Article
Chemistry, Analytical
Jiaju Hu, Ying Yu, Zhuolin Xiao, Ying Gao
Summary: Photochemical vapor generation (PVG) of Zinc (Zn) and Gallium (Ga) was reported for the first time in this study. The study investigated the main parameters influencing PVG of Zn and Ga and found that formic acid (FA) and Cu2+ were required for the generation of volatile species. The study also examined the effects of interfering ions on PVG of Zn and Ga and speculated the formation of carbonyl compounds. Good precisions and low limits of detection were achieved with PVG-ICP-MS measurement. Furthermore, nanoparticles containing Cu, Zn or Ga were discovered in the liquid solution after UV irradiation.
MICROCHEMICAL JOURNAL
(2023)
Article
Chemistry, Analytical
Ying Yu, Hanjiao Chen, Qian Zhao, Qing Mou, Liang Dong, Ruilin Wang, Zeming Shi, Ying Gao
Summary: Enhancement and/or suppression effects on the photochemical vapor generation (PVG) of 17 elements at the gas-liquid interface were observed, with up to 7.3-fold increase in analytical sensitivity in the presence of gas-liquid interface(s) compared to traditional methods. The introduction of gas-liquid interface(s) and elevated temperature likely facilitated radical generation, subsequent reactions, and separation/detection of volatile species of elements, while unstable intermediate substances/products decomposed at high temperatures, decreasing analyte signal response. This finding contributes to understanding element transport under UV irradiation and has potential applications in trace element analysis in environmental and biological samples.
ANALYTICAL CHEMISTRY
(2021)
Article
Chemistry, Applied
Richard M. Oliveira, Barbara S. Soares, Daniel L. G. Borges
Summary: A novel method using photochemical vapour generation combined with inductively coupled plasma mass spectrometry was introduced for the determination of iodine in alcoholic beverages. By diluting the samples and optimizing the operational conditions, the method showed high sensitivity and accuracy, with recoveries of spiked analyte ranging from 95 to 105% and relative standard deviations better than 9%.
JOURNAL OF FOOD COMPOSITION AND ANALYSIS
(2021)
Article
Chemistry, Analytical
Jakub Soukal, Stanislav Musil
Summary: The PVG of Ni in fresh water samples was optimized for high sensitivity and low LOD using a flow-through photoreactor with 30% formic acid, achieving an overall efficiency of 42% and LOD of 1.9 ng L-1. The addition of 1.5 M ammonium formate improved efficiency, but did not significantly impact analytical performance. Interferences from inorganic anions and transition metals were investigated, and accuracy was confirmed through analysis of standard reference materials.
MICROCHEMICAL JOURNAL
(2022)
Article
Chemistry, Analytical
Jing Hu, Hanjiao Chen, Xiaoming Jiang, Xiandeng Hou
Summary: In this study, it was found that photochemical vapor generation of halides can be achieved in organic-acid-free media, with performance comparable to traditional scenarios using acetic acid. The role of copper acetate complexes in facilitating the generation of halides was highlighted. Gas chromatography-mass spectrometry was used to identify methyl halides as principal volatile compounds, and various intermediate species were confirmed using different analytical methods. The method's application in analyzing bottled water and seawater showed spike recoveries between 92 and 101%.
ANALYTICAL CHEMISTRY
(2021)
Article
Spectroscopy
Lanlan Li, Chenxi Jiang, Jing Xiao, Hong Luo, Shu Zhang, Zhirong Zou, Ke Huang
Summary: Selenium, mercury and arsenic are widely distributed in the environment, and their toxicity depends on their concentration and forms. Accurate monitoring of these elements is necessary. Photochemical vapor generation (PVG) is a promising method for analytical atomic spectrometry, and it has been applied to determine selenium, mercury and arsenic with various separation techniques. This review summarizes the applications of PVG-analytical atomic spectrometry in selenium, mercury and arsenic speciation analysis.
