensionality Reduction in Metal-Halide Perovskites

Bekir Turedi, Kwang Jae Lee, Ibrahim Dursun, Badriah Alamer, Zhennan Wu, Erkki Alarousu, Omar F. Mohammed, Namchul Cho, Osman M. Bakr

JOURNAL OF PHYSICAL CHEMISTRY C (2018)

Article Chemistry, Multidisciplinary

Aurophilic Interactions in the Self-Assembly of Gold Nanoclusters into Nanoribbons with Enhanced Luminescence

Zhennan Wu, Yonghua Du, Jiale Liu, Qiaofeng Yao, Tiankai Chen, Yitao Cao, Hao Zhang, Jianping Xie

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2019)

Article Chemistry, Multidisciplinary

Unraveling the Impact of Gold(I)-Thiolate Motifs on the Aggregation-Induced Emission of Gold Nanoclusters

Zhennan Wu, Qiaofeng Yao, Osburg Jin Huang Chai, Nan Ding, Wen Xu, Shuangquan Zang, Jianping Xie

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

Article Chemistry, Physical

Ultrastable Hydrophilic Gold Nanoclusters Protected by Sulfonic Thiolate Ligands

Bihan Zhang, Zhennan Wu, Yitao Cao, Qiaofeng Yao, Jianping Xie

Summary: Increasing surface charge effectively improves stability of hydrophilic gold nanoclusters in solution, with sulfonic thiolate ligands showing promising results. This strategy can enhance stability under various conditions, making it suitable for biomedical and catalytic applications.

JOURNAL OF PHYSICAL CHEMISTRY C (2021)

Article Chemistry, Multidisciplinary

Self-Assembly of Au Nanoclusters into Helical Ribbons by Manipulating the Flexibility of Capping Ligands

Jiale Liu, Ye Tian, Lin Ai, Zhennan Wu, Dong Yao, Yi Liu, Bai Yang, Hao Zhang

LANGMUIR (2020)

Review Chemistry, Multidisciplinary

Correlations between the fundamentals and applications of ultrasmall metal nanoclusters: Recent advances in catalysis and biomedical applications

Zhihe Liu, Zhennan Wu, Qiaofeng Yao, Yitao Cao, Osburg Jin Huang Chai, Jianping Xie

Summary: This review article focuses on the correlation between the structures, physical and chemical properties of metal nanoclusters and their applications, highlighting the basic principles of structure- and property-oriented applications of metal nanoclusters. It provides guidance for the design of metal nanoclusters with desirable properties to meet application needs.

NANO TODAY (2021)

Article Chemistry, Multidisciplinary

Synergistic Regulation Effect of Nitrate and Calcium Ions for Highly Luminescent and Robust α-CsPbI3 Perovskite

Xiufeng Wu, He Shao, Yuan Zhong, Lifang Li, Wenda Chen, Biao Dong, Lin Xu, Wen Xu, Donglei Zhou, Zhennan Wu, Hongwei Song, Xue Bai

Summary: By engineering the lattice symmetry of perovskite and combining NO3- ion passivation and Ca2+ ion doping, highly luminescent and robust alpha-CsPbI3 nanocrystals with excellent stability, photoluminescence quantum yield, and conductivity are obtained. These nanocrystals are suitable for use in light-emitting diode devices.

SMALL (2022)

Review Chemistry, Multidisciplinary

Broadband Emission Origin in Metal Halide Perovskites: Are Self-Trapped Excitons or Ions?

Feng Jiang, Zhennan Wu, Min Lu, Yanbo Gao, Xin Li, Xue Bai, Yuan Ji, Yu Zhang

Summary: The appearance of metal halide perovskites allows for efficient and broadband emission in single-component materials. The characteristics of self-trapped excitons and ns(2) ions play important roles in achieving broadband emission.

ADVANCED MATERIALS (2023)

Review Materials Science, Multidisciplinary

Circularly polarized luminescence of lanthanide complexes: From isolated individuals, discrete oligomers, to hierarchical assemblies

Yuan Zhong, Zhennan Wu, Yu Zhang, Bin Dong, Xue Bai

Summary: This review summarizes recent advances in the chiroptical properties of lanthanide complexes, covering multiple scales from isolated mononuclear individuals, discrete polynuclear oligomers, to infinite hierarchical assemblies. The basic concept and important parameters for the assessment of CPL activity are introduced. The discussion includes mononuclear lanthanide complexes coordinated with different types of antennas, as well as unique chirality transfer and induction in achiral lanthanide complexes. The chiroptical properties in discrete polynuclear lanthanide oligomers and infinite hierarchical lanthanide assemblies are systematically discussed, along with the state-of-the-art applications of CPL-active lanthanide complexes.

INFOMAT (2023)

Review Chemistry, Multidisciplinary

Luminescent metal nanoclusters: Biosensing strategies and bioimaging applications

Yan Xiao, Zhennan Wu, Qiaofeng Yao, Jianping Xie

Summary: Metal nanoclusters (MNCs) are small metal-organic aggregates with molecule-like properties, particularly strong and bright luminescence, making them useful in biosensing and bioimaging applications. Aggregation-induced emission is a feasible mechanism for controlling the luminescence of MNCs. Despite the lack of a systematic summary in current literature, research on the design and practicality of luminescent MNCs for biomedical applications is advancing.

AGGREGATE (2021)

Review Chemistry, Multidisciplinary

Molecular reactivity of thiolate-protected noble metal nanoclusters: synthesis, self-assembly, and applications

Qiaofeng Yao, Zhennan Wu, Zhihe Liu, Yingzheng Lin, Xun Yuan, Jianping Xie

Summary: "Thiolate-protected noble metal nanoclusters exhibit molecule-like properties, behaving as molecular entities and displaying structurally sensitive molecular reactivity to ions, molecules, and other nanoclusters. Their molecular interactions and reactions are crucial for applications in various fields, yet there is a lack of systematic summary in the current literature. Advances in synthesis and characterization techniques allow for the production of noble metal nanoclusters with molecular purity and precise atomic resolution, revealing active sites for molecular interactions and reactions. Understanding and utilizing these interactions and reactions in synthesis, self-assembly, and applications can increase the acceptance of metal nanoclusters in various fields."

CHEMICAL SCIENCE (2021)

Article Materials Science, Multidisciplinary

Directed Self-Assembly of Ultrasmall Metal Nanoclusters

Zhennan Wu, Qiaofeng Yao, Shuangquan Zang, Jianping Xie

ACS MATERIALS LETTERS (2019)

Article Chemistry, Multidisciplinary

CsPbxMn1-xCl3 Perovskite Quantum Dots with High Mn Substitution Ratio

Huiwen Liu, Zhennan Wu, Jieren Shao, Dong Yao, Hang Gao, Yi Liu, Weili Yu, Hao Zhang, Bai Yang

ACS NANO (2017)

No Data Available