4.7 Article Proceedings Paper

Continuous functionally graded boron carbide-aluminum nanocomposites by spark plasma sintering

Publisher

ELSEVIER SCIENCE SA
DOI: 10.1016/j.msea.2007.05.124

Keywords

functionally graded materials; spark plasma sintering; boron carbide; aluminum; nanocomposite

Ask authors/readers for more resources

Continuous functionally graded boron carbide aluminum cermets were created using spark plasma sintering. The B4C compacts with large, precipitous density gradients were melt infiltrated with 99.999% Al at 1180 degrees C for 10 min. The microstructure of the material exhibits a gradual change from fully dense B4C with a nominal grain size of 2 pm and a hardness of 32.3 GPa to a B4C-Al cermet with a B4C grain size on the order of 200 nm and a hardness of 8.36 GPa. Prior to melt infiltration, X-ray diffraction data indicates that the B4C compacts have some microstructural defects present. This result is confirmed by the presence of twins on the fully dense fracture surface. Following melt infiltration, X-ray diffraction reveals that some of the defects are dissipated and small amounts of Al3BC are present. (C) 2007 Elsevier B.V. All rights reserved.

Authors

I am an author on this paper
Click your name to claim this paper and add it to your profile.

Reviews

Primary Rating

4.7
Not enough ratings

Secondary Ratings

Novelty
-
Significance
-
Scientific rigor
-
Rate this paper

Recommended

Article Chemistry, Inorganic & Nuclear

Colocalization of tracks from boron neutron capture reactions and images of isolated cells

Ian Postuma, Patrizia Sommi, Agostina Vitali, Diyun Shu, Greta di Martino, Laura Cansolino, Cinzia Ferrari, Vittorio Ricci, Chiara Magni, Nicoletta Protti, Setareh Fatemi, Umberto Anselmi Tamburini, Silva Bortolussi, Saverio Altieri

Summary: In Boron Neutron Capture Therapy, the effectiveness relies on the concentration and distribution of boron within the tumour cells. This study demonstrates a technique to colocalize alpha particles and lithium ions with cells, using a neutron autoradiography technique. This method combines images of cells with tracks produced in a solid-state nuclear track detector.

APPLIED RADIATION AND ISOTOPES (2021)

Article Physics, Applied

Magnetic properties of bulk nanocrystalline cobalt ferrite obtained by high-pressure field assisted sintering

Angelica Baldini, Michele Petrecca, Claudio Sangregorio, Umberto Anselmi-Tamburini

Summary: The study found that highly pure nanostructured ferrite particles can be synthesized using a simple method and densified through high-pressure field-assisted sintering to obtain materials with complex microstructures. During sintering, there was no change in phase composition, and a high degree of densification while maintaining nanometric crystallite size was achieved by using high uniaxial pressure with relatively low sintering temperatures and times.

JOURNAL OF PHYSICS D-APPLIED PHYSICS (2021)

Article Biochemistry & Molecular Biology

Oxidative Stress Boosts the Uptake of Cerium Oxide Nanoparticles by Changing Brain Endothelium Microvilli Pattern

Roberta Dal Magro, Agostina Vitali, Stefano Fagioli, Alberto Casu, Andrea Falqui, Beatrice Formicola, Lorenzo Taiarol, Valeria Cassina, Claudia Adriana Marrano, Francesco Mantegazza, Umberto Anselmi-Tamburini, Patrizia Sommi, Francesca Re

Summary: Vascular oxidative stress exacerbates the progression of Alzheimer's disease, but antioxidant compounds like cerium oxide nanoparticles may help improve vascular function. CNP restored ROS levels and increased uptake in brain cells exposed to A beta, potentially offering protection against neurotoxicity.