SPECTROCHIMICA ACTA PART B-ATOMIC SPECTROSCOPY
(2023)
Article
Chemistry, Analytical
Jin Luo, Zenghui Hu, Fujian Xu, Dongxian Geng, Xiaoling Tang
Summary: An online photochemical vapor generation (PCVG) method using MOF MIL-125-NH2 as a catalyst, coupled with HPLC-ICPMS, was proposed for highly sensitive speciation analysis of selenium. Under optimized conditions, the LOD for Se(IV) and Se(VI) were found to be as low as 0.8 ng/mL, with RSD values of 4.6% and 3.7% at 20 ng/mL concentration. Certified reference materials and bottled natural mineral water samples were successfully analyzed using this method.
MICROCHEMICAL JOURNAL
(2022)
Article
Chemistry, Analytical
Eva Jenikova, Eliska Novakova, Jakub Hranicek, Stanislav Musil
Summary: Photochemical vapor generation (PVG) of Te4+ was achieved using a simple reactor and investigated for its application in the determination of Te in water samples. The study explored the composition of the reaction medium, the irradiation time, and the effects of sensitizers and interferents. The results showed that PVG could be used for sensitive determination of Te in water samples under optimized conditions.
ANALYTICA CHIMICA ACTA
(2022)
Article
Chemistry, Analytical
Yongchun Liu, Jie Zou, Bin Luo, Hairong Yu, Zhigang Zhao, Hui Xia
Summary: Using natural plant extracts as auxiliary matrix or photocatalysts can enhance the efficiency and sensitivity of photochemical vapor generation atomic fluorescence spectrometry for trace mercury determination, while reducing biological toxicity and secondary pollution. This green and sensitive method provides an experimental basis for expanding the photochemical vapor generation system.
MICROCHEMICAL JOURNAL
(2021)
Article
Chemistry, Multidisciplinary
Alessandro D'Ulivo
Summary: This paper presents a summary of studies on the mechanisms of hydride and volatile species generation through reaction with aqueous boranes. The derivatization reaction has been widely used in elemental determination and speciation analysis. The research also includes the definition of general reaction models and the study of the effects of additives and interferences on the reaction.
PURE AND APPLIED CHEMISTRY
(2023)
Article
Biochemical Research Methods
Ying Yu, Jiaju Hu, Xinyi Zhao, Jiangchuan Liu, Ying Gao
Summary: Photochemical vapor generation (PVG) of germanium (Ge) was first reported in this work. The synergistic effect from cobalt/chloride ions and air-liquid interfaces was found to enhance the PVG of Ge. The study also investigated the PVG mechanism of Ge and explored its potential applications.
ANALYTICAL AND BIOANALYTICAL CHEMISTRY
(2022)
Article
Chemistry, Multidisciplinary
In Min Hwang, Sera Jung, Ji Young Jeong, Min Ji Kim, Ha-Young Jang, Jong-Hee Lee
Summary: Due to their rich mineral content and flavor, kimchi cabbage leaves and roots have high nutritional and medicinal values. This study analyzed the major nutrient, trace, and toxic elements in kimchi cabbage cultivation soil, leaves, and roots. The results showed high contents of K, B, and Be in kimchi cabbage leaves and roots, while all toxic elements were below the WHO-stipulated threshold values. The study also revealed the distribution of elements and confirmed the differences in content between groups. This research contributes to our understanding of the connections between plant physiology, cultivation conditions, and human health.
Article
Nutrition & Dietetics
Victor Toro-Roman, Ignacio Bartolome, Jesus Siquier-Coll, Maria C. Robles-Gil, Diego Munoz, Marcos Maynar-Marino
Summary: This study analyzed the concentrations of selenium in athletes and subjects with low levels of physical training, and found that physical training can modify selenium metabolism. Deficiencies in selenium concentrations may exist at the intracellular level.
Article
Chemistry, Analytical
Lanlan Li, Qirui Huang, Jing Xiao, Jiamin Feng, Shu Zhang, Hong Luo, Zhirong Zou, Xiaoli Xiong
Summary: In this study, Fe3O4 served as both an adsorbent and photocatalyst in the photochemical vapor generation-atomic fluorescence spectrometry (PVG-AFS) determination of Bi(III) after preconcentration. The effects of formic and acetic acid concentration, UV irradiation time, Fe3O4 concentration, and interferences from co-existing ions were investigated. Results showed that the AFS intensity was slightly enhanced by the mixed acid solution, but a significant enhancement was observed when Fe3O4 was used as a photocatalyst. Fe3O4 can decompose in the mixed acid solution, generating Fe3+ which acts as a sensitizer for improving Bi(III) efficiency. Under optimized conditions, the LOD of the proposed PVG-AFS system with or without preconcentration (5 mL sample) were 0.44 ng/mL and 0.07 ng/mL, respectively. The PVG-AFS system was successfully applied to the determination of water samples and demonstrated good accuracy and applicability with recoveries ranging from 94% to 104%.
