Manufacture and characterization of activated carbon from marigold straw (Tagetes erecta L) by H3PO4 chemical activation

Marigold straw shows promise as an alternative raw material for activated carbon production. This study investigated the adsorption performance of activated carbon prepared from marigold straw and evaluated the preferable conditions for preparation. Activated carbons were prepared from a new precursor marigold (Tagetes erecta L) straw with phosphoric acid activation, using H3PO4 as an activator in air to create an abundant pore structure. Results show a higher iodine adsorption value (1145.38 mg/g) for activated carbon with an activation time of 2 h at 400 degrees C with a 2:1 weight ratio of the activator to the raw material. This study also characterized preferable carbon through microstructure morphology, elemental analysis and physical adsorption of N-2 at -196 degrees C. Findings reveal that part of the cellulose crystalline structure was destroyed, resulting in a significant increase in carbon content, from 46.73% to 74.55%. SEM photographs show that a porous structure formed during activation. The nitrogen adsorption-desorption isotherm illustrates a micropore structure and a Brunauer-Emmett-Teller (BET) surface area corresponding to 1344.23 m(2)/g, with a micropore surface area of up to 1113.65 m(2)/g. This study also assessed the microporosity of activated carbon with a mean pore diameter of 0.59 nm using a micropore size distribution curve. (C) 2014 Elsevier B.V. All rights reserved.