ANTIOXIDANTS (2021)

Article Biology

A Novel Approach to Design and Evaluate BNCT Neutron Beams Combining Physical, Radiobiological, and Dosimetric Figures of Merit

Ian Postuma, Sara Gonzalez, Maria S. Herrera, Lucas Provenzano, Michele Ferrarini, Chiara Magni, Nicoletta Protti, Setareh Fatemi, Valerio Vercesi, Giuseppe Battistoni, Umberto Anselmi Tamburini, Yuan Hao Liu, Leena Kankaanranta, Hanna Koivunoro, Saverio Altieri, Silva Bortolussi

Summary: Novel criteria of clinical potential and safety have been introduced to evaluate neutron beams for BNCT, showing that even beams rejected by traditional physical measurements can have comparable clinical performance.Radiobiological and dosimetric criteria are effective tools in selecting safe and effective beams for patient treatment, even when standard physical recommendations are not met.

BIOLOGY-BASEL (2021)

Article Physics, Applied

Influence of ZnO nanorod surface chemistry on passivation effect of TiO2 shell coating

Xuan Li, Ying Tu, Simona Pace, Umberto Anselmi-Tamburini, Joe Briscoe

Summary: The core-shell structure with ZnO cores effectively suppresses surface defects, particularly in ZnO synthesized in an OH- rich environment, where the TiO2 shell coating has a stronger passivation effect on the surface defects. Both PL and XPS results confirm the effectiveness of the TiO2 shell coating in passivating surface defects of ZnO nanostructures.

JOURNAL OF PHYSICS D-APPLIED PHYSICS (2021)

Article Radiology, Nuclear Medicine & Medical Imaging

Target manufacturing by Spark Plasma Sintering for efficient 89Zr production

S. Cisternino, E. Cazzola, H. Skliarova, J. Amico, M. Malachini, G. Gorgoni, U. Anselmi-Tamburini, J. Esposito

Summary: The study explored using Spark Plasma Sintering (SPS) technique to manufacture yttrium solid targets for efficient Zr-89 radioisotope production. Results showed that the production yield and quality of Zr-89 obtained from SPS manufactured targets were comparable to those from standard yttrium foil targets.

NUCLEAR MEDICINE AND BIOLOGY (2022)

Article Nuclear Science & Technology

Development of the ACSpect neutron spectrometer: Technological advance and response against an accelerator-based neutron beam

Gabriele Parisi, Andrea Pola, Davide Bortot, Davide Mazzucconi, Giovanni D'Angelo, Chiara Magni, Ian Postuma, Silva Bortolussi, Nicoletta Protti, Saverio Altieri, Umberto Anselmi Tamburini, Valerio Vercesi, Stefano Agosteo

Summary: This paper presents a novel neutron spectrometer called ACSpect, which consists of a two-stages monolithic silicon telescope detector and an organic scintillator. It is capable of high-resolution measurements in the energy range of 250keV-4MeV.

RADIATION MEASUREMENTS (2022)

Letter Multidisciplinary Sciences

Is configurational entropy the main stabilizing term in rock-salt Mg0.2Co0.2Ni0.2Cu0.2Zn0.2O high entropy oxide?

Martina Fracchia, Mauro Coduri, Maela Manzoli, Paolo Ghigna, Umberto Anselmi Tamburini

NATURE COMMUNICATIONS (2022)

Article Biochemistry & Molecular Biology

Cerium Oxide Nanoparticles Regulate Oxidative Stress in HeLa Cells by Increasing the Aquaporin-Mediated Hydrogen Peroxide Permeability

Giorgia Pellavio, Patrizia Sommi, Umberto Anselmi-Tamburini, Maria Paola DeMichelis, Stefania Coniglio, Umberto Laforenza

Summary: This study analyzed the effect of cerium oxide nanoparticles (CNPs) on the functioning of aquaporins (AQPs). The results showed that CNPs increased the diffusion of hydrogen peroxide (H2O2) in cells, especially through AQP8. These findings suggest that CNPs could potentially be used as a pharmaceutical agent in diseases involving oxidative stress.

