Article
Engineering, Environmental
Guixian Li, Gan Li, Qinan Mao, Lang Pei, Hua Yu, Meijiao Liu, Liang Chu, Jiasong Zhong
Summary: Introducing smaller Mg2+ ions to replace Ca2+ site in the BaLaCaSbO6 matrix leads to a significant enhancement in luminescence intensity, red-shift, and luminescence lifetime. These modulations are mainly attributed to the strengthen pressure on the local structure, superior lattice rigidity, and suppression of non-radiative transition after the substitution of smaller Mg2+. The effective lifetime-based luminescence thermometry is achieved due to thermal quenching behavior of Mn4+ ions in the matrix.
CHEMICAL ENGINEERING JOURNAL
(2022)
Article
Materials Science, Ceramics
Hanzhao Song, Wanying Wu, Zhifeng Xing, Xunsheng Zhou, Aihua Yao, Shanshan Hu, Ying Hong, Baolong Wang, Shuang Lu, Yinzhen Wang
Summary: In this study, Novel Te4+-doped CaYAlO4 phosphors were successfully synthesized via solid-state reaction and were found to emit deep-red light when excited by specific wavelengths. The optimal Te4+ doping concentration was identified as 2 mol%, and it was observed that the luminescent intensity of the phosphors could decrease with an increase in temperature.
CERAMICS INTERNATIONAL
(2021)
Article
Engineering, Electrical & Electronic
Juling Long, Yamin Xu, Weichao Huang, Chaoyong Deng
Summary: The Mn4+, Dy3+ co-doped La2MgTiO6 phosphors were synthesized using the high-temperature solid-phase method. The crystal phase luminescence properties, X-ray photoelectron spectroscopy (XPS), and thermal quenching were analyzed. The phosphors exhibited two emission peaks, one due to the energy level jump of Dy3+ ion and the other due to the energy jump of Mn4+. The influence of Mn4+, Dy3+ on temperature was different, and the maximum relative sensitivity was 2.85% K-1 in the range of 298-498 K. These results indicate the potential applications of La2MgTiO6: Mn4+, Dy3+ phosphors in optical thermometry.
JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS
(2023)
Article
Materials Science, Ceramics
Lei Zhong, Sha Jiang, Xihui Wang, Yanru Li, Yutong Wang, Jialiang Xie, Faling Ling, Yongjie Wang, Guotao Xiang, Li Li, Xianju Zhou
Summary: Self-calibrated temperature measurements combined with luminescence intensity ratio (LIR) and luminescence lifetime can improve the accuracy of temperature measurement. A dual-mode self-calibration optical thermometer based on CaNb2O6: Tb3+/Pr3+ phosphor was designed, which showed excellent sensitivity and potential application in different temperature ranges.
CERAMICS INTERNATIONAL
(2022)
Article
Chemistry, Physical
Robert Tomala, Krzysztof Korkus, Vitalii Boiko, Dariusz Hreniak, Pawel Gluchowski
Summary: Changing the Ga:Al ratio modulates the energy gap and modifies the spectroscopic properties of the phosphors. The stabilization of the Gd3Ga5O12 garnet structure by Al3+ ions widens the energy gap. Increasing Ga content leads to a decrease in the energy gap, affecting the interaction between oxygen ligands and luminescent ions.
JOURNAL OF ALLOYS AND COMPOUNDS
(2021)
Article
Engineering, Environmental
YunCheng Jiang, Ye Tong, SunYueZi Chen, WenNa Zhang, FangFang Hu, RongFei Wei, Hai Guo
Summary: A series of Ca2MgWO6:xEr3+, yYb3+ phosphor samples were synthesized through high temperature solid-state reaction method for optical thermometry. These samples showed intense up-conversion luminescence when excited by 980 nm laser, with enhanced emissions by addition of Yb3+ ions. The phosphors demonstrated a dual-mode temperature sensor and superior thermal stability, indicating potential applications for self-referenced optical thermometry.
