4.7 Article

Fluorescent turn-on detecting CN- by nucleophilic addition induced Schiff-base hydrolysis

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.saa.2015.01.042

Keywords

Chemosensor; Cyanide; Fluorescent turn-on; High sensitivity; Specific selectivity

Categories

Funding

  1. National Natural Science Foundation of China (NSFC) [21064006, 21161018, 21262032]
  2. Natural Science Foundation of Gansu Province [1010RIZA018]
  3. Program for Changjiang Scholars and innovative Research Team in University of Ministry of Education of China [IRT1177]

Ask authors/readers for more resources

A new chemosensor Sz based on Schiff-base group as recognition site and naphthalene as the fluorescence signal group was designed and synthesised. It could fluorescent turn-on detect cyanide (CN-) via a novel mechanism of nucleophilic addition induced Schiff-base hydrolysis. Adding the CN- into the solution of Sz could induce Sz to emit blue fluorescence at 435 nm instantly. Moreover, Sz could also colorimetric detect CN-. Upon the addition of CN-, the Sz showed dramatic color change from yellow to colorless. These sensing procedures could not be interfered by other coexistent competitive anions such as F-, AcO-, H2PO4- and SCN-. In addition, Sz showed high sensitivity for CN-, the detection limits is 3.42 x 10(-8) M of CN-, which is far lower than the WHO guideline of CN- in drinking water (less than 1.9 x 10(-6) M). The CN- test strips based on Sz could act as a convenient CN- test kits. (C) 2015 Elsevier B.V. All rights reserved.

Authors

I am an author on this paper
Click your name to claim this paper and add it to your profile.

Reviews

Primary Rating

4.7
Not enough ratings

Secondary Ratings

Novelty
-
Significance
-
Scientific rigor
-
Rate this paper

Recommended

Article Chemistry, Multidisciplinary

Tuning host-guest binding model by different intramolecular alkyl chain lengths in tripodal hosts: An evidence on structure control supramolecular interactions

Zheng-Hua Zhang, You-Ming Zhang, Wen-Juan Qu, Bingbing Shi, Hong Yao, Tai-Bao Wei

Summary: In this paper, a series of tripodal nitrogen mustard derivatives (TMs) were developed, and the host-guest binding model was successfully tuned by rationally designing the intramolecular alkyl chain lengths of the host. This transformation from pi-pi to multiple hydrogen bonds enhanced the host-guest binding force and recognition efficiency.

CHINESE CHEMICAL LETTERS (2023)

Article Chemistry, Applied

A selective and stable vapochromic system constructed by pillar[5] arene-based host-guest interactions

Bingbing Shi, Weichun Li, Peng Qin, Xing-Xing Zhao, Xiao-Ni Qi, Yongping Chai, Hao-Hang Yang, Wen-Juan Qu, Hong Yao, You-Ming Zhang, Tai-Bo Wei, Qi Lin

Summary: This study presented a highly selective and stable vapochromic system constructed by pillar[5]arene-based host-guest interactions, showing specific selective responsiveness to chloroform vapor. The material can maintain its color stably in air for at least two months, and thin film and LED responsive to CHCl3 vapor were successfully prepared as well.

DYES AND PIGMENTS (2022)

Review Chemistry, Organic

Synthetic strategies of phenazine derivatives: A review

Yu-Xin Che, Xiao-Ni Qi, Wen-Juan Qu, Bing-Bing Shi, Qi Lin, Hong Yao, You-Ming Zhang, Tai-Bao Wei

Summary: The review covers sustainable and facile synthetic strategies for phenazine derivatives, discussing the approach of preparation and the advantages of each strategy.

JOURNAL OF HETEROCYCLIC CHEMISTRY (2022)

Article Materials Science, Multidisciplinary

A Discrete Platinum(II) Metallacycle Harvesting Triplet Excitons for Solution-Processed Deep-Red Organic Light-Emitting Diodes

Hao Xing, Ying Yu, Junkai Liu, Peng Qin, Jacky Wing Yip Lam, Bingbing Shi, Guohua Xie, Ben Zhong Tang

Summary: Platinum(II) coordination-driven architectures have unique features in fabricating functional supramolecular materials with various light-emitting metallacycles and metallacages. The platinum(II) center not only builds metal-ligand bonds, but also benefits the ultimate luminescence due to its unique photophysical traits. This study reveals the function of platinum(II) metallacycles in light-emitting devices, which is expected to apply to other coordination-driven architectures with versatile properties.

