Journal
ORGANOMETALLICS
Volume 28, Issue 11, Pages 3233-3238Publisher
AMER CHEMICAL SOC
DOI: 10.1021/om900009h
Keywords
-
Categories
Funding
- School of Physical and Mathematical Sciences
- Nanyang Technological University
Ask authors/readers for more resources
Neutral and cationic Pd(II) and Ni(II) OCO-type pincer complexes have been synthesized from the metalation of 1,3-dinitrones via C-H or C-Br bond activation using Pd(0), Pd(II), and Ni(0) starting materials. In each complex, the two six-membered metallacycles are non-coplanar and atropisomerization proceeds with a low barrier. Palladium dinitrone complexes have been shown as active catalysts for Heck couplings and the related Ni complex for Kumada reactions with turnover numbers up to 950 000.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available