MICROCHEMICAL JOURNAL
(2022)
Article
Chemistry, Analytical
A. Kuptsov, A. V. Volzhenin, V. A. Labusov, A. Saprykin
Summary: The analytical capabilities of the method of atomic emission spectrometry on a two-jet arc plasma with the use of spark ablation and calibration using standard solutions have been evaluated. Optimization of solution injection conditions and studying the effect of matrix element concentration on signal-to-background ratio have been carried out. Calibration using relative sensitivity factors and standard solutions, along with the use of spectral lines of analytes and an internal standard, allowed for accurate and reproducible results in impurity determination in steel and copper samples.
JOURNAL OF ANALYTICAL ATOMIC SPECTROMETRY
(2021)
Editorial Material
Chemistry, Analytical
Daniel L. G. Borges, Eduardo Carasek, Fabio R. P. Rocha, Joaquim A. Nobrega, Lauro T. Kubota, Leticia M. Costa, Pedro V. Oliveira, Sergio L. C. Ferreira, Vania P. Campos
MICROCHEMICAL JOURNAL
(2018)
Article
Chemistry, Analytical
Graziela Salvador, Barbara Souza Soares, Daniel L. G. Borges
MICROCHEMICAL JOURNAL
(2018)
Article
Chemistry, Analytical
Richard Macedo de Oliveira, Daniel L. G. Borges
JOURNAL OF ANALYTICAL ATOMIC SPECTROMETRY
(2018)
Article
Environmental Sciences
Eduardo Bastos, Mauana Schneider, Daiane Paula Cunha de Quadros, Bernhard Welz, Manuela Bernardes Batista, Paulo Antunes Horta, Leonardo Rubi Rorig, Jose Bonomi Barufi
ECOTOXICOLOGY AND ENVIRONMENTAL SAFETY
(2019)
Article
Chemistry, Analytical
Marlei Veiga, Patricia Mattiazzi, Jefferson S. de Gois, Paulo C. Nascimento, Daniel L. G. Borges, Denise Bohrer
Article
Geochemistry & Geophysics
Paul Vallelonga, Jefferson S. de Gois, Daniel L. G. Borges, Marta Costas-Rodriguez, Vasileios Gkinis, Delphine Lannuzel, Andrea Spolaor, Frank Vanhaecke
Summary: This study investigated the isotopic partitioning of Br and Cl in Southern Ocean sea ice for the first time. While the concentrations of bromine and chlorine showed a positive correlation, the isotopic compositions exhibited less consistent relation and significant variability within individual ice cores. Various factors such as ice texture, age, salt content, and algal biomass content may influence isotopic fractionation processes in sea ice.
GEOCHIMICA ET COSMOCHIMICA ACTA
(2021)
Article
Spectroscopy
Tarcisio S. Almeida, Marlon Brancher, Henrique de Melo Lisboa, Davide Franco, Tatiane A. Maranhao, Daniel L. G. Borges
SPECTROCHIMICA ACTA PART B-ATOMIC SPECTROSCOPY
(2020)
Article
Chemistry, Applied
Richard M. Oliveira, Barbara S. Soares, Daniel L. G. Borges
Summary: A novel method using photochemical vapour generation combined with inductively coupled plasma mass spectrometry was introduced for the determination of iodine in alcoholic beverages. By diluting the samples and optimizing the operational conditions, the method showed high sensitivity and accuracy, with recoveries of spiked analyte ranging from 95 to 105% and relative standard deviations better than 9%.