ADVANCED OPTICAL MATERIALS (2022)

Article Chemistry, Multidisciplinary

A supramolecular polymer network constructed by pillar[5]arene-based host-guest interactions and its application in nitro explosive detection

Peng Qin, Hao-Hang Yang, Xing-Xing Zhao, Wen-Juan Qu, Hong Yao, Tai-Bao Wei, Qi Lin, Bingbing Shi, You-Ming Zhang

Summary: A cross-linked supramolecular polymer network was successfully constructed for the efficient detection of nitro-explosives. This research provided a novel strategy for rapid detection of explosives.

JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY (2022)

Review Biochemistry & Molecular Biology

Recent advances in DNA-encoded dynamic libraries

Bingbing Shi, Yu Zhou, Xiaoyu Li

Summary: The DNA-encoded chemical library (DEL) is a powerful technology platform in drug discovery that has been widely adopted in the pharmaceutical industry. Recent innovations, such as the DNA-encoded dynamic library (DEDL), have expanded the application scope of DELs and allowed for the discovery of unique ligands in complex biological systems.

RSC CHEMICAL BIOLOGY (2022)

Article Chemistry, Multidisciplinary

Fabricating a novel supramolecular light-activated platform based on internal-driven forces induced by the UV-light

Xiaoni Qi, Weichun Li, Bingbing Shi, Youming Zhang, Hong Yao, Qi Lin, Taibao Wei

Summary: By designing a light-activated platform based on internal-driven forces of a macrocyclic host, it is possible to achieve quenching and regeneration of fluorescent molecules, showing great potential for practical applications.

CHINESE CHEMICAL LETTERS (2022)

Article Chemistry, Inorganic & Nuclear

An Organoplatinum(II) Metallacycle-Based Supramolecular Amphiphile and Its Application in Enzyme-Responsive Controlled Release

Bingbing Shi, Peng Qin, Yongping Chai, Wen-Juan Qu, Liqing Shangguan, Qi Lin, You-Ming Zhang, Yan Sun, Feihe Huang, Peter J. Stang

Summary: Enzyme-responsive nanomaterials have great potential for bioanalytical and biomedical applications, but the lack of compatible operation platforms limits their functionality. This study presents the design and synthesis of an organoplatinum(II) metallacycle that serves as a platform for enzyme-responsive supramolecular materials. The self-assembled nanosheets can transform into vesicles in the presence of beta-cyclodextrin, and demonstrate rare alpha-amylase responsiveness.

INORGANIC CHEMISTRY (2022)

Article Chemistry, Multidisciplinary

Detection of L-Aspartic Acid and L-Glutamic Acid in Water Using a Fluorescent Nanoparticle Constructed by Pillar[5]arene-Based Molecular Recognition

Bingbing Shi, Xing-Xing Zhao, Yongping Chai, Peng Qin, Wen-Juan Qu, Qi Lin, You-Ming Zhang

Summary: The research achieved highly selective detection of L-Aspartic acid and L-Glutamic acid in water by using fluorescent nanoparticles constructed with water-soluble pillar[5]arene, providing an efficient way for sensitive detection.

CHEMISTRYSELECT (2022)

Article Chemistry, Multidisciplinary

A Pd2L4 Metallacage-Cored Supramolecular Amphiphile and Its Application in Dual-Responsive Controllable Release†

Yongping Chai, Peng Qin, Xupeng Li, Tai-Bao Wei, Qi Lin, You-Ming Zhang, Hong Yao, Wen-Juan Qu, Bingbing Shi

Summary: In this study, a Pd2L4 metallacage with four pyrene units was successfully synthesized through coordination-driven self-assembly, and a supramolecular amphiphile was constructed based on host-guest molecular recognition. The supramolecular vesicles showed dual-responsive behavior and achieved rapid and effective drug release by adjusting the pH or adding a certain amount of alpha-amylase.

CHINESE JOURNAL OF CHEMISTRY (2022)

Article Chemistry, Applied

Selective fluorescent detection toluene in water by a novel and simple tetra-hydrazone-biphenol-based chemosensor

Khalid Mohammed Adam, Ting-Ting Huang, Qing-Yu Yang, Wen-Li Guan, Jian-Peng Hu, Yu Jia, Wen-Juan Qu, Bingbing Shi, Tai-Bao Wei, Hong Yao, You-Ming Zhang, Qi Lin

Summary: In this study, a novel supramolecular fluorescent sensor FB was designed by employing a synergistic effect, which can selectively and sensitively detect toluene. The detection process is based on the collaboration of the tetra hydrazine and the hydroxyl groups, and the sensor has a low detection limit, making it a potential probe for environmental detection of toluene.

