4.6 Article

A dumbbell-like supramolecular triblock copolymer and its self-assembly of light-responsive vesicles

Journal

RSC ADVANCES
Volume 5, Issue 59, Pages 47762-47765

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c5ra08661b

Keywords

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Funding

  1. National Basic Research Program [2013CB834506]
  2. China National Funds for Distinguished Young Scholar [21225420]
  3. National Natural Science Foundation of China [2144062, 91127047]
  4. Shanghai Education Development Foundation [13SG14]
  5. Shanghai Municipal Education commission

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This work reports the synthesis, self-assembly and light-responsive disassembly of a novel dumbbell-like supramolecular triblock copolymer (DSTC). The DSTC has an amphiphilic hyperbranched-linear-hyperbranched structure and can self-assemble into monolayer vesicles in water. In addition, the vesicles could disassemble into unimers under UV light due to the trans-to-cis isomerization of the AZO groups.

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