CHEMICAL ENGINEERING JOURNAL
(2021)
Article
Chemistry, Multidisciplinary
Y. Hua, T. Wang, W. Xia, J. S. Yu, L. Li
Summary: Novel red-emitting Ba2Y0.8Eu0.2NbO6:Mn4+ phosphors were designed for multi-type non-contact luminescent thermometers based on the dual-emission states and temperature-dependent lifetime models. The phosphors showed high sensing sensitivities and have the potential for various applications in thermometers.
MATERIALS TODAY CHEMISTRY
(2022)
Article
Materials Science, Multidisciplinary
Teng Zheng, Malgorzata Sojka, Przemyslaw Wozny, Inocencio R. Martin, Victor Lavin, Eugeniusz Zych, Stefan Lis, Peng Du, Laihui Luo, Marcin Runowski
Summary: The concept of optical temperature sensing using band intensity ratio is a highly effective and non-invasive technique. In this study, a dual-center system, SrB4O7:Eu2+/Sm2+ phosphors, was employed as a bifunctional sensor for temperature and pressure. The phosphors showed high sensitivity and pressure dependence, making them promising candidates for optical sensing applications.
ADVANCED OPTICAL MATERIALS
(2022)
Editorial Material
Optics
Cyrille Richard, Bruno Viana
Summary: This article reviews the mechanisms of persistent luminescence of trivalent lanthanides in wide bandgap fluoride or phosphate hosts after charging by X-rays, and envisions the potential applications.
LIGHT-SCIENCE & APPLICATIONS
(2022)
Article
Chemistry, Inorganic & Nuclear
Hongping Ma, Shixu Tao, Youjie Hua, Jun Zheng, Luyi Lou, Yiheng Ping, Peng Qiao
Summary: The developed (Ba1-x-yCax)AlSi5O2N7:yEu(2+) phosphors show great potential in LED applications, with enhanced crystallinity and luminescence intensity achieved through some amount of Ca2+ substitution, reaching the highest luminescence intensity when the Eu2+ concentration is at 0.06.
DALTON TRANSACTIONS
(2021)
Article
Optics
Pavel Morozov, Maria Lukina, Marina Shirmanova, Alexander Divochiy, Varvara Dudenkova, Gregory N. Gol'tsman, Wolfgang Becker, Vladislav Shcheslavskiy
Summary: This letter introduces a novel optical configuration for direct time-resolved measurements of luminescence from singlet oxygen in solutions and cultured cells, using a superconducting single-photon detector. The system is verified by measuring phosphorescence signals from singlet oxygen generated by commonly used photosensitizers in photodynamic therapy.
Article
Chemistry, Inorganic & Nuclear
Rui Liu, Lili He, Chunhua Ge, Renchang Zhai, Kai Jia, Meiling Ren, Xiangdong Zhang
Summary: Tubular boron carbon oxynitride (BCNO) phosphors with orange-emitting were successfully synthesized with bamboo fiber assistance in this study. It was found that the synthesized BCNO phosphor showed bright orange emission with high quantum yield at a sintering temperature of 700 degrees Celsius. Additionally, the BCNO phosphor displayed a sensitive and selective quenching effect on Fe3+ ions, making it suitable for fingerprint recognition on object surfaces.
INORGANIC CHEMISTRY COMMUNICATIONS
(2021)
Article
Engineering, Electrical & Electronic
R. Satheesh, Meenu Venugopal, H. Padma Kumar
Summary: In this study, Y2-xSmx (MoO4)(3) red phosphors were successfully synthesized using the traditional solid-state ceramic method and self-propagating solution combustion technique. The synthesis methods were found to have an impact on the structural and optical properties of the samples.
JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS
(2022)
Article
Chemistry, Physical
Amos Vincent Ntarisa, D. Joseph Daniel, D. Balaji, Arumugam Raja, H. J. Kim, Nguyen Duy Quang
Summary: In this study, powder samples of pure and Ce3+ doped cesium barium yttrium hexaborate were synthesized using a standard solid-state reaction technique. Various characterization techniques were employed to investigate the properties of the prepared samples. The rare earth ion Ce3+ was found to enhance the intrinsic luminescence of the phosphors, with an optimal doping concentration of 4 mol%. Additionally, the luminescence properties of the prepared phosphors were studied in detail for the first time in this manuscript.