INTERNATIONAL JOURNAL OF MOLECULAR SCIENCES (2022)

Article Energy & Fuels

Electrochemical performance of high and medium entropy oxides for lithium batteries

M. Fracchia, D. Callegari, M. Coduri, U. Anselmi-Tamburini, M. Manzoli, E. Quartarone, P. Ghigna

Summary: Various high and medium entropy oxides with rock salt structures were prepared and studied as anodes for lithium batteries. The reaction mechanisms of these systems are complex and involve conversion reactions. The capacity and reduction potential of these materials depend on the number of components and microstructure of the initial materials. However, the dependence cannot be rationalized based on simple stability logic.

FRONTIERS IN ENERGY RESEARCH (2022)

Article Biology

Synthesis and Characterization of Gd-Functionalized B4C Nanoparticles for BNCT Applications

Agostina Vitali, Maria Paola Demichelis, Greta Di Martino, Ian Postuma, Silva Bortolussi, Andrea Falqui, Chiara Milanese, Chiara Ferrara, Patrizia Sommi, Umberto Anselmi-Tamburini

Summary: In this study, multifunctional boron carbide nanoparticles stabilized with polyacrylic acid (PAA) and a gadolinium (Gd)-rich solid phase were synthesized and their biological activity was evaluated. The incorporation of a fluorophore (DiI) allowed for confocal microscopy imaging of the nanoparticles. Novel correlative microscopy techniques were employed to analyze the interaction and activity of these fluorescent Gd-containing B4C nanoparticles (FGdBNPs) with cultured cells. The results indicate that these nanoparticles have the potential to achieve high boron concentration in tumor cells.

LIFE-BASEL (2023)

Article Nanoscience & Nanotechnology

Enhanced Thermoelectric Performance of Nanostructured Cu2SnS3 (CTS) via Ag Doping

Ketan Lohani, Himanshu Nautiyal, Narges Ataollahi, Umberto Anselmi-Tamburini, Carlo Fanciulli, Paolo Scardi

Summary: The effect of Ag doping on the thermoelectric properties of Cu2SnS3 (CTS) was investigated. Various Cu2Ag(x)Sn(1-x)S3 (0.05 <= x <= 0.25) samples were synthesized and their structural and transport properties were studied. The x = 0.15 sample showed a 10-fold higher power factor than the undoped CTS, and both the x = 0.125 and x = 0.15 samples exhibited the highest zT value of 0.8 at 723 K. The increase in thermal conductivity of Cu2Ag(x)Sn(1-x)S3 samples with Ag substitution was found to be caused by the reduction in scattering of phonons due to the incorporation of Ag. Formation energy calculations revealed the reason for the structural transformation of CTS and similar diamond-like structures towards high symmetry polymorphs by external doping. The increase in zT value was attributed to the optimization of the band gap and the weighted mobility.

ACS APPLIED NANO MATERIALS (2023)

Article Electrochemistry

Design of Perovskite-Type Fluorides Cathodes for Na-ion Batteries: Correlation between Structure and Transport

Michele Montalbano, Daniele Callegari, Umberto Anselmi Tamburini, Cristina Tealdi

Summary: Transition metal-based sodium fluoro-perovskite materials were investigated as cathode materials for Na-ion batteries. The study combined experimental and computational techniques to investigate structures, defects, and intercalation properties. The results showed the possibility of modulating the sample's morphology and highlighted the correlation between structure and computational data for controlling both ionic and electronic conductivity.

BATTERIES-BASEL (2022)

Article Materials Science, Multidisciplinary

Lithium intercalation mechanisms and critical role of multi-doping in LiFexMn2-x-yTiyO4 as high-capacity cathode material for lithium-ion batteries

D. Callegari, M. Coduri, M. Fracchia, P. Ghigna, L. Braglia, U. Anselmi Tamburini, E. Quartarone

Summary: The ever-growing demand for high-capacity Li-ion batteries requires electrode materials that are environmentally friendly, Co-free, secure, and durable. In this study, a novel dual-doping strategy was proposed to design LiFexMn2-x-yTiyO4 (LFMT) as high-capacity cathode materials. The substitution of Mn with Fe and Ti suppressed the unwanted distortion and improved the capacity and stability of the batteries.