DYES AND PIGMENTS (2022)

Article Chemistry, Multidisciplinary

Detection of Lead(II) in Living Cells by Inducing the Transformation of a Supramolecular System into Quantum Dots

Ying-Jie Li, Ting-Ting Huang, Juan Liu, Yong-Qiang Xie, Bingbing Shi, You-Ming Zhang, Hong Yao, Tai-Bao Wei, Qi Lin

Summary: This study presents a new approach for in situ detection of Pb2+ by inducing supramolecular systems to form fluorescent quantum dots (QDs). The research demonstrates that Pb2+ can induce the transformation of nanoparticles into PbS QDs, enabling efficient sensing of Pb2+.

ACS SUSTAINABLE CHEMISTRY & ENGINEERING (2022)

Article Chemistry, Multidisciplinary

Metal-free nucleophilic 7,8-dearomatization of quinolines: Spiroannulation of aminoquinoline protected amino acids

Zhiguo Zhang, Xiyang Cao, Xiaoqing Song, Gang Wang, Bingbing Shi, Xiang Li, Nana Ma, Lantao Liu, Guisheng Zhang

Summary: Atom- and step-economy in IBX-assisted diversity-oriented synthesis is achieved with a versatile AQ auxiliary alpha-amino acid analogs, offering rapid access to polycyclic spiro-quinolines featuring a quaternary stereocenter in 20%-91% yields under mild conditions via 7,8-dearomatization of quinolines. The highlight of this intramolecular oxidation spiroannulation tandem reaction is the absence of a preinstalled activation group. These traditionally difficult-to-access N-heterospirocycles may provide a potentially interesting scaffold for synthetic and medicinal chemistry.

CHINESE CHEMICAL LETTERS (2023)

Article Chemistry, Multidisciplinary

Structure-property relationship on aggregation-induced emission properties of simple azine-based AIEgens and its application in metal ions detection

Xiao-Mei Sun, Juan Liu, Zhao-Hui Li, Yong-Peng Fu, Ting-Ting Huang, Zhong-Di Tang, Bingbing Shi, Hong Yao, Tai-Bao Wei, Qi Lin

Summary: In the past twenty years, aggregation-induced emission (AIE) has gained widespread interest due to its promising applications. The development of novel and easily synthesized AIE luminogens (AIEgens) is a fascinating research topic. This study aims to investigate the structure-property relationship of AIEgens by using a series of azine derivatives (ADs) as models.

CHINESE CHEMICAL LETTERS (2023)

Article Chemistry, Organic

Fluorinated leaning pillar[6]arene: synthesis, structure and selective iodide anion binding by anion-π interactions

Weichun Li, Peng Qin, Xing-Xing Zhao, Wen-Juan Qu, Qi Lin, Hong Yao, Tai-Bao Wei, You-Ming Zhang, Yuezhou Liu, Bingbing Shi

Summary: This study successfully designed and synthesized a novel electron-deficient fluorinated leaning pillar[6]arene, which can selectively recognize iodide anions to form a 1:1 host-guest complex driven by anion-pi interactions. This innovative application provides a new avenue for the design of selective receptors for anions and electron-deficient macrocyclic arenes.

ORGANIC & BIOMOLECULAR CHEMISTRY (2022)

Article Spectroscopy

Study of relations between chemical, colour and fluorescence properties of raw and dried meat powders of cow and yak (Bos grunniens)

Zh. E. Ozbekova, A. A. Abdyldaev, A. A. Kulmyrzaev

Summary: This study compared two drying methods for cow and yak muscles, finding that freeze drying caused less discoloration. Additionally, analysis of fluorescence spectra allowed for accurate prediction of chemical composition and color characteristics of the muscles.

SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY (2024)

Article Spectroscopy

Time-resolved spectroscopic and computational study of the initial events in doxazosin photochemistry

Leo Mandic, Ivan Ljubic, Iva Dzeba

Summary: In this study, a combined experimental and computational approach was used to investigate the photoexcitation and photodegradation mechanisms of Doxazosin (DOX). The results provide valuable insights into the primary events following the photoexcitation of DOX and its potential applications.

SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY (2024)

Article Spectroscopy

Dual-mode fluorescence and colorimetric sensing of sulfide anion in natural water based on near-infrared Ag2S quantum dots and MnO2 nanosheets complex

Xiufeng Wang, Yao Jin, Wenhui Ai, Siqi Wang, Zhiqing Zhang, Ting Zhou, Fang Wang, Guodong Zhang

Summary: This study successfully synthesized near infrared fluorescence Ag2S quantum dots (QDs) and developed a dual-mode sensor for sulfide anion using the excellent oxidase-like characteristics of manganese dioxide (MnO2) nanosheets. The sensor showed a wider detection range, higher sensitivity, and shorter reaction time, making it suitable for highly selective detection of sulfide in different concentration ranges.

SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY (2024)

Article Spectroscopy

Near-infrared wide-range dual-gas sensor system for simultaneous detection of methane and carbon monoxide in coal mine environment

Yafei Li, Yanming Ma, Chuantao Zheng, Di Yu, Lien Hu, Shuo Yang, Fang Song, Yadan Li, Shuanghai Liu, Zhanrui Zhang, Yu Zhang, Yiding Wang, Frank K. Tittel

Summary: To effectively monitor gas explosion and coal spontaneous combustion in coal mine, an intrinsically safe and explosion-proof dual-gas sensor system was developed for methane (CH4) and carbon monoxide (CO) measurement. The system achieved different measurement ranges using laser scanning and gas cells, and improved stability and accuracy through gas pre-treatment and temperature compensation algorithm.

SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY (2024)

Article Spectroscopy

Infrared characterization of hydrated products of glyoxal in aqueous solution

Pei-Rong Chen, Li-Kang Chu

Summary: In this study, the hydrates of glyoxal were investigated using infrared absorption spectrometry. The results showed that at low concentrations, glyoxal mainly exists as monomeric dihydrate. These findings provide suitable detection windows for further research on the roles of glyoxal and its hydrates in atmospheric and aerosol chemistry, as well as the relevant reaction kinetics.

SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY (2024)

Article Spectroscopy

Determining the nanostructure and main axis of gly-his-gly fibrils using the amide I' bands in FTIR, VCD, and Raman spectra

Nichole O'Neill, Thamires A. Lima, Fabio Furlan Ferreira, Nicolas J. Alvarez, Reinhard Schweitzer-Stenner

Summary: This study determines the main fibril axis of GHG gel-forming fibrils using various techniques and compares the results with simulated data. The analysis suggests that the hydrophobic xz-surfaces of GHG fibrils could be a good target for the adsorption of hydrophobic drugs.

SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY (2024)

Article Spectroscopy

An ultra-sensitive fluorescent probe for recognition of aluminum ions and its application in environment, food, and living organisms

Mengyuan Liu, Hanchuang Zhu, Yikun Fang, Caiyun Liu, Xinke Li, Xiaohui Zhang, Lixue Ma, Kun Wang, Miaohui Yu, Wenlong Sheng, Baocun Zhu

Summary: ABHS is an efficient fluorescent probe that can accurately and sensitively detect Al3+ with strong resistance to interference. It also demonstrates excellent detection and imaging capabilities in complex real samples.

SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY (2024)

Article Spectroscopy

Techno-economic assessment of waste mandarin biochar as a green adsorbent for binary dye wastewater effluents of methylene blue and basic fuchsin: Lab- and large-scale investigations

Ahmed S. El-Shafie, Evana Rahman, Yasser Gadelhak, Rehab Mahmoud, Marwa El-Azary

Summary: The recycling of waste mandarin peels into biochar (MRBC) has been used as a high performance and cost-effective adsorbent for treating polluted wastewater effluents. Batch adsorption studies were conducted to analyze the adsorption competency of MRBC on two dyes, methylene blue (MB) and basic fuchsin (BF), either in individual solutions or binary combinations. The results showed that MRBC was capable of effectively removing a high percentage of both dyes. However, the adsorption capacity decreased when the dyes were combined. The cost estimation of MRBC production and wastewater treatment indicated that both were relatively low.

SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY (2024)

Article Spectroscopy

Exploring the impact of novel thiazole-pyrazole fused benzo-coumarin derivatives on human serum albumin: Synthesis, photophysical properties, anti-cholinergic activity, and interaction studies

Anindita Bhatta, Jahnabi Upadhyaya, Dipak Chamlagai, Lincoln Dkhar, Pynskhemborlang T. Phanrang, Mohan Rao Kollipara, Sivaprasad Mitra

Summary: Derivatives of thiazole-pyrazole fused benzo-coumarin compounds were synthesized and their photophysical properties were investigated. The synthesized coumarin compounds showed potential as therapeutic agents for Alzheimer's disease, inhibiting acetylcholinesterase activity. The presence of human serum albumin was found to affect the inhibition activity.

SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY (2024)

Article Spectroscopy

Insights into temperature-induced phase transition mechanism of CL-20 using terahertz spectroscopy

Yongwei Duan, Quancheng Liu, Yiju Zhu, Qi Zhang, Xiaohui Duan, Hu Deng, Liping Shang

Summary: In this study, the phase transition of CL-20 was observed using terahertz spectroscopy, and quantum chemical calculations were employed to analyze the vibrations. The results indicated changes in the vibrations of CL-20 before and after phase transition.

SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY (2024)

Article Spectroscopy

Lead-free double perovskite Cs2NaInCl6 nanocrystals doped with Sb3+and Tb3+for copper ions detection in lubricating oil

Yuefeng Gao, Sai Xu, Baojiu Chen

Summary: This study synthesized Cs2NaInCl6 nanocrystals co-doped with Sb3+ and Tb3+ ions as probes for copper ions detection in lubricating oil. The introduction of Sb3+ effectively reduced the band gap of the host material and enabled energy transfer pathway for Tb3+ emission. The doped Tb3+ ions resulted in the suppression of emission due to electron transfer. The Cs2NaInCl6: 2.5 %Sb3+, 40 %Tb3+ NCs exhibited superior sensitivity and selectivity for copper ions detection.

SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY (2024)

Article Spectroscopy

Construction of a highly sensitive detection platform for heparin based on a turn-off cationic fluorescent dye

Yu Liu, Yue Zhang, Changyao Liu, Ce Wang, Baocai Xu, Li Zhao

Summary: A highly sensitive detection platform for heparin was developed using a cationic fluorescent dye (cresyl violet acetate) as a fluorescence probe. The platform demonstrated high selectivity towards heparin and achieved detection in both HEPES solution and serum.

SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY (2024)

Article Spectroscopy

Ultrafast spectroscopic studies on the interaction of reactive oxygen species with a probe impregnated in nanoscopic and microscopic matrix formulation

Lopamudra Roy, Nivedita Pan, Susmita Mondal, Ria Ghosh, Md. Nur Hasan, Neha Bhattacharyya, Soumendra Singh, Kallol Bhattacharyya, Arpita Chattopadhyay, Samir Kumar Pal

Summary: The study focuses on the interaction between reactive oxygen species (ROS) and a spectroscopic probe called Rose Bengal (RB), encapsulated in nanoscopic sodium dodecyl sulphate (SDS) micelles and entrapped in microscopic nylon 66 solid matrix. The research demonstrates efficient interaction between ROS and RB-SDS, and investigates the mechanism of hydroxyl radicals generation. Based on these findings, a prototype device utilizing RB embedded in a nylon thin film for quantification of ROS in extracellular fluids and food materials was developed.

SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY (2024)

Article Spectroscopy

Anthracene and tetraphenylsilane based conjugated porous polymer nanoparticles for sensitive detection of nitroaromatics in water

Xiaosong Sun, Qihao Cui, Wenyue Dong, Qian Duan, Teng Fei

Summary: Conjugated porous polymers (CPPs) are promising sensing materials and their application in aqueous media is limited. In this study, we synthesized CPPs with porous structure and prepared nanoparticles, enabling efficient photoluminescence sensing of nitroaromatic explosives in aqueous phase.

SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY (2024)

Article Spectroscopy

Non-invasive analysis of reference glass and historical mosaic tesserae by means of reflectance infrared spectroscopy

Maria Cristina Caggiani, Germana Barone, Paolo Mazzoleni

Summary: Raman spectroscopy is commonly used for studying glassy materials in cultural heritage, but it is more difficult to interpret the spectra and apply the technique with portable instruments. In contrast, diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS) can be used in archaeometric investigations as it is portable and non-invasive. However, there is limited application of this technique to historical glasses. This exploratory work demonstrates the potential of DRIFTS, in combination with portable X-ray Fluorescence (pXRF) and EDS microanalyses, for studying the composition and alteration of glass samples in cultural heritage.

SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY (2024)