4.6 Article

New method to improve the grain alignment and performance of thermoelectric ceramics

Journal

MATERIALS LETTERS
Volume 83, Issue -, Pages 144-147

Publisher

ELSEVIER SCIENCE BV
DOI: 10.1016/j.matlet.2012.05.131

Keywords

Texturing; Thermoelectric ceramics; Electrical properties; Thermopower

Funding

  1. CSIC
  2. MICINN-FEDER [MAT2008-00429]
  3. Universidad de Zaragoza [UZ2011-TEC-03]
  4. Gobierno de Aragon (Grupos de Investigacion consolidados) [T12, T87]
  5. FCT [REDE/1509/RME/2005]
  6. Portuguese Science and Technology Foundation (FCT) [PEst-C/CTM/LA0025/2011]
  7. [E-41/11]
  8. [AIB2010-PT-00247]

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Textured Bi2Ca2Co1.7Ox ceramic rods were obtained by Electrically Assisted Laser Floating Zone (EALFZ) technique. The polarity effects of an external current, applied during the laser floating zone growth, have been investigated. Microstructure and thermoelectric properties have been studied and correlated with the current polarity. An important improvement of power factor was obtained for samples grown with the positive pole connected to the seed. This result evidences the advantages of EALFZ technique as a potential method for obtaining high performance thermoelectric materials. Crown Copyright (C) 2012 Published by Elsevier B.V. All rights reserved.

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