JOURNAL OF FOOD COMPOSITION AND ANALYSIS
(2021)
Article
Chemistry, Analytical
Karine S. Coelho, Eduardo S. Chaves, Daniel L. G. Borges, Sindy R. Krzyzaniak, Rafael C. C. Rocha, Tatiana D. Saint' Pierre, Vera Lucia Azzolin Frescura Bascunan
Summary: Palladium nanoparticles were evaluated as a potential chemical modifier for lead determination in high-resolution continuum source graphite furnace atomic absorption spectrometry. The results showed that the use of palladium nanoparticles can improve sensitivity and thermal stability, especially when using 3 nm spherical-shaped particles.
INTERNATIONAL JOURNAL OF ENVIRONMENTAL ANALYTICAL CHEMISTRY
(2022)
Article
Chemistry, Multidisciplinary
Renan G. Marim, Gilberto S. Coelho Junior, Paola C. C. de Azevedo, Daniel L. G. Borges, Tatiane A. Maranhao, Fernando J. S. de Oliveira, Vera L. A. F. Bascunan, Eduardo S. Chaves
Summary: In this study, the assessment of chlorine, fluorine, and sulfur concentrations in depth profile of drill cuttings was performed using ion chromatography with optimized sample preparation by pyrohydrolysis. The results showed high accuracy, good precision, and suitability for drill cuttings analysis.
JOURNAL OF THE BRAZILIAN CHEMICAL SOCIETY
(2022)
Article
Chemistry, Analytical
Gilberto da S. Coelho Junior, Klaiani B. Fontana, Tatiane A. Maranhao, Daniel L. G. Borges
Summary: In this study, particulate matter (PM) impregnated with methylmercury was analyzed using atomic absorption spectrometry coupled with a customized dielectric barrier discharge (DBD) device. The combination of chemical vapor generation (CVG) and the DBD device allowed for efficient detection of methylmercury. The study also investigated the adsorption of methylmercury on PM and found that it was efficiently adsorbed. Furthermore, the feasibility of the device for methylmercury detection in the presence of Hg2+ was demonstrated.
ANALYTICAL METHODS
(2022)
Article
Chemistry, Analytical
Richard M. de Oliveira, Daniel L. G. Borges, Patricia Grinberg, Ralph E. Sturgeon
Summary: A novel high yield photochemical vapor generation (PVG) method for Os was developed, achieving a method detection limit of 0.16 pg mL(-1) and a precision of 4% (RSD) at 10 ng mL(-1). The product identity has not been confirmed but is suspected to be a carbonyl or alkyl-substituted carbonyl based on the reaction conditions and volatility difference from OsO4.
JOURNAL OF ANALYTICAL ATOMIC SPECTROMETRY
(2021)
Article
Chemistry, Analytical
Richard M. de Oliveira, Daniel L. G. Borges, Patricia Grinberg, Zoltan Mester, Ralph E. Sturgeon
Summary: The presence of Cu2+ significantly enhances the photochemical vapor generation (PVG) efficiencies of both Br- and BrO3- species, with Cu2+ serving as a photocatalyst in both PVG systems. Efficient synthesis of CH3Br is achieved through a flow-through photochemical reactor, while high PVG efficiency for Br- is achieved using a germicidal lamp.
JOURNAL OF ANALYTICAL ATOMIC SPECTROMETRY
(2021)
Article
Chemistry, Analytical
Leticia Pereira, Tatiane de Andrade Maranhao, Vera L. A. Frescura, Daniel L. G. Borges
JOURNAL OF ANALYTICAL ATOMIC SPECTROMETRY
(2019)
Meeting Abstract
Chemistry, Multidisciplinary
Richard de Oliveira, Graziela Salvador, Barbara Soares, Daniel Borges
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY
(2018)
Article
Chemistry, Analytical
Michel Rocha Baqueta, Augusto Cesar Costa-Santos, Ana Paula Rebellato, Gisele Marcondes Luz, Juliana Azevedo Lima Pallone, Federico Marini, Alexsandro Lara Teixeira, Douglas N. Rutledge, Patricia Valderrama
Summary: This study reports the essential element composition of new Brazilian Canephora coffees and applies chemometric tools for analysis. The results demonstrate the suitability of this method for origin and species discrimination based on the inorganic fraction of coffee.