JOURNAL OF MATERIALS CHEMISTRY C (2022)

Article Physics, Multidisciplinary

Neutron activation and dosimetry studies for a clinical facility of Boron Neutron Capture Therapy

C. Magni, M. Ferrarini, I. Postuma, N. Protti, S. Fatemi, C. Gong, U. Anselmi-Tamburini, V. Vercesi, G. Battistoni, S. Bortolussi

Summary: Boron Neutron Capture Therapy (BNCT) is a type of radiotherapy used to treat deep-seated tumors, targeting cancer cells using a borated drug before irradiating the patient with low-energy neutrons. This study presents neutron activation analysis of different aluminum fluoride powders for potential use in the Beam Shaping Assembly (BSA) material. Additionally, Monte Carlo calculations for out-of-field dosimetry are discussed, which are crucial for assessing the safety of clinical neutron beams in terms of dose absorption by surrounding organs.

NUOVO CIMENTO C-COLLOQUIA AND COMMUNICATIONS IN PHYSICS (2021)

Article Nanoscience & Nanotechnology

The role of parent austenite grain size on the variant selection and intervariant boundary network in a lath martensitic steel

Ahmad Mirzaei, Peter D. Hodgson, Xiang Ma, Vanessa K. Peterson, Ehsan Farabi, Gregory S. Rohrer, Hossein Beladi

Summary: This study investigated the influence of parent austenite grain refinement on the intervariant boundary network in a lath martensitic steel. It found that refining the parent austenite grain led to a decrease in the fraction of certain boundaries in the martensite and an increase in the connectivity of low energy boundaries, ultimately improving the impact toughness.

MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING (2024)

Article Nanoscience & Nanotechnology

The interdependence of the thermal and mechanical cycling behaviour in Ti2448 (Ti-24Nb-4Zr-8Sn, wt%)

N. L. Church, C. E. P. Talbot, L. D. Connor, S. Michalik, N. G. Jones

Summary: Metastable beta Ti alloys based on the Ti-Nb system have attracted attention due to their unique properties. However, the unstable cyclic behavior of these alloys has hindered their widespread industrial use. Recent studies have shown that internal stresses, including those from dislocations, may be responsible for this behavior. This study demonstrates that inter-cycle thermal treatments can mitigate the unstable cyclic behavior, providing a significant breakthrough in our understanding of Ti-Nb superelastic materials.

MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING (2024)

Article Nanoscience & Nanotechnology

Ultrasonic-assisted soldering of SiC ceramic and aluminum alloy with a commercial inactive Sn3.0Ag0.5Cu solder

Di Zhao, Chenchen Zhao, Ziyang Xiu, Jiuchun Yan

Summary: This study proposes a novel strategy for achieving the bonding of SiC ceramic and Al alloy using ultrasound. The ultrasound promotes the dissolution of Al into the solder, activating the solder and triggering the interfacial reaction between SiC ceramic and solder. With increasing ultrasonic duration, the bonding between SiC and Al transitions from partial to full metallurgical bonding.

MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING (2024)

Article Nanoscience & Nanotechnology

Effect of grain orientation and precipitates on the superelasticity of Fe-Ni-Co-Al polycrystalline alloys

Kang Du, Yang Zhang, Guangda Zhao, Tao Huang, Liyuan Liu, Junpeng Li, Xiyu Wang, Zhongwu Zhang

Summary: This paper systematically investigated the evolution of microstructure in Fe-Ni-Co-Al polycrystalline alloys and its effects on mechanical properties. The results revealed that the migration of grain boundaries in different processes is driven by different factors, which impacts the grain orientation and precipitate formation. In the process of directional recrystallization, grains with specific orientations grow in the grain boundary region and form the dominant orientation, while grains with lower migration rate form the minor orientation. The alloy produced through directional recrystallization exhibited good recoverable strain and superelastic strain, while the alloy produced through solid solution treatment showed no evident superelastic behavior.

MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING (2024)

Article Nanoscience & Nanotechnology

Effect of thermomechanical processing on compressive mechanical properties of Ti-15Mo additively manufactured by laser metal deposition

Edohamen Awannegbe, Liang Chen, Yue Zhao, Zhijun Qiu, Huijun Li

Summary: This study employed laser metal deposition to additively manufacture Ti-15Mo wt% alloy, and subsequently subjected it to post-fabrication uniaxial thermomechanical processing. The results showed that different zones in the microstructure remained after processing, and deformation mechanisms mainly involved slip and martensite formation. The compressive mechanical properties were found to be dependent on strain rate, with higher flow stress and compressive strength observed at higher strain rates. Grain structure homogenisation was not achieved, leading to anisotropic tensile properties.

MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING (2024)

Article Nanoscience & Nanotechnology

Crystallographic texture and the mechanical properties of API 5L X70 pipeline steel designated for an arctic environment

Reza Khatib Zadeh Davani, Enyinnaya George Ohaeri, Sandeep Yadav, Jerzy A. Szpunar, Jing Su, Michael Gaudet, Muhammad Rashid, Muhammad Arafin

Summary: This research aims to investigate the effect of roughing and finishing reductions on crystallographic texture. The results show significant heterogeneity in the centerline region, with higher intensity of certain textures. Drop Weight Tear Test indicates that steel specimens with lower and medium reductions exhibit superior low-temperature impact toughness compared to steel with higher reductions. The electrochemical hydrogen charging experiments confirm the presence of internal hydrogen cracks only in steel with lower and medium reductions.

MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING (2024)

Article Nanoscience & Nanotechnology

Effect of Cr content in temperature-dependent mechanical properties and strain hardening of a twinning-induced plasticity steel

Flavio De Barbieri, Denis Jorge-Badiola, Rodrigo Allende, Karem Tello, Alfredo Artigas, Franco Perazzo, Henry Jami, Juan Perez Ipina

Summary: This study examines the effect of Cr additions on the mechanical behavior of TWIP steel at temperatures ranging from 25°C to 350°C. The results indicate that different temperature-dependent strengthening mechanisms, including mechanical twinning, Dynamic Strain Aging, and slip bands, are at play. The stacking fault energy (SFE) influences the percentage of mechanical twinning, which in turn affects the strain hardening rate.

MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING (2024)

Article Nanoscience & Nanotechnology

Electron beam welding of L12-nanoparticle-strengthened strong and ductile medium-entropy alloys for cryogenic applications

Hanlin Peng, Siming Huang, Ling Hu, Bingbing Luo, Liejun Li, Ian Baker

Summary: This study explores the weldability, microstructures, and mechanical properties of two L1(2)-nanoparticle-strengthened medium-entropy alloys after electron beam welding (EBW). The results show that strong yet ductile defect-free joints were produced, with larger grain sizes in the fusion zones compared to the heat-affected zones and base materials. Both EBWed MEAs exhibited high yield strengths, high ultimate tensile strengths, and good fracture strains at 77 K. The V-doping improved the cryogenic mechanical properties of the TMT MEA.

MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING (2024)

Article Nanoscience & Nanotechnology

Strain rate-dependent tensile deformation behavior and fracture mechanism of Mn-N bearing lean duplex stainless steel

Yongxin Wang, Lei Chen, Lizi Shao, Shuo Hao, Motomichi Koyama, Xingzhou Cai, Xiaocong Ma, Miao Jin

Summary: This study investigated the tensile deformation behavior of an Mn-N bearing lean duplex stainless steel with metastable austenite. The results showed that the strain rate had significant influence on the work hardening, strain-induced martensitic transformation, and fracture mechanism.

MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING (2024)

Article Nanoscience & Nanotechnology

Recovery of sheet formability of cold-rolled pure titanium by cryogenic-deformation treatment

Jong Woo Won, Seulbi Lee, Hye-Jeong Choe, Yong-Taek Hyun, Dong Won Lee, Jeong Hun Lee

Summary: Cold-rolled pure titanium showed improved sheet formability after undergoing cryogenic-deformation treatment. This treatment increased the thinning capability of the titanium and suppressed cracking during sheet forming. The formation of twins during deformation contributed to high thinning capability and increased strength through grain refinement and dislocation accumulation.

MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING (2024)

Article Nanoscience & Nanotechnology

Rapidly induced homogenization and microstructure control of Cu-15Ni-8Sn alloy by electropulsing treatment

Handong Li, Lin Su, Lijuan Wang, Yanbin Jiang, Jiahui Long, Gaoyong Lin, Zhu Xiao, Yanlin Jia, Zhou Li

Summary: Homogenization heat treatment is a key procedure in controlling the second phase, enhancing composition uniformity, and workability of as-cast Cu-15Ni-8Sn alloy. This study found that electropulsing treatment (EPT) can significantly reduce treatment temperature and time, improve elongation and overall mechanical properties of the alloy.

MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING (2024)

Article Nanoscience & Nanotechnology

Study on the regulation of microstructure and mechanical properties of Cu-15Sn-0.3Ti alloy by a novel mechanical-heat-electricity synergistic method

Yuxuan Wang, Juntao Zou, Lixing Sun, Yunfei Bai, Zhe Zhang, Junsheng Cheng, Lin Shi, Dazhuo Song, Yihui Jiang, Zhiwei Zhang

Summary: A novel mechanical-heat-electricity synergistic method was proposed to enhance the mechanical properties of Cu-15Sn-0.3Ti alloy by forming annealing twins (ATs). The combination method of Rotary swaging (RS) and Electric pulse treatment (EPT) successfully induced recrystallization and refinement of the microstructure, leading to a significant increase in the strength of the alloy within a short time.

MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING (2024)

Article Nanoscience & Nanotechnology

Ta-induced strengthening of CoCrNi-AlTi medium-entropy alloys via nanoscale heterogeneous coherent precipitate

Zhiyi Ding, Jiangtao Xie, Tong Wang, Aiying Chen, Bin Gan, Jinchao Song

Summary: This study demonstrated the Ta-induced strengthening of CoCrNi-AlTi MEAs using nanoscale heterogeneous coherent precipitates. The addition of Ta and aging treatments significantly enhanced the mechanical properties of the alloy, including yield strength, ultimate tensile strength, and elongation.

MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING (2024)

Article Nanoscience & Nanotechnology

Microstructural evolution and deformation behavior of an interstitial TRIP high-entropy alloy under dynamic loading

Z. Y. You, Z. Y. Tang, B. Wang, H. W. Zhang, P. Li, L. Zhao, F. B. Chu, H. Ding

Summary: The mechanical properties and microstructural evolution of C-doped TRIP-assisted HEA under dynamic loading conditions were systematically investigated in this study. The results showed that dynamic tensile deformation led to an increase in yield strength and a decrease in ultimate tensile strength, with a trend towards increased total elongation. The primary deformation mechanisms shifted from TRIP and TWIP effects to deformation twinning and dislocations. The presence of carbides formed through C-doping hindered dislocation slip and promoted the activation of multiple twinning systems.

MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING (2024)

Article Nanoscience & Nanotechnology

Strong resistance to shear instability in multilayered metallic composites by nanoscale amorphous-BCC crystalline interfaces

Feng Qin, Feihu Chen, Junhua Hou, Wenjun Lu, Shaohua Chen, Jianjun Li

Summary: Plastic instability in strong multilayered composites is completely suppressed by architecting nanoscale BCC Nb crystalline-amorphous CuNb interfaces.

MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING (2024)