Journal
MATERIALS LETTERS
Volume 231, Issue -, Pages 43-46Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.matlet.2018.08.006
Keywords
Ceramics; Garnet; Sintering; Solid electrolytes; Ionic conductor
Funding
- Innovation Program of Shanghai Municipal Education Commission [14ZZ127]
- PCSIRT [IRT_16R49]
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Li7La3Zr2O12 (LLZO) garnet is one of the most promising Lithium-ion solid electrolytes in all-solid-state Lithium-ion batteries, due to its higher chemical stability to Li metal and relatively higher lithium-ion conductivity. To further increase the electrical conductivity of LLZO, Sm3+ is doped into the Zr4+ site of LLZO so that excess Li occupies the position of the octahedral. Thereby lithium ion transport and increasing ionic conductivity are promoted. The optimal addition of Sm3+ is 0.06. Li(7+x)La(3)Zr(2-x)SmxO(12) (LLZSO, x = 0.06) electrolyte with cubic phase is obtained with sintering at 1200 degrees C for only 3 h. It has higher relative density and better ionic conductivity than the pristine LLZO. Its bulk and total ionic conductivity are similar to 6.4 x 10(-4) S.cm(-1) and 2.46 x 10(-4) S.cm(-1) at 20 degrees C, respectively. (C) 2018 Elsevier B.V. All rights reserved.
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