JOURNAL OF ALLOYS AND COMPOUNDS
(2021)
Review
Materials Science, Multidisciplinary
Yangmin Tang, Mingxue Deng, Machao Wang, Xiaofeng Liu, Zhenzhen Zhou, Jiacheng Wang, Qian Liu
Summary: This review discusses the recent advances in Bi-activated persistent luminescence (PersL) phosphors, focusing on the structure-defect-property relationships. The review highlights the strategies of modulating PersL through adjusting the local structures, including defect engineering and theoretical prediction. It also proposes future challenges and perspectives for Bi-activated PersL phosphors.
ADVANCED OPTICAL MATERIALS
(2022)
Article
Chemistry, Physical
Yong Zhang, Rui Zhang, FeiFei Chen, FeiFei Zhang, Yingda Liu, Xiaoya Hao, Haokun Jin, Xinghua Zhang, Zunming Lu, Hong Dong, Feng Lu, Weihua Wang, Hui Liu, Yahui Cheng
Summary: The study proposes an in-situ electroreduction strategy to solve the mass transfer and product mixing issues in electrochemical CO2 reduction reaction by constructing hydrophobic Bi microsheets. The obtained microsheets exhibit high activity and selectivity, demonstrating the potential for continuous production of pure formate solution.
APPLIED CATALYSIS B-ENVIRONMENTAL
(2023)
Article
Chemistry, Physical
Baosong Li, Yangyang Ren, Chenhao Lv, Fan Gao, Xinghua Zhang, Xiaojing Yang, Lanlan Li, Zunming Lu, Xiaofei Yu
Summary: A facile template-free method was reported for the synthesis of ultrathin-wall PtCu nanocages with small islands on the surface (U-PtCu NCs). The wall thickness of nanocages and the density of islands were well-tuned by controlling the experiment conditions. The novel hollow structures with abundant defects as well as the synergistic interaction between Pt and Cu elements endowed U-PtCu NCs with enhanced ORR activity.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2023)
Article
Chemistry, Physical
Zehao Zang, Qianjin Guo, Xiang Li, Yahui Cheng, Lanlan Li, Xiaofei Yu, Zunming Lu, Xiaojing Yang, Xinghua Zhang, Hui Liu
Summary: This paper proposes a strategy to regulate the non-metal atom sulfur and oxyphilic transition metal atom iron to optimize the alkaline hydrogen evolution reaction and oxygen evolution reaction performance of metallic nickel. The results show that this regulation method can significantly enhance the activity of nickel catalyst, enabling it to achieve high current density at lower overpotential. Experimental results demonstrate that the sulfur and iron regulation can optimize the adsorption of hydrogen and water, thereby improving the performance of the hydrogen evolution reaction, and the derived sulfur-doped NiFe hydroxyl oxide enhances the performance of the oxygen evolution reaction.
JOURNAL OF MATERIALS CHEMISTRY A
(2023)
Article
Nanoscience & Nanotechnology
Xiaoming Mu, Kai Wang, Keyi Lv, Bo Feng, Xiaofei Yu, Lanlan Li, Xinghua Zhang, Xiaojing Yang, Zunming Lu
Summary: In this work, a multicomponent transition metal catalyst Cr-Cu/CoOx was loaded on copper foam by electrodeposition and annealing, and exhibited excellent electrochemical activity. The HER overpotential is 21 mV and the OER overpotential is 252 mV at a current density of 10 mA cm-2. The overall water splitting voltage is 1.51 V, even better than the Pt/C//RuO2 two-electrode system (1.61 V). The excellent performance of this catalyst is mainly derived from the synergistic interaction among Cu, Co, and Cr.
