4.6 Article

Iodine-catalyzed C-H/S-H oxidative coupling: from 1,3-diketones and thiophenols to β-dicarbonyl thioethers

Journal

RSC ADVANCES
Volume 5, Issue 52, Pages 41493-41496

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c5ra04906g

Keywords

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Funding

  1. 973 Program [2012CB725302, 2011CB808600]
  2. National Natural Science Foundation of China [21390400, 21025206, 21272180, 21302148]
  3. Research Fund for the Doctoral Program of Higher Education of China [20120141130002]
  4. Program for Changjiang Scholars and Innovative Research Team in University [IRT1030]
  5. Ministry of Science and Technology of China [2012YQ120060]

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A novel method on iodine-catalyzed oxidative coupling between 1,3-diketones and thiophenols to form beta-dicarbonyl thioethers was developed. The C-S bond was supposed to be formed via a radical substitution pathway instead of the usual nucleophilic substitution one.

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