MICROCHEMICAL JOURNAL
(2024)
Article
Chemistry, Analytical
Mengjie Li, Jiapeng Wang, You Zhou, Yang Chen, Lingying Xia
Summary: A novel photoelectrochemical biosensor based on gold nanoparticles and specific structures was developed for highly sensitive detection of mercury ion. The multiple sandwich structures hindered electron supply and light harvesting, resulting in a weakened PEC signal, while the specific structures extinguished the PEC signal, enabling quantitative detection of Hg2+. The sensor exhibited high selectivity and stability, with potential applications in environmental detection, biological analysis, and medical research.
MICROCHEMICAL JOURNAL
(2024)
Article
Chemistry, Analytical
Mohamed A. Korany, Rasha M. Youssef, Marwa A. A. Ragab, Mostafa A. Afify
Summary: A stability-indicating fit-for-purpose method was developed for the determination of HC, TL, and PS in syrup dosage form. The method successfully separated CL from THY and quantified the analytes using HPLC-DAD. The robustness of the method was assessed through statistical analysis and self-validation.
MICROCHEMICAL JOURNAL
(2024)
Article
Chemistry, Analytical
Lingling Lin, Minyu Li, Ping Li, Chenqing Ye, Huanglong Zhuang, Shaohuang Weng, Feng Chen
Summary: This study developed a highly sensitive and selective electrochemical sensor for simultaneous detection of dopamine and uric acid. The sensor exhibited excellent anti-interference and stability, and could accurately measure dopamine and uric acid in human urine samples.
MICROCHEMICAL JOURNAL
(2024)
Article
Chemistry, Analytical
Peifang Chen, Caiyun Jiang, Zhouping Wang, Hong-zhen Lian, Xiaoyuan Ma
Summary: In this study, a high-performance SERS-active aptasensor was successfully developed for the quantitative analysis of AFB1 in cereal grains, which is of great significance in the field of food safety.
MICROCHEMICAL JOURNAL
(2024)
Article
Chemistry, Analytical
E. Abas, C. Marina-Montes, C. Perez-Marin, J. Puimedon, J. Anzano
Summary: This study conducted a comprehensive measurement of natural and anthropogenic radionuclides in soil, water, and air in different locations around Deception Island in Antarctica. The results revealed significant levels of 210Pb and anthropogenic 137Cs in soil samples near old human settlements and facilities, as well as detectable levels of 137Cs and 60Co in water samples from old hunting areas. The findings also suggested potential resuspension processes based on higher-than-expected air quality results.
MICROCHEMICAL JOURNAL
(2024)
Article
Chemistry, Analytical
Joao Franciso Allochio, Nayara A. dos Santos, Nathalia dos S. Conceicao, Clara S. D. Baptista, Keyller B. Borges, Valdemar Lacerda Jr, Wanderson Roma
Summary: This study developed a fiber spray ionization mass spectrometry (FSI-MS) method, which shows great potential in detecting illicit drugs. Compared with paper spray ionization mass spectrometry (PSI-MS), FSI-MS demonstrates higher sensitivity in COC detection.
MICROCHEMICAL JOURNAL
(2024)
Article
Chemistry, Analytical
Dina A. Ahmed, Ola G. Hussein, Mamdouh R. Rezk, Mohamed Abdelkawy, Yasmin Rostom
Summary: The main goal of this study was to develop two green chromatographic techniques, HPLC and TLC, for the determination of alcaftadine (ALF) in pharmaceutical formulation and biological samples. The developed HPLC technique showed high efficiency and minimal environmental impact, successfully identifying ALF in the presence of its degradate. The TLC method provided a stability indicating study for ALF and was determined to be safe, green, and eco-friendly.
MICROCHEMICAL JOURNAL
(2024)
Article
Chemistry, Analytical
Abdullah Taner Bisgin
Summary: A green, speedy, and handy method for separation and determination of four commonly used food colorants was established using vortex assisted sequential-simultaneous liquid phase micro-extraction (VA-SS-LPME). The method does not require any instrumental chromatographic techniques. The procedure includes sequential separation steps using different extractants and simultaneous UV-vis spectrophotometric determination steps. The method is environmentally friendly and applicable for determination of colorants in food and pharmaceuticals.