ACS APPLIED MATERIALS & INTERFACES
(2023)
Article
Chemistry, Physical
Xianchao Wang, Zehao Zang, Chunyan Fan, Yintao Zhang, Xiang Li, Lanlan Li, Xiaofei Yu, Xiaojing Yang, Zunming Lu, Xinghua Zhang
Summary: In this study, group IB metals including gold, silver, and copper were used to enhance the performance of cobalt hydroxide (Co(OH)(2)) catalyst for the oxygen evolution reaction (OER) via electrodeposition method. The formation of Ag-Co(OH)(2) heterostructure optimized the electronic structure through interfacial interactions and improved the charge transport capacity and adsorption of hydroxyl species, thus accelerating the OER kinetics and enhancing the inherent catalytic activity.
Article
Engineering, Environmental
Rui Zhang, Feifei Chen, Haokun Jin, Yong Zhang, Xiaoya Hao, Yingda Liu, Tianming Feng, Xinghua Zhang, Zunming Lu, Weihua Wang, Feng Lu, Hong Dong, Hui Liu, Yahui Cheng
Summary: In Cu-based electrocatalysts, maintaining an appropriate amount of Cu0 and Cu+ species is crucial for efficient CO2 conversion. Intermediate confinement is a promising solution to delay Cu+ deterioration and protect Cu+ species. Synthesizing hollow Cu2O nanoreactors with different cavity sizes allows for the modulation of intermediates concentration and Cu+/Cu0 ratio, leading to improved performance.
CHEMICAL ENGINEERING JOURNAL
(2023)
Article
Chemistry, Physical
Yangyang Ren, Zehao Zang, Chenhao Lv, Beibei Li, Lanlan Li, Xiaojing Yang, Zunming Lu, Xiaofei Yu, Xinghua Zhang
Summary: Highly durable and active PtCuCo nanoframes were prepared as enhanced bifunctional electrocatalysts for oxygen reduction reaction (ORR) and methanol oxidation reaction (MOR) in acidic environment. The PtCuCo nanoframes exhibited remarkable activity and durability due to their ternary compositions and structure-fortifying frame structures. The specific/mass activity of PtCuCo nanoframes for ORR in perchloric acid solution was 12.8/7.5 times as large as that of commercial Pt/C, while for MOR in sulfuric acid solution, the mass/specific activity was 5.4/9.4 times as large as that of Pt/C. This work may provide a promising nanoframe material for developing dual catalysts for fuel cells.
JOURNAL OF COLLOID AND INTERFACE SCIENCE
(2023)
Article
Chemistry, Physical
Jianxiu Wang, Xinning Zhao, Guoqing Qin, Xinghua Zhang, Zunming Lu, Xiaofei Yu, Lanlan Li, Xiaojing Yang
Summary: Ammonia borane (AB, NH3BH3) is a promising hydrogen storage material due to its high hydrogen content, low molecular weight, high solubility, high stability, and non-toxicity. However, the slow rate of hydrogen release from AB in pure water has led to research on catalysts. Metal oxides have shown potential as catalysts for the hydrolysis of AB, but oxidation and agglomeration of transition metals hinder their activity and stability. This review summarizes the research progress on metal oxide-based catalysts, discussing their preparation methods, compositional structures, performance optimization, hydrolysis mechanisms, and future prospects.
RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A
(2023)
Article
Electrochemistry
Chunyan Fan, Zehao Zang, Xiang Li, Junfang Zhang, Ping Yang, Lanlan Li, Xiaofei Yu, Xiaojing Yang, Zunming Lu, Xinghua Zhang
Summary: A copper modified sulfur doped Co(OH)2 hybrid catalyst (Cu@S-Co(OH)2) was prepared and showed efficient hydrogen evolution reaction (HER) activity with ultralow overpotential of 42 mV at a current density of 10 mA cm 2. The active center was identified as cobalt metal, and both sulfur and copper enhanced the adsorption of OH species while sulfur contributed to the adsorption of H and copper promoted the desorption of H. This study provides a facile method and new insight to enhance the HER activity for transition metal hydroxides via metal and non-metallic elements co-modulation.