MICROCHEMICAL JOURNAL
(2024)
Article
Chemistry, Analytical
Yifan Zhang, Tong Zhang, Wenjing Ba, Li Liu, Yuan Rao, Xiaodan Zhang, Hanhan Zhang, Xiu Jin
Summary: This paper proposes a novel spectral transfer modelling method based on neural network architecture searching for the asymptomatic prediction of Akizuki pear cork spot disorder. The experiments show that the model by this method is more effective, achieving an accuracy of 82.61%.
MICROCHEMICAL JOURNAL
(2024)
Article
Chemistry, Analytical
Krzysztof Greda, Maja Welna, Anna Szymczycha-Madeja, Pawel Pohl
Summary: For the first time, a dispersive micro-solid phase extraction (D-mu SPE) based on graphene oxide was used for the ultrasensitive determination of Cd. With this method, Cd can be efficiently extracted from a mixture of alkali and alkaline earth metals without the need for an elution step. The combination of D-mu SPE and SAGD OES significantly reduces matrix effects and improves the tolerance of Cd to alkali metals. The method shows simplicity in the measurement system and the commercially available nanosorbent used.
MICROCHEMICAL JOURNAL
(2024)
Article
Chemistry, Analytical
P. K. Fathima Anjila, G. R. Tharani, Anand Sundaramoorthy, Venkat Kumar Shanmugam, Karthikeyan Subramani, Shanmugavel Chinnathambi, Ganesh N. Pandian, Vimala Raghavan, Andrews Nirmala Grace, Singaravelu Ganesan, Mangaiyarkarasi Rajendiran
Summary: This work proposes a rapid and sensitive spectroscopic method for detecting melamine in food products using rare-earth Terbium-doped Graphene Quantum Dots (Tb-GQDs) synthesized by microwave and simple chemical conjugation methods. The synthesized Tb-GQDs show a spherical shape with a size of approximately 6 nm and a quantum yield of 52%. The maximum detection limit for melamine concentration in milk and milk products is found to be 0.31 μM. The dual emitting Tb-GQDs provide a sensitive and effective platform for real-time detection of melamine in food samples, particularly in milk, and show promising potential in the food industry.
MICROCHEMICAL JOURNAL
(2024)
Review
Chemistry, Analytical
Piyush Dey, Mandeep Kaur, Akhil Khajuria, Dilmeet Kaur, Manpreet Singh, Hema Kumari Alajangi, Neha Singla, Gurpal Singh, Ravi Pratap Barnwal
Summary: Environmental issues, such as the uncontrolled release of dangerous pollutants, have significant impacts on human health. Traditional methods for detecting pollutants require specialized personnel and equipment, but nanotechnology has improved the performance of biosensors. This article discusses the use of nanotechnology in pollutant detection and the associated techniques.
MICROCHEMICAL JOURNAL
(2024)
Article
Chemistry, Analytical
Sa Dong, Qiuyun Shi, Lingjun Guan, Yulong Wang, Pengyan Liu, Cunzheng Zhang, Jianguo Feng
Summary: In this study, a highly sensitive indirect competitive chemiluminescence enzyme immunoassay (icCLEIA) method was developed for the determination of sodium pentachlorophenolate (PCP-Na) and its metabolite pentachlorophenol (PCP). The method showed high specificity and affinity with a detection limit of 0.0032 ng/mL for PCP-Na and 0.0192 ng/mL for PCP. The method had no cross reaction with other chlorophenols compounds except for PCP. The average recoveries in chicken, pork and fish samples were 81.3-105.8% with low coefficient of variation (CV).
MICROCHEMICAL JOURNAL
(2024)
Article
Chemistry, Analytical
Palaniappan Ilayaraja, Murugan Manivannan, Paramasivam Parthiban
Summary: Nirmatrelvir, an antiviral drug used for the treatment of COVID-19, has been recommended by the World Health Organization. We developed an optimized analytical method for the quantification of Nirmatrelvir and its products, with high sensitivity and a wide linear range. The method also meets the requirements for greenness evaluation.
MICROCHEMICAL JOURNAL
(2024)