ELECTROCHIMICA ACTA
(2023)
Article
Chemistry, Physical
Chenhao Lv, Yangyang Ren, Beibei Li, Zunming Lu, Lanlan Li, Xinghua Zhang, Xiaojing Yang, Xiaofei Yu
Summary: Co4N@NCNT-900, prepared by 1,2,4-TZ-assisted pyrolysis of Co-MOF-74, exhibited excellent catalytic performance in both ORR and OER due to the activity of Co4N particles and the highly graphitized NCNTs, making it a bifunctional high active catalyst for ZABs.
JOURNAL OF COLLOID AND INTERFACE SCIENCE
(2023)
Article
Chemistry, Multidisciplinary
Yintao Zhang, Zehao Zang, Xiang Li, Ping Yang, Junfang Zhang, Lanlan Li, Xiaofei Yu, Xiaojing Yang, Zunming Lu, Xinghua Zhang
Summary: Efficient, stable, and low-cost Co3O4/BCNO composites were prepared as catalysts for the oxygen reduction reaction. BCNO nanosheets doped with carbon and oxygen elements effectively prevent the agglomeration of Co3O4 and stimulate catalytic activity. The Co3O4/BCNO composite catalyst exhibits better performance than Co3O4 and commercial Pt/C in terms of half-wave potential, kinetic reaction rate, stability, and methanol tolerance. The Co3O4/BCNO composite-based Zn-air battery shows high power density and specific capacity.
NEW JOURNAL OF CHEMISTRY
(2023)
Article
Materials Science, Multidisciplinary
Deyong Zheng, Huihui Jin, Yucong Liao, Pengxia Ji
Summary: In this study, a highly stable and efficient catalyst, fluorine-doped Co3O4 (F-Co3O4), was developed for hydrogen production by water electrolysis. The F-Co3O4 catalyst exhibited a remarkable reduction in overpotential and demonstrated excellent stability for over 100 hours.
Article
Materials Science, Multidisciplinary
Ziwen Lv, Jintao Wang, Fengyi Wang, Jianqiang Wang, Fuquan Li, Hongtao Chen
Summary: Adding Cu6Sn5 nano particles can effectively inhibit the overgrowth of intermetallic compounds at the interfaces of solder joints in electronic devices, providing a solution to this issue. A new growth mechanism of intermetallic compounds at the interfaces was identified.
Article
Materials Science, Multidisciplinary
Jun Wang, Jiawei Chen, Wanru Liao, Fangyang Liu, Min Liu, Liangxing Jiang
Summary: A BiOI/AgI/Ag plasmonic heterostructure photocathode was successfully designed through electrodeposition, ion-exchange, and illumination methods. This photocathode exhibits superior performance in photoelectrochemical water splitting.
Article
Materials Science, Multidisciplinary
Xiaoxiao Liu, Xianxian Zhou, Xiaotao Ma, Qinbo Yuan, Shibin Liu
Summary: In this study, the authors propose a method to accelerate the reaction of polysulfides in lithium-sulfur batteries using a Ni@OC Mott-Schottky heterojunction as a catalyst. The experimental results demonstrate that the charge redistribution at the Ni@OC interface accelerates electron transfer and enhances catalytic activity, leading to improved reaction kinetics and battery performance.
Article
Materials Science, Multidisciplinary
Dayou Ma, Mohammad Rezasefat, Joziel Aparecido da Cruz, Sandro Campos Amico, Marco Giglio, Andrea Manes
Summary: The matrix has a significant effect on the impact resistance of composite materials. Replacing a brittle polymer with a more flexible one can improve impact resistance, but it poses challenges to standard testing methods. This study designs a new fixture for testing the low-velocity impact of soft composites and investigates the effect of the fixture on the mechanical performance.
Article
Materials Science, Multidisciplinary
Lingchang Wang, Qihang Yang, Huzhen Li, Ming Wei, Qian Wang, Zhenzhong Hu, Mengmeng Zhen
Summary: Bronze titanium dioxide (TiO2(B)) is a promising anode material for lithium-ion batteries due to its high specific capacity. However, its practical applications are hindered by poor conductivity and limited electrochemical kinetics. In this study, TiO2(B)-carbon nanosheets heterostructures are synthesized to enhance the cycling performance and rate capability of TiO2(B).
Article
Materials Science, Multidisciplinary
Atul Thakur, Ritesh Verma, Ankush Chauhan, Fayu Wan, Preeti Thakur
Summary: In this study, BaFe12O19 and BaFe12O19: Epoxy (50:50) nanocomposites were synthesized using the co-precipitation method. The structural information and material properties, such as crystallite size and electrical conductivity, were characterized by XRD, FESEM, EDX, and TEM techniques.
Article
Materials Science, Multidisciplinary
Jingyu Wu, Xinyan Ma, Yong Yang
Summary: A well-defined CoS2@NC(CS-500) hierarchical binder-free catalyst cathode is constructed through in-situ grown of ZIF-67 on carbon cloth and high-temperature carbonization. The cathode shows excellent reaction kinetics and electrochemical performance, providing inspiration for developing advanced Li-CO2 battery catalysts.
Article
Materials Science, Multidisciplinary
Svetlana M. Posokhova, Vladimir A. Morozov, Kirill N. Boldyrev, Dina Deyneko, Erzhena T. Pavlova, Bogdan I. Lazoryak
Summary: This study explores the impact of synthesis method and composition on the structure and luminescence properties of K5Eu1-xHox(MoO4)4 with the palmierite-type matrix. The co-doping of Eu3+ and Ho3+ ions plays a critical role in manipulating charge transfer and luminescence efficiency in the visible and infrared regions.
Article
Materials Science, Multidisciplinary
Jian Wang, Yeting Tao, Jingsheng Wang, Youtian Tao
Summary: A new electron-transport material iTPyBI-CN is developed through non-catalytic C-N coupling reaction. It exhibits better electroluminescence efficiency in organic light-emitting diodes compared to the commercial material TPBI, due to its twisted geometry and higher energy levels.
Article
Materials Science, Multidisciplinary
Tao Zhu, Feng Huang, Shuo Li, Yang Zhou
Summary: This article combines XRD analysis and microscopic structural observation to investigate the changes in limestone after high-temperature treatment. It finds that 500 degrees C is the critical temperature for crystalline and spatial arrangement changes in limestone, and the thermal conductivity, specific heat capacity, and heat storage coefficient gradually decrease after thermal treatment.
Article
Materials Science, Multidisciplinary
Muhammad Haekal Habibie, Fransiska Sri Herwahyu Krismastuti, Abdi Wira Septama, Faiza Maryani, Vivi Fauzia
Summary: This study focuses on the synthesis of zinc oxide nanostructure from zinc recovered from galvanization ash and highlights its potential as a sustainable source of zinc and as an antibacterial agent.
Article
Materials Science, Multidisciplinary
Jingyi Li, Yixin Xing, Wei Gu, Shousi Lu
Summary: In this study, PC@CaP microparticles were fabricated using biomimetic mineralization. The results showed that under environmental stress, PC@CaP exhibited improved stability and antioxidative activity, indicating its potential use in high-added value fields.
Article
Materials Science, Multidisciplinary
Yan Liu, Shunyou Chen
Summary: In this study, TNTs were used as a drug carrier and modified with ZIF-8 and silk fibroin to obtain a new drug loading platform. The results showed that this drug-loaded platform had a good drug release effect in vitro and could promote cell proliferation and osteogenic differentiation.
Article
Materials Science, Multidisciplinary
Chunhui Zhu, Wentao Wang, Qing Zhen, Xinning Huang, Shixin Li, Shaochang Wang, Xiaoping Ma, Xiaoxia Liu, Yalong Jiao, Kai Sun, Zhuangzhi Li, Huaixin Yang, Jianqi Li
Summary: A type of stacking fault is revealed in e-InSe crystal, which is associated with a small stacking-fault energy and shows exceptional plasticity.
